IP Library Granted Patent US 7,235,287
Granted Patent B2
US 7,235,287 · App. 10/595,261 · Granted Jun 26, 2007

Biodegradable laminated sheet

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 7,235,287
App. No.
10/595,261
Granted
Jun 26, 2007
Kind
B2
Abstract

The biodegradable sheet is a laminated sheet including at least two layers. Each of the layers forming the laminated sheet is a resin composition comprising 75 to 25% by mass of a polylactic acid resin, and 25 to 75% by mass of a polyester resin having a glass transition temperature not exceeding 0 degrees C. and a melting point higher than the glass transition temperature of the polylactic acid resin, and not exceeding the melting point of the polylactic acid resin, based on 100 mass percent of the total amount of the polylactic acid resin and the polyester resin. The D-lactic acid content of the polylactic acid resin contained in one layer, and the D-lactic acid content of the polylactic acid resin in the other layer are determined to satisfy a predetermined relationship. The laminated sheet is subjected to crystallization treatment.

Claims (25)

1. A biodegradable laminated sheet comprising at least two layers, each of said two layers comprising:

a resin composition containing 75 to 25 mass percent of a polylactic acid resin, and 25 to 75 mass percent of a polyester resin having a glass transition temperature not exceeding 0 degrees C, and having a melting point higher than the glass transition temperature of said polylactic acid resin, and not exceeding the melting point of said polylactic acid resin, based on 100 mass percent of the total amount of said polylactic acid resin and said polyester resin,

wherein the content Da (%) of D-lactic acid of the polylactic acid resin contained in one of said at least two layers and the content Db (%) of D-lactic acid of the polylactic acid resin contained in the other of said at least two layers satisfy the following relations (1):

Da≦ 7 and Db−Da >3  (1)

said laminated sheet being subjected to crystallization treatment.

2. The biodegradable laminated sheet of claim 1 wherein said one of said at least two layers have a thickness of 3 to 300 micrometers.

3. The biodegradable laminated sheet of claim 1 wherein said one of said at least two layers comprises two outer layers, said other of said at least two layers being at least one layer disposed between said two outer layers.

4. An article obtained by forming the biodegradable laminated sheet of claim 1 at a temperature of not less than the melting point of the polyester resin and less than the melting point of the polylactic acid resin contained in said one of said at least two layers.

5. A method of forming an article from the biodegradable laminated sheet of claim 1 , said method comprising forming said laminated sheet at a temperature of not less than the melting point of the polyester resin and less than the melting point of the polylactic acid resin contained in said one of said at least two layers.

6. A biodegradable laminated sheet comprising at least two layers, each of said two layers comprising a resin composition containing 75 to 25 mass percent of a polylactic acid resin, and 25 to 75 mass percent of a polyester resin having a glass transition temperature not exceeding 0 degrees C., and having a melting point of not less than 80 degrees C. and not exceeding the melting point of said polylactic acid resin, based on 100 mass percent of the total amount of said polylactic acid resin and said polyester resin,

wherein the content Da (%) of D-lactic acid of the polylactic acid resin contained in one of said at least two layers and the content Db (%) of D-lactic acid of the polylactic acid resin contained in the other of said at least two layers satisfy the following relations (1):

Da≦ 7 and Db−Da >3  (1)

said laminated sheet being subjected to crystallization treatment.

7. The biodegradable laminated sheet of claim 6 wherein said one of said at least two layers have a thickness of 3 to 300 micrometers.

8. The biodegradable laminated sheet of claim 6 wherein said one of said at least two layers comprises two outer layers, said other of said at least two layers being at least one layer disposed between said two outer layers.

9. An article obtained by forming the biodegradable laminated sheet of claim 6 at a temperature of not less than the melting point of the polyester resin and less than the melting point of the polylactic acid resin contained in said one of said at least two layers.

10. A method of forming an article from the biodegradable laminated sheet of claim 6 , said method comprising forming said laminated sheet at a temperature of not less than the melting point of the polyester resin and less than the melting point of the polylactic acid resin contained in said one of said at least two layers.

11. A biodegradable laminated sheet comprising at least two layers, each of said two layers comprising a resin composition containing 75 to 25 mass percent of a polylactic acid resin, and 25 to 75 mass percent of a polyester resin having a glass transition temperature not exceeding 0 degrees C., and having a melting point higher than the glass transition temperature of said polylactic acid resin, and not exceeding the melting point of said polylactic acid resin, based on 100 mass percent of the total amount of said polylactic acid resin and said polyester resin,

wherein the content Da (%) of D-lactic acid of the polylactic acid resin contained in one of said at least two layers and the content Db (%) of D-lactic acid of the polylactic acid resin contained in the other of said at least two layers satisfy the following relations (1):

Da≦ 7 and Db−Da >3  (1)

said polylactic acid resin contained in said one of said at least two layers having a crystallinity of not less than 20% and not more than 100%, said polylactic acid resin contained in said other of said at least two layers having a crystallinity of not less than 0% and less than 20%.

12. A biodegradable laminated sheet comprising at least two layers, each of said two layers comprising a resin composition containing 75 to 25 mass percent of a polylactic acid resin, and 25 to 75 mass percent of a polyester resin having a glass transition temperature not exceeding 0 degrees C., and having a melting point of not less than 80 degrees C. and not exceeding the melting point of said polylactic acid resin, based on 100 mass percent of the total amount of said polylactic acid resin and said polyester resin,

wherein the content Da (%) of D-lactic acid of the polylactic acid resin contained in one of said at least two layers and the content Db (%) of D-lactic acid of the polylactic acid resin contained in the other of said at least two layers satisfy the following relations (1):

Da≦ 7 and Db−Da >3  (1)

said polylactic acid resin contained in said one of said at least two layers having a crystallinity of not less than 20% and not more than 100%, said polylactic acid resin contained in said other of said at least two layers having a crystallinity of not less than 0% and less than 20%.

Assignments (2)
CHANGE OF NAME Recorded Sep 5, 2017
From: MITSUBISHI RAYON CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043750/0834 →
MERGER Recorded Aug 31, 2017
From: MITSUBISHI PLASTICS, INC
To: MITSUBISHI RAYON CO., LTD.
Reel/Frame 043746/0912 →