Production Processes and Systems, Compositions, Surfactants, Monomer Units, Metal Complexes, Phosphate Esters, Glycols, Aqueous Film Foams, and Foam Stabilizers
Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohols, reacting olefins and a saturated compounds, reacting reactants having at least two —CF 3 groups with reactants having cyclic groups. R F -compositions such as R F -intermediates, R F -surfactants, R F -monomers, R F -monomer units, R F -metal complexes, R F -phosphate esters, R F -glycols, R F -urethanes, and/or R F -foam stabilizers. The R F portion can include at least two —CF 3 groups, at least three —CF 3 groups, and/or at least two —CF 3 groups and at least two —CH 2 — groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the R F -surfactant composition are provided. Acrylics, resins, and polymers are provided that include a R F -monomer unit. Compositions are provided that include a substrate having a R F -composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include R F -surfactants and/or R F -foam stabilizers are provided.
1 - 24 . (canceled)
25 . A composition comprising R F -Q g , wherein R F comprises at least three —CF 3 groups and Q g is not a proton, methyl group, or methylene group.
26 . The composition of claim 25 wherein Q g comprises one more of a halogen, a hydroxyl, a cyano, an acetate, an allyl, an epoxide, an acrylic ester, an ether, a sulfate, a thiol, a phosphate, and an amine.
27 . The composition of claim 25 wherein R F comprises at least one (CF 3 ) 2 CF— group.
28 . The composition of claim 25 wherein R F comprises at least two (CF 3 ) 2 CF— groups.
29 . The composition of claim 25 wherein R F -Q g is
30 . The composition of claim 29 wherein R F -Q g is
31 . The composition of claim 25 wherein R F -Q g is
32 . The composition of claim 25 wherein R F -Q g is
33 . The composition of claim 25 wherein R F -Q g is
34 . The composition of claim 25 wherein R F -Q g is
35 . The composition of claim 25 wherein R F -Q g is
36 . The composition of claim 25 wherein R F -Q g is
37 . The composition of claim 25 wherein R F -Q g is
38 . The composition of claim 25 wherein R F -Q g is
39 . The composition of claim 25 wherein R F -Q g is
40 . The composition of claim 25 wherein R F -Q g is
41 . The composition of claim 25 wherein the R F -Q g comprises
42 . A composition comprising R F -Q g , wherein:
R F comprises at least two —CF 3 groups and at least two —CH 2 — groups; and
Q g is not a proton, methyl group or methylene group.
43 . The composition of claim 42 wherein Q g comprises one or more of a halogen, a hydroxyl, a cyano, an acetate, an allyl, an epoxide, an acrylic ester, an ether, a sulfate, a thiol, a phosphate, and an amine.
44 . The composition of claim 42 wherein R F comprises at least one (CF 3 ) 2 CF— group.
45 . The composition of claim 42 wherein R F -Q g is
46 . The composition of claim 42 wherein R F -Q g is
47 . The composition of claim 42 wherein R F -Q g is
48 . The composition of claim 42 wherein R F -Q g is
49 . The composition of claim 42 wherein R F -Q g is
50 . The composition of claim 42 wherein R F -Q g is
51 . The composition of claim 42 wherein R F -Q g is
52 . The composition of claim 42 wherein R F -Q g is
53 . The composition of claim 42 wherein R F -Q g is
54 . The composition of claim 42 wherein R F -Q g is
55 . The composition of claim 42 wherein R F -Q g is
56 . The composition of claim 42 wherein R F -Q g is
57 . The composition of claim 42 wherein R F -Q g is
58 . The composition of claim 42 wherein R F -Q g is
59 . The composition of claim 42 wherein R F -Q g is
60 . The composition of claim 42 wherein R F -Q g is
61 - 64 . (canceled)
65 . A composition comprising R F -Q g , wherein R F comprises at least two —CF 3 groups and Q g comprises an epoxide group.
66 . The composition of claim 65 wherein R F -Q g is
67 . A composition comprising R F -Q g , wherein R F comprises at least two —CF 3 groups and Q g comprises an ester group.
68 . The composition of claim 67 wherein the ester group is unsaturated.
69 . The composition of claim 67 wherein the ester group is a methyl ester group.
70 . The composition of claim 67 wherein the ester group is an ethyl ester group.
71 . The composition of claim 67 wherein R F -Q g is
72 . The composition of claim 67 wherein R F -Q g is
73 . A composition comprising R F -Q g , wherein:
R F comprises at least two —CF 3 groups and a cyclic group; and
Q g is not a proton, methyl group, or methylene group.
74 . The composition of claim 73 wherein Q g comprises one or more of a halogen, a hydroxyl, a cyano, an acetate, an allyl, an epoxide, an acrylic ester, an ether, a sulfate, a thiol, a phosphate, and an amine.
75 . The composition of claim 73 wherein R F -Q g is
76 . The composition of claim 73 wherein R F -Q g is
77 . The composition of claim 73 wherein R F -Q g is
wherein X is a halogen.
78 . The composition of claim 73 wherein R F -Q g is
79 - 167 . (canceled)