IP Library Granted Patent US 6,981,666
Granted Patent B2
US 6,981,666 · App. 10/614,424 · Granted Jan 3, 2006

Titanium dioxide slurries

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Quick Facts
Patent No.
US 6,981,666
App. No.
10/614,424
Granted
Jan 3, 2006
Kind
B2
Abstract

Improved methods for producing titanium dioxide slurries. The output from a micronizer is passed through a condenser to condense the steam and form an aqueous slurry of titanium dioxide, which can in most cases then be further concentrated as desired or which can be sold or used without further concentration, instead of passing the micronizer output to apparatus for separating the TiO2 from the steam, as is currently practiced in the art. The resultant slurry from the condenser is in a further refinement preferably sent to an agitated storage tank together with dispersant and anti-settling compounds to aid in preventing settling of the titanium dioxide solids out of the slurry. To help facilitate condensation of the steam/pigment mixture sent to the condenser, a portion of the condensed slurry is in yet a further refinement pumped from the slurry storage tank to a heat exchanger. The output from the heat exchanger is then fed to the condenser to facilitate the condensing of the steam in the condenser. The temperature and volume (flow) of cooled condensate to the condenser are set to match the amount of steam and its temperature so as to ensure that substantially all of the steam and contained pigment are collected from the condenser.

Claims (15)

1. An apparatus for producing a titanium dioxide slurry, comprising:

a micronizer that produces an output comprising titanium dioxide and steam;

a condenser that receives the micronizer output and combines the micronizer output with a first titanium dioxide slurry to condense the titanium dioxide and steam mixture and produces a resulting titanium dioxide slurry.

2. An apparatus for producing a titanium dioxide slurry, comprising:

a micronizer that produces an output comprising titanium dioxide and steam;

a condenser that receives the micronizer output and combines the micronizer output with a first titanium dioxide slurry to condense the titanium dioxide and steam mixture and produces a resulting titanium dioxide slurry;

a storage tank that receives the resulting titanium dioxide slurry and recycles some of the resulting titanium dioxide slurry to the condenser.

3. An apparatus according to claim 1 , wherein the micronizer produces an output comprises from about 25 percent to about 50 percent titanium dioxide.

4. An apparatus according to claim 1 , wherein the temperature of the micronizer output is at least about 300° F.

5. An apparatus according to claim 1 , wherein the temperature of the micronizer output is at least about 400° F.

6. An apparatus according to claim 1 , wherein the temperature of the micronizer output is not more than about 600° F.

7. An apparatus according to claim 1 , wherein the temperature of the micronizer output is no more than about 500° F.

8. An apparatus according to claim 1 , wherein the resulting slurry comprises at least about 40 percent by weight of titanium dioxide.

9. An apparatus according to claim 2 , wherein the temperature of the first titanium dioxide slurry is lower than the temperature of the micronizer output.

10. An apparatus according to claim 2 , wherein the micronizer output and the first titanium dioxide slurry comprise approximately the same percentage by weight of titanium dioxide.

Assignments (15)
ASSIGNMENT OF SECURITY INTEREST IN PATENT COLLATERAL RECORDED AT REEL/FRAME 044100/0339 Recorded Mar 12, 2021
From: BANK OF AMERICA, N.A.
To: HSBC BANK USA, NATIONAL ASSOCIATION, AS THE SUCCESSOR ADMINISTRATIVE AGENT AND COLLATERAL AGENT
Reel/Frame 055578/0880 →
RELEASE OF SECURITY INTEREST Recorded Mar 12, 2021
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: TRONOX LLC
Reel/Frame 055583/0001 →
PATENT SECURITY AGREEMENT Recorded Oct 2, 2017
From: TRONOX LLC
To: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
Reel/Frame 044100/0339 →
RELEASE OF SECURITY INTEREST IN INTELLECTUAL PROPERTY COLLATERAL AT REEL/FRAME NOS. 027682/0086 AND 030047/0422 Recorded Sep 26, 2017
From: GOLDMAN SACHS BANK USA, AS COLLATERAL AGENT
To: TRONOX LLC
Reel/Frame 044018/0893 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Sep 25, 2017
From: UBS AG, STAMFORD BRANCH, AS COLLATERAL AGENT
To: TRONOX LLC; TRONOX WORLDWIDE LLC
Reel/Frame 043993/0306 →
SECURITY INTEREST Recorded Sep 25, 2017
From: TRONOX LLC
To: WELLS FARGO BANK, NATIONAL ASSOCIATION
Reel/Frame 043993/0340 →
PATENT SECURITY AGREEMENT Recorded Jul 18, 2012
From: TRONOX LLC; TRONOX WORLDWIDE LLC
To: UBS AG, STAMFORD BRANCH
Reel/Frame 028582/0669 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Jul 12, 2012
From: WELLS FARGO CAPITAL FINANCE, LLC
To: TRONOX LLC; TRONOX WORLDWIDE LLC
Reel/Frame 028535/0362 →
RELEASE OF SECURITY INTEREST Recorded Feb 9, 2012
From: GOLDMAN SACHS LENDING PARTNERS LLC
To: TRONOX LLC
Reel/Frame 027682/0064 →
SECURITY AGREEMENT Recorded Feb 9, 2012
From: TRONOX LLC
To: GOLDMAN SACHS BANK USA, AS COLLATERAL AGENT
Reel/Frame 027682/0086 →
BANKRUPTCY COURT NOTICE CONFIRMING RELEASE OF LIENS EFFECTIVE 2/14/2011 Recorded Mar 24, 2011
From: LEHMAN COMMERCIAL PAPER, INC.
To: TRONOX LLC
Reel/Frame 026010/0684 →
SECURITY AGREEMENT Recorded Feb 22, 2011
From: TRONOX LLC; TRONOX PIGMENTS (SAVANNAH) INC.
To: WELLS FARGO CAPITAL FINANCE, LLC, AS AGENT
Reel/Frame 025822/0026 →
SECURITY AGREEMENT Recorded Feb 15, 2011
From: TRONOX LLC
To: GOLDMAN SACHS LENDING PARTNERS LLC, AS COLLATERAL AGENT
Reel/Frame 025795/0130 →
SECURITY AGREEMENT Recorded Aug 21, 2008
From: TRONOX LLC F/K/A KERR-MCGEE CHEMICAL LLC
To: LEHMAN COMMERCIAL PAPER INC.
Reel/Frame 021411/0792 →
CHANGE OF NAME Recorded Aug 15, 2008
From: KERR-MCGEE CHEMICAL LLC
To: TRONOX LLC
Reel/Frame 021411/0498 →