Golf ball comprising saturated polyurethanes and methods of making the same
View Patent ↗A golf ball comprising a layer including a saturated polyurethane composition formed of a saturated prepolymer and a saturated curing agent, wherein the layer may be casted as an outer cover, formed as an intermediate layer, or both.
1. A golf ball comprising:
a core;
a layer disposed about the core forming a center; and
a cover cast onto the center, wherein the cover comprises a light stable castable reactive liquid polyurethane material comprising a saturated diisocyanate, a dimerate polyester polyol, and at least one of a saturated hydroxy-terminated curing agent, a saturated amine-terminated curing agent, or a mixture thereof.
2. The golf ball of claim 1 , wherein the saturated diisocyanate is selected from the group consisting of isophoronediisocyanate, 4,4′-dicyclohexylmethane diisocyanate, 1,6-hexamethylene diisocyanate, or a combination thereof.
3. The golf ball of claim 1 , wherein the saturated hydroxy-terminated curing agent is selected from the group consisting of ethylene glycol; diethylene glycol; polyethylene glycol; propylene glycol; 2-methyl-1,3-propanediol; 2,-methyl-1,4-butanediol; dipropylene glycol; polypropylene glycol; 1,2-butanediol; 1,3-butanediol; 1,4-butanediol; 2,3-butanediol; 2,3-dimethyl-2,3-butanediol; trimethylolpropane; cyclohexyldimethylol; triisopropanolamine; tetra-(2-hydroxypropyl)-ethylene diamine; diethylene glycol di-(aminopropyl) ether; 1,5-pentanediol; 1,6-hexanediol; 1,3-bis-(2-hydroxyethoxy) cyclohexane; 1,4-cyclohexyldimethylol; 1,3-bis-[2-(2-hydroxyethoxy) ethoxy] cyclohexane; 1,3-bis-{2-[2-(2-hydroxyethoxy) ethoxy] ethoxy} cyclohexane; trimethylolpropane; polytetramethylene ether glycol; and mixtures thereof.
4. The golf ball of claim 1 , wherein the material comprises 4,4′-dicyclohexylmethane diisocyanate, dimerate polyester polyol, and 1,4-butanediol.
5. The golf ball of claim 1 , wherein the cover has a thickness of about 0.02 inches to about 0.35 inches.
6. The golf ball of claim 1 , wherein the layer comprises saturated polyurethane.
7. The golf ball of claim 1 , wherein the cover has a yellowness index of about 12 or less after 120 hours of exposure.
8. The golf ball of claim 1 , wherein the cover has a difference in b chroma dimension is about 6 or less after 120 hours of exposure.
9. A golf ball comprising at least one layer formed from a polyurethane composition comprising:
a saturated diisocyanate;
a hydroxy-terminated dimerate polyester polyol; and a
a saturated hydroxy-terminated curing agent.
10. The polyurethane composition of claim 9 , wherein the hydroxy-terminated dimerate polyester polyol is aliphatic.
11. The polyurethane composition of claim 9 , wherein the saturated diisocyanate is selected from the group consisting of isophoronediisocyanate, 4,4′-dicyclohexylmethane diisocyanate, 1,6-hexamethylene diisocyanate, or a combination thereof, and wherein the saturated hydroxy-terminated curing agent is selected from the group consisting of ethylene glycol; diethylene glycol; polyethylene glycol; propylene glycol; 2-methyl-1,3-propanediol; 2,-methyl-1,4-butanediol; dipropylene glycol; polypropylene glycol; 1,2-butanediol; 1,3-butanediol; 1,4-butanediol; 2,3-butanediol; 2,3-dimethyl-2,3-butanediol; trimethylolpropane; cyclohexyldimethylol; triisopropanolamine; tetra-(2-hydroxypropyl)-ethylene diamine; diethylene glycol di-(aminopropyl) ether; 1,5-pentanediol; 1,6-hexanediol; 1,3-bis-(2-hydroxyethoxy) cyclohexane; 1,4-cyclohexyldimethylol; 1,3-bis-[2-(2-hydroxyethoxy) ethoxy] cyclohexane; 1,3-bis-{2-[2-(2-hydroxyethoxy) ethoxy] ethoxy} cyclohexane; trimethylolpropane; polytetramethylene ether glycol; and mixtures thereof.
12. The golf ball of claim 11 , wherein the saturated diisocyanate is 4,4′-dicyclohexylmethane diisocyanate and wherein the saturated hydroxy-terminated curing agent is 1,4-butanediol.
13. The golf ball of claim 9 , wherein the cover has a yellowness index of about 12 or less after 120 hours of exposure.
14. The golf ball of claim 13 , wherein the yellowness index is about 8 or less after 120 hours of exposure.
15. The golf ball of claim 14 , wherein the yellowness index is about 2 or less after 120 hours of exposure.
16. The golf ball of claim 9 , wherein the cover has a difference in b chroma dimension is about 6 or less after 120 hours of exposure.
17. The golf ball of claim 16 , wherein the difference in b chroma dimension is about 2 or less after 120 hours of exposure.
18. The golf ball of claim 9 , wherein the at least one layer comprises a cover of the golf ball.