Process for producing moldings
View Patent ↗The present invention is directed to a process of producing moldings by a layer-by-layer process including selectively melting regions of a respective pulverulent layer via unfocused introduction of electromagnetic energy, using a polymer powder, wherein the powder includes at least one thermoplastic random copolymer with an ISO 1133 MFR value of from 12 to 1 gm/10 min.
1. A process for producing moldings by a layer-by layer process, comprising selectively melting regions of a respective pulverulent layer via unfocused introduction of electromagnetic energy, using a polymer powder, wherein the powder comprises at least one thermoplastic random copolymer with an ISO 1133 MFR value of from 12 to 1 g/10 min.
2. The process as claimed in claim 1 , wherein the powder comprises at least one thermoplastic random copolymer with an ISO 1133 MFR value of from 10 to 1 g/10 min.
3. The process as claimed in claim 1 , wherein the powder comprises at least one thermoplastic random copolymer with an ISO 1133 MFR value of from 12 to 1 g/10 min, the selectivity being achieved via application of susceptors or of absorbers, or via masks.
4. The process as claimed in claim 1 , wherein the powder comprises at least one thermoplastic random copolymer with an ISO 1133 MFR value of from 10 to 1 g/10 min, the selectivity being achieved via application of susceptors or of absorbers, or via masks.
5. The process as claimed in claim 1 , wherein the powder comprises at least one thermoplastic random copolymer with an ISO 1133 MFR value of from 12 to 1 g/10 min, the selectivity being achieved via application of inhibitors.
6. The process as claimed in claim 1 , wherein the powder comprises at least one copolyester.
7. The process as claimed in claim 6 , wherein the powder comprises at least one copolyester containing at least one of the monomer units from the group of adipic acid, isophthalic acid, dimethyl phthalate, 1,4-butanediol, 1,6-hexanediol, and polyethylene glycol.
8. The process as claimed in claim 1 , wherein the powder comprises at least one copolyamide.
9. The process as claimed in claim 8 , wherein the powder comprises at least one copolyamide containing at least one of the units selected from the group of the lactams, the diamine/dicarboxylic acid salts, and/or the aminocarboxylic acids.
10. The process as claimed in claim 8 , wherein the powder comprises at least one copolyamide containing at least one of the units selected from the group of laurolactam, caprolactam, aminoundecanoic acid, and also containing approximately equimolar amounts of the dicarboxylic acids adipic acid, sorbic acid, azelaic acid, sebacic acid, dodecanedioic acid, brassylic acid, tetradecanedioic acid, pentadecanedioic acid, octadecanedioic acid; terephthalic acid, isophthalic acid, and of the diamines hexamethylenediamine, 2-methylpentamethylenediamine, 2,2,4-trimethylhexamethylenediamine, 2,4,4-tri-methylhexamethylenediamine, isophoronediamine, piperazine, bis(4-aminocyclohexyl)methane, or of the nylon salts formed therefrom.
11. The process as claimed in claim 8 , wherein the powder comprises at least one copolyamide containing caprolactam, laurolactam, and AH salt.
12. The process as claimed in claim 8 , wherein the powder comprises at least one copolyamide containing caprolactam, laurolactam, and DH salt.
13. The process as claimed in claim 8 , wherein the powder comprises at least one copolyamide containing caprolactam and laurolactam.
14. The process as claimed in claim 8 , wherein the powder comprises at least one copolyamide, the DIN 53727 relative solution viscosity in m-cresol being from 1.55 to 1.9.
15. The process as claimed in claim 8 , wherein the powder comprises at least one copolyamide, the DIN 53727 relative solution viscosity in m-cresol being from 1.6 to 1.7.
16. The process as claimed in claim 1 , further comprising auxiliaries and/or filler and/or pigments.
17. The process as claimed in claim 16 , comprising flow aids as auxiliary.
18. The process as claimed in claim 16 , comprising glass particles as filler.
19. The process as claimed in claim 16 , comprising metal soaps as auxiliary.
20. A process as claimed in claim 1 , further comprising processing the polymer powder at a construction chamber temperature of from 80 to 160° C.
21. A process as claimed in claim 1 , further comprising processing the polymer powder at a construction chamber temperature of from 85 to 120° C.