Extruded polylactide foams blown with carbon dioxide
View Patent ↗This invention provides a process for extruding a PLA resin using high levels of CO 2 . Excellent quality, low density foam is produced easily and reproducibly. The foams arc capable of being heat-annealed to induce significant crystallinity, even when an ordinarily amorphous PLA resin is used.
1. A process that comprises forming a pressurized, molten mixture of a melt-processable polylactide resin containing about 5 to about 15% by weight, based on the weight of the polylactide resin, of carbon dioxide, and extruding the molten mixture at an extrusion temperature through a die to a region of reduced pressure such that the carbon dioxide expands and the polylactide resin simultaneously cools to form a stable foam, wherein the foam has least 70% closed cells and a crystallinity of about 13-24 J/g measured by differential scanning calorimetry, and wherein the polylactide resin contains at least 80% by weight polymerized lactic acid units.
2. The process of claim 1 , comprising the further step of heat treating the foam to induce crystallinity.
3. The process of claim 2 , wherein the polylactide resin contains a mixture of L- and D-enantiomers and the mixture of L- and D-enantiomers includes from about 85-96% by weight of one enantiomer and about 4-15% by weight of the other enantiomer.
4. A process that comprises forming a pressurized, molten mixture of a melt-processable polylactide resin containing 7-11% by weight, based on the weight of the polylactide resin, of carbon dioxide, and extruding the molten mixture at an extrusion temperature through a die to a region of reduced pressure such that the carbon dioxide expands and the polylactide resin simultaneously cools to form a stable foam having at least 70% closed cells, wherein the polylactide resin contains at least 80% by weight polymerized lactic acid units.
5. The process of claim 1 , wherein the extrusion temperature is from from about 70 to about 140° C.
6. The process of claim 1 wherein the PLA resin contains long-chain branching.