Developer mixture for thermal recording materials and thermal recording materials
View Patent ↗The present invention relates to a developer mixture for a thermal recording material, which comprises a mixture of the first organic developer comprising a condensate or a condensed composition represented by the formula (I): wherein R is a lower alkyl group or an aralkyl group, n is an integer of 0 to 5, and X and Y are each a hydrogen atom, an alkyl group or an aryl group, and the second organic developer other than the first organic developer (except 2,2-bis(3-methyl-4-hydroxyphenyl)propane), a developer mixture for a thermal recording material, and a thermal recording material having a heat-coloring layer containing the developer mixture. Using the developer mixture for a thermal recording material of the present invention, a thermal recording material sufficiently satisfying the recent requirement for high sensitivity, and having superior preservation stability of color images and non-image areas can be realized.
1. A thermal recording material comprising a support and a heat-coloring layer containing a sensitizer which is at least one member selected from the group consisting of benzyl p-benzyloxybenzoate, di-p-methylbenzyl oxalate, 2-naphthylbenzyl ether, p-benzylbiphenyl, 4-biphenyl-p-tolyl ether, 1,2-di(3-methylphenoxy)ethane, 1,2-bis(phenoxymethyl)benzene and stearic acid amide formed thereon, which layer comprises a colorless or pale basic dye and a developer mixture for a thermal recording material as main components, which developer mixture comprises a mixture of a first organic developer which is a condensed composition mainly comprising a condensate represented by the formula (I):
wherein R is a tert-butyl group, X and Y are each a hydrogen atom, and n=0 (2 core condensate), and further comprising at least one kind of condensate selected from condensates of the formula (I) wherein n=1-5 (3-7 core condensates), and a second organic developer other than the first organic developer which is not 2,2-bis(3-methyl-4-hydroxyphenyl)propane, wherein the second organic developer is at least one member selected from the group consisting of 4-hydroxy-4′-isopropoxydiphenylsulfone; 4-hydroxy-4′-propoxydiphenylsulfone; benzyl p-hydroxybenzoate; bis(3-allyl-4-hydroxyphenyl)sulfone; a composition comprising 2,2′-bis[4-(4-hydroxyphenylsulfone)phenoxy]diphenylether; 2,4-bisphenolsulfone; and 4,4-bisphenolsulfone, the content of the condensate of the formula (I) wherein n=0 (2 core condensate) in the condensed composition, which is the first organic developer, is 40-90%, and the first and the second organic developers are mixed at a mixing ratio (the first organic developer: the second organic developer) of 99.9:0.1-70:30 (weight ratio).
2. The thermal recording material of claim 1 , wherein the developer mixture is obtained by dissolution mixing or melt mixing the first and the second organic developers.
3. The thermal recording material of claim 1 , wherein the content of an organic developer in the heat-coloring layer is 1-8 parts by weight per 1 part by weight of the basic dye.
4. The thermal recording material of claim 1 , wherein the second organic developer is at least one member selected from the group consisting of 4-hydroxy-4′-isopropoxydiphenylsulfone, 4-hydroxy-4′-propoxydiphenylsulfone and benzyl p-hydroxybenzoate.
5. The thermal recording material of claim 1 , wherein the content of the sensitizer in the heat-coloring layer is 0.1-5 parts by weight per 1 part by weight of the condensed composition.