Oil-based suspension concentrates

1. An oil-based suspension concentrate composition comprising

at least one room-temperature-solid compound of the formula (I′)

in which

V is oxygen or N-D,

X is halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano,

W, Y and Z independently of one another are hydrogen, halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano,

A is hydrogen, in each case optionally halogen-substituted alkyl, alkoxyalkyl, saturated, optionally substituted cycloalkyl, in which optionally at least one ring atom is replaced by a heteroatom,

B is hydrogen or alkyl,

A and B together with the carbon atom to which they are attached are a saturated or unsaturated, unsubstituted or substituted ring optionally including at least, one heteroatom,

D is hydrogen or an optionally substituted alkyl, alkenyl, alkoxyalkyl, or saturated cycloalkyl, in which optionally one or more ring members are replaced by heteroatoms, or

A and D together with the atoms to which they are attached are a saturated or unsaturated ring which optionally includes at least one heteroatom and is unsubstituted or substituted in the A,D moiety,

G is hydrogen (a) or is one of the groups

in which

E is a metal ion or an ammonium ion,

L is oxygen or sulphur,

M is, oxygen or sulphur,

R 1 is in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or optionally halogen-, alkyl- or alkoxy-substituted cycloalkyl which is optionally interrupted by at least one heteroatom, or in each case optionally substituted phenyl, phenylalkyl, heteroaryl, phenoxyalkyl or hetaryloxyalkyl,

R 2 is in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or is in each case optionally substituted cycloalkyl, phenyl or benzyl,

R 3 is optionally halogen-substituted alkyl or optionally substituted phenyl,

R 4 and R 5 independently of one another are in each case optionally halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio or are in each case optionally substituted phenyl, benzyl, phenoxy or phenylthio, and

R 6 and R 7 independently of one another are hydrogen, in each case optionally halogen-substituted alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, are optionally substituted phenyl, are optionally substituted benzyl or together with the nitrogen atom to which they are attached are an optionally oxygen- or sulphur-interrupted optionally substituted ring,

at least one penetrant that is an alkanol alkoxylate of the formula (Id)

CH 3 —(CH 2 ) t —CH 2 —O—(—CH 2 —CH 2 —O—) u —H  (Id)

in which

t stands for an average value from 9 to 10.5, and

u stands for an average value from 7 to 9,

at least one vegetable oil,

at least one nonionic surfactant and/or at least one anionic surfactant, and optionally one or more additives selected from the group consisting of emulsifiers, foam inhibitors, preservatives, antioxidants, colorants and inert filler materials,

wherein,

said compound of the formula (I′) is between 5% and 30% by weight;

said penetrant is between 5% and 30% by weight,

said vegetable oil is between 20% and 55% by weight,

said surfactant is between 2.5% and 30% by weight, and

said optionally one or more additives are between 0% and 25% by weight.

2. The composition according to claim 1 , in which

V is oxygen or N-D,

W is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, chlorine, bromine or fluorine,

X is C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 4 -haloalkyl, fluorine, chlorine or bromine,

Y and Z are independently of one another hydrogen, C 1 -C 4 -alkyl, halogen, C 1 -C 4 -alkoxy or C 1 -C 4 -haloalkyl,

A is hydrogen or in each case optionally halogen-substituted C 1 -C 6 -alkyl or C 3 -C 8 -cycloalkyl,

B is hydrogen, methyl or ethyl,

A, B and the carbon atom to which they are attached are saturated C 3 -C 6 -cycloalkyl, in which optionally a ring member is replaced by oxygen or sulphur, and which is optionally mono- or disubstituted by C 1 -C 4 -alkyl, trifluoromethyl or C 1 -C 4 -alkoxy,

D is hydrogen, in each case optionally fluorine- or chlorine-substituted C 1 -C 6 -alkyl, C 3 -C 4 -alkenyl or C 3 -C 6 -cycloalkyl,

A and D are together in each case optionally methyl-substituted C 3 -C 4 -alkanediyl, in which optionally a methylene group is replaced by sulphur,

G is hydrogen (a) or is one of the groups

in which

B is a metal ion or an ammonium ion,

L is oxygen or sulphur,

M is oxygen or sulphur,

R 1 is in each case optionally halogen-substituted C 1 -C 10 -alkyl, C 2 -C 10 -alkenyl, C 1 -C 4 -alkoxy-C 1 -C 4 -alkyl, C 1 -C 4 -alkylthio-C 1 -C 4 -alkyl or optionally fluorine-, chlorine-, C 1 -C 4 -alkyl- or C 1 -C 2 -alkoxy-substituted C 3 -C 6 -cycloalkyl,

is optionally fluorine-, chlorine-, bromine-, cyano-, nitro-, C 1 -C 4 -alkyl-, C 1 -C 4 -alkoxy-, trifluoromethyl- or trifluoromethoxy-substituted phenyl,

is in each case optionally chlorine- or methyl-substituted pyridyl or thienyl,

R 2 is in each case optionally fluorine- or chlorine-substituted C 1 -C 10 -alkyl, C 2 -C 10 -alkenyl, or C 1 -C 4 -alkoxy-C 2 -C 4 -alkyl,

is optionally methyl- or methoxy-substituted C 5 -C 6 -cycloalkyl or

is in each case optionally fluorine-, chlorine-, bromine-, cyano-, nitro-, C 1 -C 4 -alkyl-, C 1 -C 4 -alkoxy-, trifluoromethyl- or trifluoromethoxy-substituted phenyl or benzyl,

R 3 is optionally fluorine-substituted C 1 -C 4 -alkyl or is optionally fluorine-, chlorine-, bromine-, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, trifluoromethyl-, trifluoromethoxy-, cyano- or nitro-substituted phenyl,

R 4 is, in each case optionally fluorine- or chlorine-substituted C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 4 -alkylamino, C 1 -C 4 -alkylthio or is in each case optionally fluorine-, chlorine-, bromine-, nitro-, cyano-, C 1 -C 4 -alkoxy-, trifluoromethoxy-, C 1 -C 4 -alkylthio-, C 1 -C 4 -haloalkylthio-, C 1 -C 4 -alkyl- or trifluoromethyl-substituted phenyl, phenoxy or phenylthio,

R 5 is C 1 -C 4 -alkoxy or C 1 -C 4 -thioalkyl,

R 6 is C 1 -C 6 -alkyl, C 3 -C 6 -cycloalkyl, C 1 -C 6 -alkoxy, C 3 -C 6 -alkenyl, or C 1 -C 4 -alkoxy-C 1 -C 4 -alkyl,

R 7 is C 1 -C 6 -alkyl, C 3 -C 6 -alkenyl or C 1 -C 4 -alkoxy-C 1 -C 4 -alkyl,

R 6 and R 7 together are an optionally methyl- or ethyl-substituted C 3 -C 6 -alkylene radical, in which optionally a carbon atom is replaced by oxygen or sulphur.

3. The composition according to claim 1 , in which

V is oxygen or N-D,

W is hydrogen, methyl, ethyl, chlorine, bromine or methoxy,

X is chlorine, bromine, methyl, ethyl, propyl, isopropyl, methoxy, ethoxy or trifluoromethyl,

Y and Z are independently of one another hydrogen, fluorine, chlorine, bromine, methyl, ethyl, propyl, isopropyl, trifluoromethyl or methoxy,

A is methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, cyclopropyl, cyclopentyl or cyclohexyl,

B is hydrogen, methyl or ethyl,

A, B and the carbon atom to which they are attached are saturated C 6 -cycloalkyl, in which optionally a ring member is replaced by oxygen, and which is optionally monosubstituted by methyl, ethyl, trifluoromethyl, methoxy, ethoxy, propoxy or butoxy,

D is hydrogen, is methyl, ethyl, propyl, isopropyl, butyl, isobutyl, allyl, cyclopropyl, cyclopentyl or cyclohexyl,

A and D are together optionally methyl-substituted C 3 -C 4 -alkanediyl,

G is hydrogen (a) or is one of the groups

in which

M is oxygen or sulphur,

R 1 is C 1 -C 8 -alkyl, C 2 -C 4 -alkenyl, methoxymethyl, ethoxymethyl, ethylthiomethyl, cyclopropyl, cyclopentyl or cyclohexyl,

is optionally fluorine-, chlorine-, bromine-, cyano-, nitro-, methyl-, ethyl-, methoxy-, trifluoromethyl- or trifluoromethoxy-substituted phenyl,

is in each case optionally chlorine- or methyl-substituted pyridyl or thienyl,

R 2 is C 1 -C 8 -alkyl, C 2 -C 4 -alkenyl, methoxyethyl, ethoxyethyl or is phenyl or benzyl,

R 6 and R 7 are independently of one another methyl, ethyl or together are a C 5 -alkylene radical in which the C 3 -methylene group is replaced by oxygen.

4. The composition according to claim 1 , in which

V is N-D,

W is hydrogen or methyl,

X is chlorine, bromine or methyl,

Y and Z are independently of one another hydrogen, chlorine, bromine or methyl,

A, B and the carbon atom to which they are attached are saturated C 6 -cycloalkyl, in which optionally a ring member is replaced by oxygen, and which is optionally monosubstituted by methyl, trifluoromethyl, methoxy, ethoxy, propoxy or butoxy,

D is hydrogen,

G is hydrogen (a) or is one of the groups

in which

M is oxygen or sulphur,

R 1 is C 1 -C 8 -alkyl, C 2 -C 4 -alkenyl, methoxymethyl, ethoxymethyl, ethylmethylthio, cyclopropyl, cyclopentyl, or cyclohexyl or

is optionally fluorine-, chlorine-, bromine-, methyl-, methoxy-, trifluoromethyl-, trifluoromethoxy-, cyano- or nitro-substituted phenyl,

is in each case optionally chlorine- or methyl-substituted pyridyl or thienyl,

R 2 is C 1 -C 8 -alkyl, C 2 -C 4 -alkenyl, methoxyethyl, ethoxyethyl, phenyl or benzyl,

R 6 and R 7 are independently of one another methyl, ethyl or together are a C 5 -alkylene radical, in which the C 3 -methylene group is replaced by oxygen.

5. The composition according to claim 1 , in which

V is N—H, and

A and B together with the carbon atom to which they are attached are a substituted six-membered ring

and the substituents W, X, Y, Z, G and R have the definitions indicated in the table

W

X

Y

Z

R

G

H

Br

5-CH 3

H

OCH 3

CO-i-C 3 H 7

H

Br

5-CH 3

H

OCH 3

CO 2 —C 2 H 5

H

CH 3

5-CH 3

H

OCH 3

H

H

CH 3

5-CH 3

H

OCH 3

CO 2 —C 2 H 5

CH 3

CH 3

3-Br

H

OCH 3

H

CH 3

CH 3

3-Cl

H

OCH 3

H

H

Br

4-CH 3

5-CH 3

OCH 3

CO-i-C 3 H 7

H

CH 3

4-Cl

5-CH 3

OCH 3

CO 2 C 2 H 5

CH 3

CH 3

3-CH 3

4-CH 3

OCH 3

H

CH 3

CH 3

3-Br

H

OC 2 H 5

CO-i-C 3 H 7

H

CH 3

4-CH 3

5-CH 3

OC 2 H 5

CO-n-C 3 H 7

H

CH 3

4-CH 3

5-CH 3

OC 2 H 5

CO-i-C 3 H 7

H

CH 3

4-CH 3

5-CH 3

OC 2 H 5

CO-c-C 3 H 5

6. A process for producing a the composition according to claim 1 , comprising mixing

at least one room-temperature-solid compound of the formula (I′),

at least one penetrant that is an alkanol alkoxylate of the formula (Id)

CH 3 —(CH 2 ) t —CH 2 —O—(—CH 2 —CH 2 —O—) u —H  (Id)

in which

t stands for an average value from 9 to 10.5, an

u stands for an average value from 7 to 9,

at least one vegetable oil,

at least one nonionic surfactant and/or at least one anionic surfactant, and optionally one or more additives selected from the group consisting of emulsifiers, foam inhibitors, preservatives, antioxidants, colorants and/or inert filler materials,

and optionally grounding the resultant suspension.

7. The composition according to claim 1 , comprising said penetrant in which

t stands for average value 10.5 and

u stands for average value 8.4.

8. The composition according to claim 1 , further comprising extenders, and/or surface-active reagents.