IP Library Granted Patent US 7,168,833
Granted Patent B2
US 7,168,833 · App. 10/605,511 · Granted Jan 30, 2007

Automotive headlamps with improved beam chromaticity

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Quick Facts
Patent No.
US 7,168,833
App. No.
10/605,511
Granted
Jan 30, 2007
Kind
B2
Abstract

Lenses for lamps can improve the quality of the light emitted through lens by interacting with the light bulb. Photoluminescent dyes as well as non-photoluminescent dyes may be incorporated into a polycarbonate lens in order to shift the chromaticity of the light source. Further, design features such as grooves or protrusions may be incorporated into the lens to allow light produced by the photoluminescent material to escape the lens and be added to the emitted beam to further shift the chromaticity. The emitted beam is of a legal color and intensity as defined per the SAE J578 and SAE J1383 standards. The lighting performance may also be improved in such manner as reducing discomfort glare, increasing brightness or producing a beam that enhances road visibility at night to the human eye.

Claims (77)

1. An automotive headlamp comprising:

a housing for receiving a light source;

a light source received in the housing;

an outer lens affixed to the housing and disposed such that light from the light source received in the housing passes through the lens;

wherein the lens comprises a polycarbonate and a photoluminescent material; and

wherein the light source and the material of the lens are selected such that light emitted from the light source is modified in chromaticity as it passes through the lens such that the illuminating beam from the headlamp has an average x chromaticity coordinate of 0.345 to 0.405 and has chromaticity coordinates inside the following boundaries as defined by the CIE 1931 color model and measured using spectrophotometric methods as presented in the ASTM standard E 308-66:

a blue boundary of X=0.31

a yellow boundary of X=0.50

a green boundary of Y=0.15+0.64x

a purple boundary of Y=0.05+0.75x

a green boundary of Y=0.44

and a red boundary of Y=0.38.

2. The headlamp of claim 1 , wherein the photoluminescent material comprises an organic fluorescent dye.

3. The headlamp of claim 2 , wherein the lens material further comprises a non-fluorescent dye.

4. The headlamp of claim 3 , wherein the fluorescent dye is included at a concentration of 0.0001 to 1 weight % of fluorescent dye and the non-fluorescent dye is included at a concentration of 0.00001 to 0.1 weight % of non-fluorescent dye.

5. The headlamp of claim 3 , wherein the fluorescent dye is included at a concentration of 0.005 to 0.5 weight % of fluorescent dye and the non-fluorescent dye is included at a concentration of 0.0001 to 0.01 weight % of non-fluorescent dye.

6. The headlamp of claim 2 , wherein the fluorescent dye is selected from the group consisting of perylenes, anthracenes, benzoxazoles, stilbenes, indigoids and thioindigoids, irnidazoles, naphtalirnides, xanthenes, thioxanthenes, coumarins, rhodarnines, and (2,5 -bis[5-tert-butyl-2-benzoxazolyl]thiophene).

7. The headlamp of claim 1 , wherein the light source is selected from the group consisting of:

a high intensity gas discharge light source,

a solid state light source,

a standard halogen light source, and

a halogen infrared reflected light source.

8. The headlamp of claim 7 , wherein the light source has an average x chromaticity coordinate of greater than 0.405.

9. The headlamp of claim 7 , wherein the photoluminescent material comprises an organic fluorescent dye.

10. The headlamp of claim 9 , wherein the lens material further comprises a non-fluorescent dye.

11. The headlamp of claim 10 , wherein the fluorescent dye is included at a concentration of 0.0001 to 1 weight % of fluorescent dye and the non-fluorescent dye is included at a concentration of 0.00001 to 0.1 weight % of non-fluorescent dye.

12. The headlamp of claim 10 , wherein the fluorescent dye is included at a concentration of 0.005 to 0.5 weight % of fluorescent dye and the non-fluorescent dye is included at a concentration of 0.0001 to 0.01 weight % of non-fluorescent dye.

13. The headlamp of claim 12 , wherein the light source has an average x chromaticity coordinate of greater than 0.405.

14. The headlamp of claim 10 , wherein the fluorescent dye is included at a concentration of 0.01 to 0.25 weight % of fluorescent dye and the non-fluorescent dye is included at a concentration of 0.001 to 0.01 weight of non-fluorescent dye.

15. The headlamp of claim 14 , wherein the light source has an average x chromaticity coordinate of greater than 0.405.

16. The headlamp of claim 9 , wherein the fluorescent dye is selected from the group consisting of perylenes, anthracenes, benzoxazoles, stilbenes, indigoids and thioindigoids, imidazoles, naphtalimides, xanthenes, thioxanthenes, coumarins, rhodarnines, and (2,5-bis[5-tert-butyl-2-benzoxazolyl]thiophene).

17. The headlamp of claim 7 ,

wherein the light source is a halogen infrared reflected light source;

wherein the light source has a low beam output and an high beam output;

wherein the low beam output is greater than or equal to 980 lumens and the high beam output is greater than or equal to 1180 lumens;

wherein the headlamp has a low illuminating beam output and a high illuminating beam output; and

wherein the low illuminating beam output is greater than or equal to 43(1 lumens and the high illuminating beam output is greater than or equal to 680 lumens.

18. The headlamp of claim 17 ,

wherein the low beam output is greater than or equal to 1280 lumens and the high beam output is greater than 1500 lumens; and

wherein the low illuminating beam output is greater than or equal to 480 lumens and the high illuminating beam output is greater than or equal to 730 lumens.

19. The headlamp of claim 17 ,

wherein the low beam output is greater than or equal to 1480 lumens and the high beam output is greater than or equal to 1680 lumens; and

wherein the low illuminating beam output is greater than or equal to 530 lumens and the high illuminating beam output is greater than or equal to 780 lumens.

20. The headlamp of claim 17 , wherein the photoluminescent material comprises an organic fluorescent dye.

21. The headlamp of claim 20 , wherein the lens material further comprises a non-fluorescent dye.

22. The headlamp of claim 21 , wherein the fluorescent dye is included at a concentration of 0.0001 to 1 weight % of fluorescent dye and the non-fluorescent dye is included at a concentration of 0.00001 to 0.1 weight % of non-fluorescent dye.

23. The headlamp of claim 21 , wherein the fluorescent dye is included at a concentration of 0.005 to 0.5 weight % of fluorescent dye and the non-fluorescent dye is included at a concentration of 0.0001 to 0.01 weight % of non-fluorescent dye.

24. The headlamp of claim 21 , wherein the fluorescent dye is included at a concentration of 0.01 to 0.25 weight % of fluorescent dye and the non-fluorescent dye is included at a concentration of 0.001 to 0.01 weight % of non-fluorescent dye.

25. The headlamp of claim 20 , wherein the fluorescent dye is selected from the group consisting of perylenes, anthracenes, benzoxazoles, stilbenes, indigoids and thioindigoids, imidazoles, naphtalimides, xanthenes, thioxanthenes, coumarins, rhodamines, and (2,5-bis[5-tert-buty1-2-benzoxazoly]thiophene).

26. The headlamp of claim 1 , wherein the lens has grooves or protrusions formed on a major surface thereof, the major surface facing inwards toward the light source and the housing.

27. The headlamp of claim 26 , wherein the lens has an edge and an edge reflector, wherein the edge reflector covers at least a portion of the edge, whereby light conducted within the lens that reaches the edge and is reflected back into the lens.

28. The headlamp of claim 27 , wherein the photoluminescent material comprises an organic fluorescent dye.

29. The headlamp of claim 28 , wherein the lens material further comprises a non-fluorescent dye.

30. The headlamp of claim 29 , wherein the fluorescent dye is included at a concentration of 0.0001 to 1 weight % of fluorescent dye and the non-fluorescent dye is included at a concentration of 0.00001 to 0.1 weight % of non-fluorescent dye.

31. The headlamp of claim 29 , wherein the fluorescent dye is included at a concentration of 0.005 to 0.5 weight % of fluorescent dye and the non-fluorescent dye is included at a concentration of 0.0001 to 0.01 weight % of non-fluorescent dye.

32. The headlamp of claim 29 , wherein the fluorescent dye is included at a concentration of 0.01 and 0.25 weight % of fluorescent dye and the non-fluorescent dye is included at a concentration of 0.001 and 0.01 weight % of non-fluorescent dye.

33. The headlamp of claim 29 , wherein the fluorescent dye produces a visual effect at an edge of the lens.

34. The headlamp of claim 28 , wherein the fluorescent dye is selected from the group consisting of perylenes, anthracenes, benzoxazoles, stilbenes, indigoids and thioindigoids, imidazoles, naphtalimides, xanthenes, thioxanthenes, coumarins, rhodamines, and (2,5-bis[5-tert-butyl-2-benzoxazolyl]thiophene).

35. The headlamp of claim 1 , wherein an exterior surface of the lens is coated with a UV-coating.

36. The headlamp of claim 35 , wherein the photoluminescent material comprises an organic fluorescent dye.

37. The headlamp of claim 36 , wherein the lens material further comprises a non-fluorescent dye.

38. The head lamp of claim 37 , wherein the fluorescent dye is included at a concentration of 0.0001 to 1 weight % of fluorescent dye and the non-fluorescent dye is included at a concentration of 0.00001 to 0.1 weight % of non-fluorescent dye.

39. The head lamp of claim 37 , wherein the fluorescent dye is included at a concentration of 0.005 to 0.5 weight % of fluorescent dye and the non-fluorescent dye is included at a concentration of 0.0001 to 0.01 weight % of non-fluorescent dye.

40. The headlamp of claim 36 , wherein the fluorescent dye is selected from the group consisting of perylenes, anthracenes, benzoxazoles, stilbenes, indigoids and thioindigoids, imidazoles, naphtalimides, xanthenes, thioxanthenes, coumarins, rhodamines, and (2,5-bis[5-tert-butyl-2-benzoxazolyl]thiophene).

41. The headlamp of claim 2 , wherein the fluorescent dye has a quantum yield of 0.7 or greater.

42. The headlamp of claim 38 , wherein the fluorescent dye has a quantum yield of 0.9 or greater.

43. A method for altering chromaticity of an automotive headlamp comprising the steps of,

selecting a partial headlamp assembly comprising a light source and a housing, wherein the light source has a first chromaticity;

selecting a lens comprising a polycarbonate and a fluorescent dye; and

affixing the lens to the partial headlamp assembly thereby forming a headlamp assembly, such that light emitted from the light source passes through the lens to form an illuminating beam, wherein the composition of the lens is selected to modify the first chromaticity such that the illuminating beam has a second chromaticity that is different from the first chromaticity, and said second chromaticity has an average x chromaticity coordinate of 0.345 to 0.405 and has chromaticity coordinates inside the following boundaries as defined by the CIE 1931 color model and measured using spectrophotometric methods as presented in the ASTM standard E 308-66:

a blue boundary of X=0.31

a yellow boundary of X=0.50

a green boundary of Y=0.15 +0.64x

a purple boundary of Y=0.05 +0.75x

a green boundary of Y=0.44

and a red boundary of Y=0.38.

44. The method of claim 43 wherein the light source has an average x chromaticity coordinate greater than 0.405.

Assignments (5)
CHANGE OF NAME Recorded Jun 6, 2016
From: SABIC INNOVATIVE PLASTICS IP B.V.
To: SABIC GLOBAL TECHNOLOGIES B.V.
Reel/Frame 038883/0811 →
RELEASE OF SECURITY INTEREST Recorded Mar 17, 2014
From: CITIBANK, N.A.
To: SABIC INNOVATIVE PLASTICS IP B.V.
Reel/Frame 032459/0798 →
SECURITY AGREEMENT Recorded Aug 18, 2008
From: SABIC INNOVATIVE PLASTICS IP B.V.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 021423/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 30, 2008
From: GENERAL ELECTRIC COMPANY
To: SABIC INNOVATIVE PLASTICS IP B.V.
Reel/Frame 021311/0259 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 12, 2003
From: SCHOTTLAND, PHILIPPE; TERBURG, BART; BRYCE, DAVID S.
To: GENERAL ELECTRIC COMPANY
Reel/Frame 014190/0690 →