Preparation of polyethylene films
View Patent ↗A process for preparing polyethylene thin films is disclosed. The process comprises extruding a blend that comprises a linear low density polyethylene (LLDPE) and a high molecular weight, high density polyethylene (HMW-HDPE) or high molecular weight, medium density polyethylene (HMW-MDPE). The blend has an LLDPE/HMW-HDPE or HMW-MDPE weight ratio at least 50/50. The blend is extruded through an annular die to form a molten material tube. The molten material tube is then pulled around a flexible internal orientation device (FIOD) to form the film. The FIOD makes it possible to prepare polyethylene thin films from LLDPE-rich LLDPE/HMW-HDPE or HMW-MDPE blends on a high stalk film line. The films have increased machine-direction (MD) tears.
1. A process for preparing a thin film on a high stalk extrusion line, said process comprising:
(a) extruding a blend through an annular die to form a molten material tube, said blend comprising:
(i) a linear low density polyethylene (LLDPE) which has a density within the range of about 0.90 to about 0.93 g/cc and an MI 2 within the range of about 0.5 to about 50 dg/min; and
(ii) a high molecular weight high density polyethylene (HMW-HDPE) which has a density within the range of about 0.95 to about 0.97 g/cc and an MI 2 within the range of about 0.01 to about 0.5 dg/min;
in a weight ratio of (i)/(ii) greater than or equal to 50/50; and
(b) pulling the molten material tube around a flexible internal orientation device (FIOD) to form the film; wherein the film has a thickness of 0.5 mil or less.
2. The process of claim 1 wherein the weight ratio of (i)/(ii) is greater than or equal to 60/40.
3. The process of claim 1 wherein the weight ratio of (i)/(ii) is greater than or equal to 70/30.
4. The process of claim 1 wherein the film has a machine-direction tear of 18 grams or greater.
5. The process of claim 1 wherein the film has a machine-direction tear of 40 grams or greater.
6. A thin film produced by the process of claim 1 .
7. The film of claim 6 wherein the LLDPE is a copolymer of ethylene with an alpha-olefin selected from the group consisting of propylene, 1-butene, 1-pentene, 1-hexene, 1-octene, 4-methyl-1-pentene, and mixtures thereof.
8. The film of claim 6 wherein the LLDPE is a copolymer of ethylene with 1-hexene.
9. The film of claim 6 wherein the film has a machine-direction tear of 18 grams or greater.
10. The film of claim 6 wherein the film has a machine-direction tear 40 grams or greater.