Binder compositions
A binder composition for a non-woven fabric, the binder composition comprising a latex, the latex including a heterogeneous blend of dispersed polymer particles and a surfactant, where the particles include from about 55 to about 100% by weight of a gelled polymer, from about 1 to about 15% by weight polymeric units bearing an acid functionality, and where dried films of the latex exhibit a Tg of from about −50° C. to about 60° C.
1 . A binder composition for a non-woven fabric, the binder composition comprising:
a latex, the latex including a heterogeneous blend of dispersed polymer particles and a surfactant, where the particles include from about 55 to about 100% by weight of a gelled polymer, from about 1 to about 15% by weight polymeric units bearing an acid functionality, and where dried films of the latex exhibit a Tg of from about −50° C. to about 60° C.
2 . The binder composition of claim 1 , where the polymer particles includes from about 75 to about 98% by weight of a gelled polymer.
3 . The binder composition of claim 1 , where the polymer particles include from about 3 to about 12% by weight polymeric units bearing an acid functionality.
4 . The binder composition of claim 1 , where dried films of the latex exhibit a Tg of from about −35° C. to about 35° C.
5 . The binder composition of claim 1 , where the gelled polymer includes from about 15 to about 75% by weight units deriving from conjugated diene monomer.
6 . The binder composition of claim 5 , where the conjugated diene monomer is 1,3-butadiene.
7 . The binder composition of claim 1 , where the polymeric units bearing an acid functionality derived from acrylic acid, methacrylic acid, itaconic acid, or mixtures thereof.
8 . The binder composition of claim 7 , where the polymer particles include from about 0 to about 3% by weight units deriving from itaconic acid, from about 2 to about 7% by weight units deriving from acrylic acid, and from about 1 to about 6% by weight units deriving from methacrylic acid.
9 . The binder composition of claim 7 , where the polymer particles include from about 0 to about 8% by weight units deriving from acrylic acid, and from about 0 to about 8% by weight units deriving from methacrylic acid.
10 . The binder composition of claim 7 , where the polymer particles include from about 1 to about 7% by weight units deriving from acrylic acid, and from about 1 to about 7% by weight units deriving from methacrylic acid.
11 . The binder composition of claim 7 , where the polymer particles include from about 2 to about 6% by weight units deriving from acrylic acid, and from about 2 to about 6% by weight units deriving from methacrylic acid, and from about 0.5 to about 3% by weight units deriving from itaconic acid.
12 . The binder composition of claim 7 , where the polymer particles include from about 2.5 to about 5% by weight units deriving from acrylic acid, and from about 2.5 to about 5% by weight units deriving from methacrylic acid, and from about 1 to about 2% by weight units deriving from itaconic acid.
13 . The binder composition of claim 1 , where the latex is characterized by a pH of from about 4.5 to about 8.0.
14 . The binder composition of claim 1 , where the surfactant includes an alkali metal salt of an alkyl sulfosuccinate, a salt of alkyl sulfate, a salt of an organo disulfonate, or a mixture thereof.
15 . The binder composition of claim 14 , where the alkali metal salt of an alkyl sulfosuccinate includes alkali metal salts of mono and dialkyl sulfosuccinates, and where the alkyl substituents include from about 5 to about 12 carbon atoms.
16 . The binder composition of claim 15 , where the surfactant includes from about 50 to about 99% by weight sodium dihexyl sulfosuccinate compounds and from about 1 to about 50% by weight sodium dioctyl sulfosuccinate compounds.
17 . The binder composition of claim 1 , where the surfactant includes sodium dihexyl sulfosuccinate, sodium dioctyl sulfosuccinate, sodium octane sulfonate, an alkyl phenol ethoxylate, a fatty alcohol ethoxylate, an alkyl polyglucoside, an alkyl phosphate, sodium lauryl sulfate, sodium dodecyl diphenyloxide disulfonate, sodium laureth sulfate, Laureth-3, Laureth-4, Laureth-, Laureth-6, Laureth-7, sodium lauryl ether sulfate, sodium laureth-12 sulfate, sodium laureth-30 sulfate, or a mixture thereof.
18 . The binder composition of claim 1 , where the composition further includes a froth agent.
19 . The binder composition of claim 18 , where the froth agent includes disodium stearyl sulfosuccinamate.
20 . The binder composition of claim 1 , where the composition includes sodium laureth sulfate, and optionally an alkali metal salt of an alkyl sulfosuccinate, a salt of alkyl sulfate, or a salt of an organo disulfonate.
21 . The binder composition of claim 1 , where the composition includes sodium laureth sulfate and disodium stearyl sulfosuccinamate.
22 . The binder composition of claim 1 , where the composition includes sodium dodecyl diphenyloxide disulfonate and disodium stearyl sulfosuccinamate.
23 . The binder composition of claim 1 , where the composition includes an alkyl ether sulfate.
24 . The binder composition of claim 23 , where the composition further includes disodium stearyl sulfosuccinamate.
25 . The binder composition of claim 1 , where the latex composition includes from about 0.1 to about 10% by weight surfactant.
26 . The binder composition of claim 1 , where the polymer particles include from about 15 to about 75% by weight units deriving from styrene.
27 . A non-woven fabric bound with a binder composition, the binder composition comprising:
a latex, the latex including a heterogeneous blend of dispersed polymer particles and a surfactant, where the particles include from about 55 to about 100% by weight of a gelled polymer, from about 1 to about 15% by weight polymeric units bearing an acid functionality, and where dried films of the latex exhibit a Tg of from about −50° C. to about 60° C.
28 . The non-woven fabric bound with a binder composition of claim 27 , where the polymer particles include from about 75 to about 98% by weight of a gelled polymer.
29 . The non-woven fabric bound with a binder composition of claim 27 , where the polymer particles include from about 3 to about 12% by weight polymeric units bearing an acid functionality.
30 . The non-woven fabric bound with a binder composition of claim 27 , where dried films of the latex exhibit a Tg of from about −35° C. to about 35° C.
31 . A diaper sub-layer comprising a non-woven fabric bound with a binder composition, the binder composition comprising:
a latex, the latex including a heterogeneous blend of dispersed polymer particles and a surfactant, where the particles include from about 55 to about 100% by weight of a gelled polymer, from about 1 to about 15% by weight polymeric units bearing an acid functionality, and where dried films of the latex exhibit a Tg of from about −50° C. to about 60° C.
32 . The diaper sub-layer of claim 31 , where the polymer particles includes from about 75 to about 98% by weight of a gelled polymer.
33 . The diaper sub-layer of claim 31 , where dried films of the latex exhibit a Tg of from about −35° C. to about 35° C.