Impact resistance modifier and resin composition
View Patent ↗Disclosed is a resin composition having excellent impact resistance and resistance to whitening by impact without deteriorating excellent transparency of a methacrylic resin. Specifically, an impact resistance modifier composed of a multilayered polymer having at least three layers, namely an innermost-layer polymer derived from an alkyl methacrylate, an intermediate-layer polymer derived from an alkyl acrylate and an outer-layer polymer having its Tg within the range of 20 to 80° C., wherein mass average particle diameter of the intermediate-layer polymer is 200 to 300 nm and the mass ratio of each layer is within an appropriate range, is blended with a methacrylic resin.
1. An impact resistance modifier comprising a multilayered graft copolymer, comprising:
an innermost-layer polymer (A) obtained by polymerizing monomer components comprising 100 parts by mass of a monomer mixture comprising 40 to 100% by mass of an alkyl methacrylate having an alkyl group with carbon number of 1 to 4, 0 to 60% by mass of an alkyl acrylate having an alkyl group with carbon number of 1 to 8 and 0 to 20% by mass of another copolymerizable monomer and 0.1 to 10 parts by mass of a polyfunctional monomer;
an intermediate-layer polymer (B) obtained by polymerizing monomer components comprising 100 parts by mass of a monomer mixture comprising 70 to 90% by mass of an alkyl acrylate having an alkyl group with carbon number of 1 to 8, 10 to 30% by mass of an aromatic vinyl compound and 0 to 20% by mass of another copolymerizable monomer and 1 to 3 parts by mass of a polyfunctional monomer in the presence of the innermost-layer polymer (A); and
an outer-layer polymer (C) having a Tg within the range of 20 to 80° C. and obtained by polymerizing monomer component(s) comprising 50 to 100% by mass of an alkyl methacrylate having an alkyl group with carbon number of 1 to 4, 0 to 50% by mass of an alkyl acrylate having an alkyl group with carbon number of 1 to 8 and 0 to 20% by mass of another copolymerizable monomer in the presence of a polymer which has been made up to the intermediate-layer polymer (B),
wherein mass average particle diameter of the polymer which has been made up to the intermediate-layer polymer (B) is 200 to 300 nm, wherein the mass average particle diameter is evaluated using a capillary cartridge for particle fractionation and a carrier liquid at neutral pH, the mass ratio (A)/(B) of the innermost-layer polymer (A) to the intermediate-layer polymer (B) is 10/90 to 40/60 and the proportion of the outer-layer polymer (C) is 30 to 100 parts by mass when the sum of the innermost-layer polymer (A) and the intermediate-layer polymer (B) is set as 100 parts by mass.
2. A resin composition comprising a methacrylic resin composed mainly of constitutional units of methyl methacrylate and the impact resistance modifier according to claim 1 .