IP Library Granted Patent US 6,875,814
Granted Patent B2
US 6,875,814 · App. 10/602,255 · Granted Apr 5, 2005

Process aid for melt processable polymers

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Quick Facts
Patent No.
US 6,875,814
App. No.
10/602,255
Granted
Apr 5, 2005
Kind
B2
Abstract

Extrusion processability of non-fluorinated melt-processable polymers is improved by introducing a fluoropolymer process aid by means whereby the weight average particle size of the fluoropolymer is greater than 2 microns as it reaches the extruder die entrance.

Claims (10)

1. An extrudable composition for passing through a die, said composition comprising:

A) a non-fluorinated melt processable polymer, wherein said non-fluorinated melt processable polymer is a hydrocarbon resin selected from the group consisting of i) polyethylenes, ii) polypropylene, iii) polybutene-1, iv) poly(3-methylbutene), v) poly(methylpentene), and vi) copolymers of ethylene with an alpha-olefin; and

B) 25 to 2000 parts per million by weight, based on total weight of the extrudable composition, of fluoropolymer, said fluoropolymer having a weight average particle size greater than 2 microns and less than 10 microns, as measured at a point immediately preceding the die; and wherein said composition is substantially free of interfacial agent.

2. The composition of claim 1 wherein the fluoropolymer is a fluoroelastomer.

3. The composition of claim 2 wherein the fluoroelastomer has a ML(1+10) at 121° C. up to 80.

4. The composition of claim 1 wherein the fluoropolymer is a semi-crystalline fluoropolymer.

5. The composition of claim 4 wherein the semi-crystalline fluoropolymer has a melt index (ASTM D1238, 265° C., 5 kg weight) greater than 0.5 dg/min.

6. The composition of claim 1 wherein the weight average particle size of the fluoropolymer is greater than 4 microns as measured at a point immediately preceding the die.

7. The composition of claim 6 wherein the weight average particle size of the fluoropolymer is greater then 6 microns as measured at a point immediately preceding the die.

8. The composition of claim 1 wherein said copolymers of ethylene with an alpha-olefin are selected from the group consisting of ethylene copolymers of propylene, butene-1, hexene-1, octene-1, decene-1, and octadecene.

Assignments (3)
RELEASE OF SECURITY INTEREST Recorded Apr 4, 2018
From: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: THE CHEMOURS COMPANY FC, LLC
Reel/Frame 045845/0913 →
SECURITY AGREEMENT Recorded Jun 10, 2015
From: THE CHEMOURS COMPANY FC LLC; THE CHEMOURS COMPANY TT, LLC
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 035839/0675 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 15, 2015
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: THE CHEMOURS COMPANY FC, LLC
Reel/Frame 035432/0023 →