IP Library Granted Patent US 6,898,929
Granted Patent B2
US 6,898,929 · App. 10/606,012 · Granted May 31, 2005

Method and apparatus for supplying a reductant to an engine exhaust treatment system

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Quick Facts
Patent No.
US 6,898,929
App. No.
10/606,012
Granted
May 31, 2005
Kind
B2
Abstract

A method and apparatus for providing a vaporized reductant to an engine exhaust stream find particular utility in the regeneration of a nitrous oxide absorber in a Diesel engine exhaust treatment system. The method and apparatus are based on fueling the Diesel engine with a mixture of Diesel oil and an alcohol, such as methanol. At least a portion of the alcohol vaporizes in the fuel tank, or is forced to vaporize by passing the fuel mixture through a heat exchanger. The vapor is then stored in a canister for subsequent selective injection of the alcohol into the exhaust stream upstream of the adsorber. The alcohol then thermally decomposes to provide sufficient hydrogen and carbon monoxide to regenerate the adsorber.

Claims (42)

1. A method for providing a reductant to an engine exhaust stream of a vehicle, the method comprising:

placing a mixture into a fuel tank of the vehicle, the mixture comprising fuel normally used by the engine of the vehicle and a liquid reductant which is compatible with the fuel but of higher volatility than the fuel;

recovering vaporized reductant emitted by the liquid reductant and storing the vaporized reductant in a storage device; and

selectively injecting the reductant into the exhaust stream.

2. The method of claim 1 , wherein the vaporized reductant is recovered directly from the fuel tank.

3. The method of claim 1 , wherein the vaporized reductant is recovered by passing the mixture through a heat exchanger.

4. A method for regeneration of a nitrous oxide adsorber in a Diesel engine exhaust treatment system, the method comprising:

fueling the engine from a fuel tank of the vehicle containing a mixture of Diesel oil and an alcohol;

recovering vaporized alcohol and storing the vaporized alcohol in a storage device; and

initiating regeneration by injecting alcohol in the storage device into an exhaust stream upstream of the adsorber, whereby the alcohol thermally decomposes to produce sufficient hydrogen and carbon monoxide to regenerate the adsorber.

5. The method of claim 4 , wherein the alcohol comprises methanol.

6. The method of claim 4 , wherein the alcohol comprises ethanol.

7. The method of claim 4 , further comprising monitoring the exhaust stream at an output of the adsorber and initiating regeneration whenever a level of nitrous oxide exceeds a predetermined threshold value.

8. The method of claim 4 , further comprising:

monitoring oxygen content of the exhaust stream at an output of the adsorber and determining an amount of alcohol vapor to be injected in accordance with the oxygen content.

9. The method of claim 8 , wherein the amount of alcohol vapor is determined by controlling flow rate of injected alcohol vapor to the exhaust stream.

10. The method of claim 4 , wherein the storage device comprises a charcoal canister.

11. The method of claim 4 , wherein vaporized alcohol is recovered directly from the fuel tank.

12. The method of claim 4 , wherein vaporized alcohol is recovered by passing the mixture of Diesel oil and alcohol through a heat exchanger.

13. The method of claim 4 , wherein alcohol from the storage device is injected in vapor form into the exhaust stream.

14. The method of claim 4 , wherein alcohol from the storage device is injected in liquid form into the exhaust stream.

15. The method of claim 4 , wherein alcohol from the storage device is injected in both vapor and liquid form into the exhaust stream.

16. An arrangement for providing a reductant to an engine exhaust stream of a vehicle, the arrangement comprising:

a fuel tank containing a mixture of fuel normally used by the engine of the vehicle and a liquid reductant which is compatible with the fuel but of higher volatility than the fuel;

a storage device coupled for receipt of reductant vapor derived from the mixture; and

an injection conduit coupling the storage device to the engine exhaust stream.

17. The arrangement of claim 16 , further comprising a vapor conduit having a first end located in the fuel tank above a liquid level of the mixture and a second end coupled to the storage device.

18. The arrangement of claim 16 , further comprising a heat exchanger coupled to a fuel line extending between the engine and the fuel tank, the heat exchanger operative to vaporize at least a portion of the liquid reductant in the mixture, and a vapor conduit coupled between the heat exchanger and the storage device.

19. An arrangement for effecting regeneration of a nitrous oxide adsorber in a Diesel engine exhaust treatment system, the arrangement comprising:

a fuel tank containing a fuel mixture of Diesel oil and an alcohol;

a storage device coupled for receipt of alcohol vapor derived from the mixture; and

an alcohol injection conduit coupling the storage device to an engine exhaust stream at an inlet to the nitrous oxide adsorber.

20. The arrangement of claim 19 , further comprising a pump coupled to the storage device and operative to drive alcohol out of the storage device into the injection conduit.

21. The arrangement of claim 20 , further comprising a metering valve located in the injection conduit and operative to control flow rate therethrough.

22. The arrangement of claim 21 , further comprising an engine control unit coupled to the metering valve and the pump for selective operation thereof.

23. The arrangement of claim 22 , further comprising a nitrous oxide sensor positioned in the engine exhaust stream at an output of the nitrous oxide adsorber and having an output coupled to the engine control unit, the engine control unit operative to actuate the pump to deliver alcohol to the exhaust stream whenever a level of nitrous oxide detected by the nitrous oxide sensor exceeds a predetermined threshold value.

24. The arrangement of claim 22 , further comprising an oxygen sensor positioned in the engine exhaust stream at an output of the nitrous oxide adsorber and having an output coupled to the engine control unit, the engine control unit operative to adjust the metering valve in accordance with a level of oxygen detected by the oxygen sensor.

25. The arrangement of claim 19 , further comprising a vapor conduit having a first end located in the fuel tank above a liquid level therein and a second end coupled to the storage device.

26. The arrangement of claim 19 , further comprising a heat exchanger coupled to a fuel line extending between the Diesel engine and the fuel tank, the heat exchanger operative to vaporize at least a portion of the alcohol in the fuel mixture, and a vapor conduit coupled between the heat exchanger and the storage device.

27. The arrangement of claim 19 , wherein the alcohol comprises methanol.

28. The arrangement of claim 19 , wherein the alcohol comprises ethanol.

29. The arrangement of claim 19 , wherein the storage device comprises a charcoal canister.

Assignments (19)
RELEASE OF SECURITY INTEREST Recorded Jan 24, 2019
From: JPMORGAN CHASE BANK, N.A.
To: FCA US LLC (FORMERLY KNOWN AS CHRYSLER GROUP LLC)
Reel/Frame 048177/0356 →
RELEASE OF SECURITY INTEREST Recorded May 30, 2017
From: CITIBANK, N.A.
To: FCA US LLC (FORMERLY KNOWN AS CHRYSLER GROUP LLC)
Reel/Frame 042885/0255 →
RELEASE OF SECURITY INTEREST RELEASING SECOND-LIEN SECURITY INTEREST PREVIOUSLY RECORDED AT REEL 026426 AND FRAME 0644, REEL 026435 AND FRAME 0652, AND REEL 032384 AND FRAME 0591 Recorded Feb 11, 2016
From: CITIBANK, N.A.
To: FCA US LLC, FORMERLY KNOWN AS CHRYSLER GROUP LLC
Reel/Frame 037784/0001 →
CHANGE OF NAME Recorded Apr 30, 2015
From: CHRYSLER GROUP LLC
To: FCA US LLC
Reel/Frame 035553/0356 →
SECURITY AGREEMENT Recorded Mar 4, 2014
From: CHRYSLER GROUP LLC
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 032384/0640 →
SECURITY AGREEMENT Recorded Jun 13, 2011
From: CHRYSLER GROUP LLC
To: CITIBANK, N.A.
Reel/Frame 026435/0652 →
SECURITY AGREEMENT Recorded Jun 7, 2011
From: CHRYSLER GROUP LLC
To: CITIBANK, N.A.
Reel/Frame 026404/0123 →
RELEASE OF SECURITY INTEREST Recorded May 26, 2011
From: THE UNITED STATES DEPARTMENT OF THE TREASURY
To: CHRYSLER GROUP LLC; CHRYSLER GROUP GLOBAL ELECTRIC MOTORCARS LLC
Reel/Frame 026343/0298 →
CHANGE OF NAME Recorded Jul 7, 2009
From: NEW CARCO ACQUISITION LLC
To: CHRYSLER GROUP LLC
Reel/Frame 022919/0126 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 6, 2009
From: CHRYSLER LLC
To: NEW CARCO ACQUISITION LLC
Reel/Frame 022915/0001 →
RELEASE OF SECURITY INTEREST IN PATENT RIGHTS - SECOND PRIORITY Recorded Jul 6, 2009
From: WILMINGTON TRUST COMPANY
To: CHRYSLER LLC
Reel/Frame 022910/0740 →
SECURITY AGREEMENT Recorded Jul 6, 2009
From: NEW CARCO ACQUISITION LLC
To: THE UNITED STATES DEPARTMENT OF THE TREASURY
Reel/Frame 022915/0489 →
RELEASE OF SECURITY INTEREST IN PATENT RIGHTS - FIRST PRIORITY Recorded Jul 6, 2009
From: WILMINGTON TRUST COMPANY
To: CHRYSLER LLC
Reel/Frame 022910/0498 →
RELEASE OF SECURITY INTEREST Recorded Jul 1, 2009
From: US DEPARTMENT OF THE TREASURY
To: CHRYSLER LLC
Reel/Frame 022902/0310 →
GRANT OF SECURITY INTEREST IN PATENT RIGHTS - THIR Recorded Jan 14, 2009
From: CHRYSLER LLC
To: US DEPARTMENT OF THE TREASURY
Reel/Frame 022259/0188 →
CHANGE OF NAME Recorded Nov 13, 2008
From: DAIMLERCHRYSLER COMPANY LLC
To: CHRYSLER LLC
Reel/Frame 021826/0001 →
CHANGE OF NAME Recorded Nov 4, 2008
From: DAIMLERCHRYSLER CORPORATION
To: DAIMLERCHRYSLER COMPANY LLC
Reel/Frame 021779/0793 →
GRANT OF SECURITY INTEREST IN PATENT RIGHTS - SECOND PRIORITY Recorded Aug 30, 2007
From: CHRYSLER LLC
To: WILMINGTON TRUST COMPANY
Reel/Frame 019767/0810 →
GRANT OF SECURITY INTEREST IN PATENT RIGHTS - FIRST PRIORITY Recorded Aug 29, 2007
From: CHRYSLER LLC
To: WILMINGTON TRUST COMPANY
Reel/Frame 019773/0001 →