Production processes and systems, compositions, surfactants, monomer units, metal complexes, phosphate esters, glycols, aqueous film forming foams and foam stabilizers
Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohols, reacting olefins and a saturated compounds, reacting reactants having at least two —CF 3 groups with reactants having cyclic groups. R F -compositions such as R F -intermediates, R F -surfactants, R F monomers, R F -monomer units, R F -metal complexes, R F -phosphate esters, R F -glycols, R F -urethanes, and/or R F -foam stabilizers. The R F portion can include at least two CF 3 groups, at least three —CF 3 groups, and/or at least two —CF 3 groups and at least two —CH 2 — groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the R F -surfactant composition are provided. Acrylics, resins, and polymers are provided that include a R F -monomer unit. Compositions are provided that include a substrate having a R F -composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include R F surfactants and/or R F -foam stabilizers are provided.
1 . A composition comprising an R F -monomer, wherein R F comprises at least three —CF 3 groups and at least two hydrogens.
2 . The composition of claim 1 wherein R F comprises at least one —CH 2 — group.
3 . The composition of claim 1 wherein R F comprises at least one cyclic group.
4 . The composition of claim 1 wherein R F comprises at least one aromatic group.
5 - 6 . (canceled)
7 . The composition of claim 1 wherein R F comprises at least two (CF 3 ) 2 CF— groups.
8 . The composition of claim 1 wherein R F comprises at least four carbons and one of the four carbons comprises a —CH 2 — group.
9 . The composition of claim 1 wherein the R F -monomer comprises R F -Q M , wherein the Q M portion comprises a group configured to react with another monomer to form at least a portion of an oligomer.
10 . The composition of claim 9 wherein the Q M portion comprises an olefin.
11 . The composition of claim 10 wherein the
12 . The composition of claim 9 wherein the Q M portion comprises an acrylate.
13 . The composition of claim 12 wherein the R F -Q M is
wherein R is H or CH 3 .
14 - 15 . (canceled)
16 . The composition of claim 9 wherein the R F -Q M is
17 . The composition of claim 9 wherein the R F -Q M is
18 - 19 . (canceled)
20 . The composition of claim 9 wherein the R F -Q M is
21 . The composition of claim 9 wherein the R F -Q M is
22 . The composition of claim 9 wherein the R F -Q M is
23 . The composition of claim 9 wherein the R F -Q M is
24 - 25 . (canceled)
26 . The composition of claim 9 wherein the R F -Q M is
27 . The composition of claim 9 wherein the R F -Q M is
28 - 29 . (canceled)
30 . A composition comprising a R F -monomer unit, wherein R F comprises a pendant group of the monomer unit, the pendant group comprising at least two —CF 3 groups and at least two hydrogens.
31 . The composition of claim 30 wherein the R F -monomer unit comprises R F -Q MU , Q MU comprising a remainder of the monomer unit.
32 . The composition of claim 30 wherein the pendant group comprises at least one
—CH 2 — group.
33 . The composition of claim 30 wherein the pendant group comprises at least one cyclic group.
34 . The composition of claim 30 wherein the pendant group comprises at least one aromatic group.
35 . The composition of claim 30 wherein the pendant group comprises at least one (CF 3 ) 2 CF— group.
36 . The composition of claim 30 wherein the pendant group comprises at least three —CF 3 groups.
37 . The composition of claim 30 wherein the pendant group comprises at least two (CF 3 ) 2 CF— groups.
38 . The composition of claim 30 wherein the pendant group comprises at least four carbons and one of the four carbons comprises a —CH 2 — group.
39 . The composition of claim 30 wherein the composition comprises an acrylic and the R F -Q MU is a monomer unit of the acrylic.
40 . The composition of claim 30 wherein the composition comprises a resin and the R F -Q MU is a monomer unit of the resin.
41 . The composition of claim 40 wherein the resin comprises a polyurethane resin.
42 . The composition of claim 30 wherein the composition comprises a polymer and the R F -Q MU is a monomer unit of the polymer.
43 . The composition of claim 42 wherein the polymer comprises a copolymer.
44 . The composition of claim 42 wherein the polymer comprises a block polymer.
45 . A composition comprising a R F -composition, R F comprising at least two —CF 3 groups and the composition comprises one or more of a metal complex, a phosphate ester, a glycol, and a urethane.
46 . The composition of claim 45 wherein the R F -composition comprises R F -Q MC , Q MC comprising a remainder of a metal complex.
47 . The composition of claim 46 wherein R F comprises at least one —CH 2 — group.
48 . The composition of claim 46 wherein R F comprises at least one cyclic group.
49 . The composition of claim 46 wherein the cyclic group comprises an aromatic group.
50 . The composition of claim 46 wherein R F comprises at least one (CF 3 ) 2 CF— group.
51 . The composition of claim 46 wherein R F comprises at least three —CF 3 groups.
52 . The composition of claim 46 wherein R F comprises at least two (CF 3 ) 2 CF— groups.
53 . The composition of claim 46 wherein R F comprises at least four carbons and one of the four carbons comprises a —CH 2 — group.
54 . The composition of claim 46 wherein R F -Q MC , is
55 . The composition of claim 45 wherein Q C comprises a metal complex, the metal complex comprising a metal and a ligand, the ligand comprising R F -Q g , wherein:
R F comprises at least two —CF 3 groups and at least two hydrogens; and
Q g is coordinated with the metal of the complex.
56 - 63 . (canceled)
64 . The composition of claim 45 wherein the R F -composition comprises R F -Q PE , Q PE comprising a remainder of a phosphate ester.
65 . The composition of claim 64 wherein R F -Q PE
66 - 73 . (canceled)
74 . The composition of claim 45 wherein the R F -composition comprises R F -Q H , Q H comprising a remainder of a glycol.
75 . The composition of claim 74 wherein R F -Q H is
76 - 82 . (canceled)
83 . The composition of claim 45 wherein the R F -composition comprises R F -Q U , Q U comprising a remainder of a urethane.
84 . The composition of claim 83 wherein R F -Q U