Zinc/air cell with improved anode
View Patent ↗A method of forming an anode comprising zinc for a zinc/air cell. The method involves mixing zinc particles with binders including preferably polyvinylalcohol, surfactant and water to form a wet paste. The wet paste is compacted and molded into the near shape of the cell's anode cavity and then heated to evaporate water. A solid porous zinc mass is formed wherein the zinc particles are held bound within a network with microscopic void spaces between the zinc particles. The solid mass can be inserted into the cell's anode cavity and aqueous alkaline electrolyte, preferably comprising potassium hydroxide, then added. The solid mass absorbs the aqueous electrolyte and expands to fill the anode cavity to form the final fresh anode.
1. A method of forming an anode for a zinc/air cell having an anode cavity therein, comprising the step of:
a) forming a wet mixture comprising zinc particles, a binder comprising polyvinylalcohol and a gelling agent, and water;
a.1) inserting said wet mixture into a mold cavity;
a.2) applying pressure to said wet mixture in said mold cavity thereby compacting said wet mixture within said mold cavity;
a.3) ejecting said compacted wet mixture from said mold cavity thereby producing a molded wet mixture having a molded shape, whereupon said molded wet mixture retains its molded shape;
b) drying said molded wet mixture to evaporate water therein and thereby producing a dry solid mass comprising said zinc particles, said solid mass retaining its molded shape;
c) inserting said solid mass into the anode cavity of a zinc/air cell; and
d) adding an aqueous alkaline electrolyte to the anode cavity whereby said aqueous electrolyte is absorbed by said solid mass, said aqueous electrolyte activates said gelling agent, and thereby forms said anode.
2. The method of claim 1 wherein said solid mass is a solid porous mass comprising zinc particles.
3. The method of claim 2 wherein said solid porous mass expands as said aqueous electrolyte is absorbed therein in step (d).
4. The method of claim 1 wherein said mixture is molded into a designated shape conforming to the shape of said mold cavity prior to drying said mixture.
5. The method of claim 1 wherein the aqueous alkaline electrolyte comprises potassium hydroxide.
6. The method of claim 1 wherein said drying in step b) is effected by heating said wet mixture.
7. The method of claim 1 wherein the polyvinylalcohol has a molecular weight between about 85000 and 146000.
8. The method of claim 1 wherein said binder further comprises a crosslinked acrylic acid polymer gelling agent.
9. The method of claim 1 wherein said binder further comprises a gelling agent comprising a starch graft copolymer of polyacrylic acid and polyacrylamide.
10. The method of claim 1 wherein said mixture prior to drying further comprises indium in total amount between about 200 and 1000 ppm of the zinc.
11. The method of claim 1 wherein said mixture prior to drying further comprises a surfactant.
12. The method of claim 11 wherein said surfactant comprises an organic phosphate ester.
13. The method of claim 2 wherein said solid porous mass has the property that it is storable in ambient air.
14. The method of claim 1 wherein said wet mixture is molded in said mold cavity into the approximate shape of the anode cavity of a zinc/air cell prior to drying said mixture.
15. The method of claim 1 wherein said pressure applied to said wet mixture in step a.2 corresponds to a force of between about 10 and 300 pounds applied by a plunger to said wet mixture in said mold cavity being cylindrical and having a diameter between about 3 and 7 mm, thereby compacting said wet mixture within said mold cavity.