IP Library Granted Patent US 7,579,500
Granted Patent B2
US 7,579,500 · App. 10/586,491 · Granted Aug 25, 2009

Method for producing 2,5-dimethylphenyl acetic acid

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Quick Facts
Patent No.
US 7,579,500
App. No.
10/586,491
Granted
Aug 25, 2009
Kind
B2
Abstract

The invention relates to a method for preparing 2,5-dimethylphenylacetic acid by converting p-xylene with chloroacetyl chloride into 2-chloro-1-(2,5-dimethylphenyl)ethanone, which is reacted with the compound of the formula (II) to give the compound of the formula (III), which is then rearranged to give a mixture of the compounds (IV) and (V), which is then hydrolyzed to 2,5-dimethylphenylacetic acid.

Claims (12)

1. A method for preparing 2,5-dimethyiphenylacetic acid, characterized in that p-xylene is converted with chloroacetyl chloride in a Friedel-Crafts reaction into 2-chloro-1-(2,5-dimethylphenyl)ethanone, which is reacted with the compound of the formula (II)

HO—CH 2 —X—CH 2 —OH  (II)

in which

X is a direct single bond or selected from the group consisting of CH 2 , CHCH 3 , C(CH 3 ) 2 and C(C 2 H 5 ) 2 ,

to give the compound of the formula (III)

in which

X has the meaning indicated above; the compound of the formula (III) is then rearranged to give a mixture of the formulae (IV) and (V)

in which

X has the meanings indicated above,

and the latter is then hydrolyzed to 2,5-dimethylphenylacetic acid.

2. The method for preparing 2,5-dimethylphenylacetic acid as claimed in claim 1 , where X is a direct single bond or selected from the group consisting of CH 2 , C(CH 3 ) 2 and C(C 2 H 5 ) 2 .

3. The method for preparing 2,5-dimethylphenylacetic acid as claimed in claim 1 , where X is a direct single bond or selected from the group consisting of C(CH 3 ) 2 and C(C 2 H 5 ) 2 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 20, 2015
From: BAYER CROPSCIENCE AG
To: BAYER INTELLECTUAL PROPERTY GMBH
Reel/Frame 034990/0879 →