Cleaning and corrosion inhibition system and composition for surfaces of aluminum or colored metals and alloys thereof under alkaline conditions
View Patent ↗The present invention relates to corrosion inhibitor systems, in particular to cleaning and corrosion inhibiting compositions for surfaces of aluminum or colored metals and alloys thereof under alkaline conditions, especially in the food and pharmaceutical industries. The cleaning and corrosion inhibiting compositions comprise as a corrosion inhibitor at least one alkyleneoxy alkylphosphate di- or triester having the general formula (I) where Z is either —O-M or —O-(AO) n 2 — Alkyl wherein M is an ammonium, alkali metal or alkaline earth metal cation, Alkyl is a C 5 -C 22 alkyl or alkylaryl group, AO is a C 2-4 -alkylene oxide unit and n 1 , n 2 and n 3 each are integers from 2 to 10.
1. A process for treating metal surfaces of aluminum or colored metals and alloys thereof, the process comprising subjecting the metal surfaces to a corrosion inhibitor system consisting of
a) an alkyleneoxy-alkyl phosphate di- or triester having the general formula
where Z is either —O-M or —O-(AO) n 2 -Alkyl
wherein
M is an ammonium, alkali metal or alkaline earth metal cation,
Alkyl independent from each other, is a straight or branched, saturated or unsaturated alkyl group having from 5 to 22 carbon atoms or is an alkylaryl group wherein alkyl is as defined above and aryl is a monocyclic or bicyclic aromatic group,
AO represents an alkylene oxide having from 2 to 4 carbon atoms which may be substituted by one or more C 1-3 alkyl groups, and
n 1 , n 2 and n 3 independent from each other are an integer of from 2 to 10;
b) an alkaline agent in amount sufficient to achieve a pH of >7.0 in the global system;
c) a chelating agent;
d) an alkanolamine;
e) a nonionic surfactant;
f) water; and
g) a hydrotrope;
at a temperature from 0 to 80° C. for 10 s to 60 min,
wherein the alkyleneoxy-alkyl phosphate di- or triester of formula I is selected such that the corrosion inhibitor system reduces the corrosion rate of an aluminum surface subjected to the corrosion inhibitor system at a temperature of 60° C. for 60 min by a factor of at least 300 as compared to the aluminum surface subjected to the corrosion inhibitor system without the selected alkyleneoxy-alkyl phosphate di- or triester of formula I under the same conditions.
2. The process according to claim 1 wherein in formula (I) of component (a) AO represents ethylene oxide (EO), propylene oxide (PO) and/or butylene oxide (BO), wherein EO, PO and BO can be present in any sequence order.
3. The process according to claim 2 , wherein AO represents ethylene oxide and/or propylene oxide.
4. The process according to claim 1 wherein the alkaline agent (component (b)) is selected from the group consisting of sodium and potassium hydroxides, sodium and potassium tripolyphosphates, ammonium, sodium and potassium carbonates and/or hydrogencarbonates and amines.
5. The process according to claim 1 , wherein the chelating agent (component (c)) is selected from the group consisting of aminocarboxylic acids and salts thereof, phosphonic acids and salts thereof, gluconic acid and salts thereof and water-soluble acrylic polymers.
6. The process according to claim 5 , wherein the chelating agent is selected from the group consisting of iminodisuccinie acid (IDS), nitrilotriacetic acid (NTA), ethylenediamine tetraacetic acid (EDTA), N-hydroxyethyl-ethylenediamine triacetic acid (HEDTA), diethylonetriamine pentaacetic acid (DTPA), glutainic-N,N-diacetic acid (GLDA), aspartic-N,N-diacetic acid (ASDA), methylglcine diacetic acid (MGDA), hydroxyethyl iminodiacctic acid (HEIDA), triethylenetetremine hexaacetie acid (TTHA) and salts thereof.
7. The process according to claim 1 wherein the alkanolamine (component (d)) is diethanolamine or triethanolamine.
8. The process according to claim 1 , wherein the surfactant (component (e)) is a nonionic surfactant selected from the group consisting of ethoxylated alkylphenols, ethoxylated aliphatic alcohols, ethoxylated amines, ethoxylated etheramines, carboxylic esters, carboxylic amides, polyoxyalkyleneoxide block-copolymers and alkylated alkylethoxylates.
9. The process according to claim 1 , wherein the hydrotrope is selected from the group consisting of monofunctional and polyfunctional alcohols and glycol and glycolether compounds, and polyfunctional organic alcohols.
10. The process according to claim 1 , wherein the corrosion inhibitor system consists of
a) from 0.01 to 15 wt. % of the alkylenoxy-alkyl phosphate di- or triester of general formula (I),
b) from 0.5 to 50 wt. % of the alkaline agent the amount being sufficient to achieve a pH of >7.0 in the global system,
c) from 0.01 to 50 wt. % of the chelating agent,
d) from 0.05 to 10 wt. % of the alkanolamine,
e) from 0.1 to 98 wt. % of the nonionic surfactant,
f) water for the balance, and
g) from 0.01 to 20 wt. % of the hydrotrope.
11. The process according to claim 1 , wherein the corrosion inhibitor system consists of
a) from 0.0001 to 0.15 wt. % of the alkylenoxy-alkyl phosphate di- or triester of general formula (I),
b) from 0.005 to 0.50 wt. % of the alkaline agent, the amount being sufficient to achieve a pH of >7.0 in the global system,
c) from 0.0001 to 0.50 wt. % of the chelating agent,
d) from 0.0005 to 0.10 wt. % of the alkanolamine,
e) from 0.001 to 0.98 wt. % of the nonionic surfactant,
f) water for the balance, and
g) from 0.0001 to 0.20 wt. % of the hydrotrope.
12. The process according to claim 1 , wherein the metal is aluminum, copper, brass, zinc, or bismuth.
13. The process according to claim 1 , wherein the alkyleneoxy-alkyl phosphate di- or triester of formula I is selected such that the corrosion inhibitor system reduces the corrosion rate of an aluminum surface subjected to the corrosion inhibitor system at a temperature of 60° C. for 60 min by a factor of at least 1000 as compared to the aluminum surface subjected to the corrosion inhibitor system without the selected alkyleneoxy-alkyl phosphate di- or triester of formula I under the same conditions.
14. The process according to claim 1 , wherein the alkyleneoxy-alkyl phosphate di- or triester of formula I is an ethoxylated alkyl phosphate diester.
15. A process for treating metal surfaces of aluminum or colored metals and alloys thereof, the process comprising subjecting the metal surfaces to a corrosion inhibitor system comprising
a) at least one alkyleneoxy-alkyl phosphate di- or triester having the general formula
where Z is either —O-M or —O-(AO) n 2 -Alkyl
wherein
M is an ammonium, alkali metal or alkaline earth metal cation,
Alkyl independent from each other, is a straight or branched, saturated or unsaturated alkyl group having from 5 to 22 carbon atoms or is an alkylaryl group wherein alkyl is as defined above and aryl is a monocyclic or bicyclic aromatic group,
AO represents an alkylene oxide having from 2 to 4 carbon atoms which may be substituted by one or more C 1-3 alkyl groups, and
n 1 , n 2 and n 3 independent from each other are an integer of from 2 to 10;
b) at least one alkaline agent in an amount sufficient to achieve a pH of >7.0 in the global system,
c) optionally at least one chelating agent,
d) optionally at least one alkanolamine as an additional corrosion inhibiting agent and/or a further corrosion co-inhibitor,
e) at least one anionic surfactant, wherein the anionic surfactant is a phosphate ester, and
f) water,
at a temperature of from 0 to 80° C. for 10 s to 60 min,
wherein the alkyleneoxy-alkyl phosphate di- or triester of formula I and the anionic phosphate ester surfactant are different compounds.
16. A process for treating metal surfaces of aluminum or colored metals and alloys thereof, the process comprising subjecting the metal surfaces to a corrosion inhibitor system consisting of
a) an alkyleneoxy-alkyl phosphate di- or triester having the general formula
where Z is either —O-M or —O-(AO) n 2 -Alkyl
wherein
M is an ammonium, alkali metal or alkaline earth metal cation,
Alkyl independent from each other, is a straight or branched, saturated or unsaturated alkyl group haying from 5 to 22 carbon atoms or is an alkylaryl group wherein alkyl is as defined above and aryl is a monocyclic or bicyclic aromatic group,
AO represents an alkylene oxide having from 2 to 4 carbon atoms which may be substituted by one or more C 1-3 alkyl groups, and
n 1 , n 2 and n 3 independent from each other are an integer or from 2 to 10;
b) an alkaline agent in an amount sufficient to achieve a pH of >7.0 in the global system;
c) a chelating agent;
d) an alkanolamine;
e) a nonionic surfactant;
f) water; and
g) a hydrotrope;
at a temperature of from 0 to 80° C. for 10 s to 60 min.