IP Library Granted Patent US 7,981,581
Granted Patent B2
US 7,981,581 · App. 10/591,767 · Granted Jul 19, 2011

Phthalocyanine composition and photoconductive material, electrophotographic photoreceptor cartridge, and image-forming apparatus each employing the composition

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Quick Facts
Patent No.
US 7,981,581
App. No.
10/591,767
Granted
Jul 19, 2011
Kind
B2
Abstract

A phthalocyanine composite with high sensitivity and low environmental dependence is provided. It comprises both at least one phthalocyanine compound expressed by general formula (1) and at least one phthalocyanine compound expressed by general formula (2): where, in the general formulae (1) and (2), M 1 represents at least one arbitrary atom or atomic group that is capable of binding to a phthalocyanine, M 2 represents an atom, or an atomic group containing an atom, selected from the second and subsequent periods of the periodic table and capable of binding to a phthalocyanine, M 1 and M 2 being different in kind from each other, X 1 -X 4 represent, independently of each other, a halogen atom, and a, b, c, and d represent, independently of each other, an integer between 0 and 4 and satisfy a+b+c+d≧1.

Claims (31)

1. A phthalocyanine composite comprising both at least one phthalocyanine compound expressed by general formula (1) and at least one phthalocyanine compound expressed by general formula (2), and having a eutectic-crystalline structure:

where, in the general formulae (1) and (2),

M 1 and M 2 represent, independently of and differently from each other, at least one atom or atomic group selected from the group consisting of gallium, indium and titanium, that are capable of binding to a phthalocyanine,

X 1 -X 4 represent, independently of one another, a halogen atom, and

a, b, c, and d represent, independently of each other, an integer between 0 and 4 and satisfy

a+b+c+d≧ 1.

2. A phthalocyanine composite according to claim 1 , wherein said phthalocyanine composite is produced through a mechanical process for making amorphous state.

3. The phthalocyanine composite according to claim 1 , wherein a+b+c+d=1.

4. A phthalocyanine composite comprising both at least one phthalocyanine compound expressed by general formula (3) and at least one phthalocyanine compound expressed by general formula (4), and having a eutectic-crystalline structure:

where, in the general formulae (3) and (4),

M 3 and M 4 each represent an atom selected from the 13th group of the long-form periodic table, M 3 and M 4 being atoms of the same kind,

X 5 -X 8 represent, independently of one another, a halogen atom,

Y 1 represents a monovalent bonding group capable of binding to M 3 ,

Y 2 represents a monovalent bonding group capable of binding to M 4 , at least either Y 1 or Y 2 being a halogen atom, and

e, f, g, and h represent, independently of one another, an integer between 0 and 4 and satisfy

e+f+g+h≧ 1.

5. The phthalocyanine composite according to claim 4 , wherein e+f+g+h=1.

6. A phthalocyanine composite according to claim 4 , wherein said phthalocyanine composite is produced through a mechanical process for making amorphous state.

7. A photoconductive material comprising a phthalocyanine composite according to any one of claim 1 , 2 - 4 or 6 .

8. An electrophotographic photoreceptor comprising an electroconductive substrate and a photosensitive layer formed on said substrate, wherein said photosensitive layer contains a phthalocyanine composite according to any one of claim 1 , 2 - 4 or 6 .

9. An electrophotographic photoreceptor cartridge comprising:

an electrophotographic photoreceptor according to claim 8 ; and

at least one of

a charge unit for charging said electrophotographic photoreceptor,

an exposure unit for exposing the charged electrophotographic photoreceptor to form an electrostatic latent image thereon, and

a development unit for developing the electrostatic latent image formed on the electrophotographic photoreceptor.

10. An image forming apparatus comprising:

an electrophotographic photoreceptor according to claim 8 ;

a charge unit for charging said electrophotographic photoreceptor;

an exposure unit for exposing the charged electrophotographic photoreceptor to form an electrostatic latent image thereon; and

a development unit for developing the electrostatic latent image formed on the electrophotographic photoreceptor.

Assignments (3)
CHANGE OF NAME Recorded Sep 5, 2017
From: MITSUBISHI RAYON CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043750/0834 →
MERGER Recorded Sep 4, 2017
From: MITSUBISHI CHEMICAL CORPORATION
To: MITSUBISHI RAYON CO., LTD.
Reel/Frame 043750/0207 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 29, 2007
From: WADA, MITSUO; IDA, KAZUTAKA; FUJII, AKITERU
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 019081/0546 →