Alkaline cell with improved anode
View Patent ↗A method of forming an anode comprising zinc for an alkaline cell. The method involves mixing zinc particles with binders including preferably polyvinylalcohol, surfactant and water to form a wet paste. The wet paste is molded into the near shape of the cell's anode cavity and then heated to evaporate water. A solid porous zinc mass is formed having microscopic void spaces between the zinc particles. The solid mass can be inserted into the cell's anode cavity and aqueous alkaline electrolyte, preferably comprising potassium hydroxide, then added. The solid mass absorbs the aqueous electrolyte and expands to fill the anode cavity to form the final fresh anode.
1. A method of forming an anode for an alkaline cell having an anode cavity therein, comprising the step of:
a) forming a wet mixture comprising zinc particles, a binder comprising polyvinylalcohol and a gelling agent, and water;
a.1) inserting said wet mixture into a mold cavity;
a.2) applying pressure to said wet mixture in said mold cavity thereby compacting said wet mixture within said mold cavity;
a.3) ejecting said compacted wet mixture from said mold cavity thereby producing a molded wet mixture having a molded shape, whereupon said molded wet mixture retains its molded shape;
b) drying said molded wet mixture to evaporate water therein and thereby producing a dry solid mass comprising said zinc particles, said solid mass retaining its molded shape;
c) inserting said solid mass into the anode cavity of an alkaline cell; and
d) adding a fluid to the anode cavity whereby said fluid is absorbed by said solid mass, said fluid activates said gelling agent, and thereby forms said anode.
2. The method of claim 1 wherein said fluid comprises aqueous alkaline electrolyte.
3. The method of claim 1 wherein said solid mass is a solid porous mass comprising zinc particles.
4. The method of claim 3 wherein said solid porous mass expands as said fluid is absorbed therein in step (d).
5. The method of claim 1 wherein said molded mixture is at least substantially wrapped with a separator material prior to drying said mixture.
6. The method of claim 1 wherein said wet mixture is molded into a designated shape conforming to the shape of said mold cavity prior to drying said mixture.
7. The method of claim 2 wherein the aqueous alkaline electrolyte comprises potassium hydroxide.
8. The method of claim 1 wherein said drying in step b) is effected by heating said wet mixture.
9. The method of claim 1 wherein the polyvinylalcohol has a molecular weight between about 85000 and 146000.
10. The method of claim 1 wherein said binder further comprises a crosslinked acrylic acid polymer gelling agent.
11. The method of claim 1 wherein said binder further comprises a gelling agent comprising a starch graft copolymer of polyacrylic acid and polyacrylamide.
12. The method of claim 1 wherein said mixture prior to drying further comprises indium in total amount between about 200 and 1000 ppm of the zinc.
13. The method of claim 1 wherein said mixture prior to drying further comprises a surfactant.
14. The method of claim 13 wherein said surfactant comprises an organic phosphate ester.
15. The method of claim 3 wherein said solid porous mass is storable in ambient air.
16. The method of claim 1 wherein said wet mixture is molded in said mold cavity into the approximate shape of the anode cavity of an alkaline cell prior to drying said mixture.
17. The method of claim 1 wherein said pressure applied to said wet mixture in step a.2 corresponds to a force of between about 10 and 300 pounds applied by a plunger to said wet mixture in said mold cavity being cylindrical and having a diameter between about 3 and 7 mm, thereby compacting said wet mixture within said mold cavity.