Pigmented inkjet ink
View Patent ↗The present invention provides pigmented inks comprising self-dispersing pigment and an amino-containing compound. The addition of an amino-containing compound to the self-dispersing pigment can improve the reliability and performance of the ink in an inkjet printhead. The present invention also provides methods for making a surface modified pigment comprising associating a self-dispersing pigment with an amino-containing compound having no more than one primary amino group or one secondary amino group.
1. An inkjet ink comprising:
a self-dispersing pigment;
a basic, amine-functional-group-containing compound selected from the group consisting of cyclic compounds comprising only one secondary amine functional group in the cyclic ring structure of said compounds and having no primary amine functional group, compounds comprising only one primary amine functional group and at least one tertiary amine functional group and having no secondary amine functional group, and tetrahydrofurfuryl amine; and
an aqueous vehicle.
2. The inkjet ink of claim 1 , wherein the self-dispersing pigment is a surface oxidized carbon black.
3. The inkjet ink of claim 2 , wherein the self-dispersing carbon black has been oxidized to form carboxylate functional groups on the surface of the carbon black.
4. The inkjet ink of claim 3 , wherein the self-dispersing carbon black has an acid number of about 0.5 to about 1.5 milliequivalents of COOH/gram of carbon black.
5. The inkjet ink of claim 1 , wherein the amine-functional-group-containing compound comprises one primary amine functional group and at least one tertiary amine functional group.
6. The inkjet ink of claim 1 , wherein the amine-functional-group-containing compound has a molecular weight of less than about 600.
7. The inkjet ink of claim 1 , wherein the amine-functional-group-containing compound comprises said ring containing 5 to 8 atoms.
8. The inkjet ink of claim 1 , wherein the amine-functional-group-containing compound comprises one primary amine functional group and one tertiary amine functional group wherein the tertiary amine functional group is part of a ring containing 5 to 8 atoms.
9. The inkjet ink of claim 1 , further comprising a binder.
10. The inkjet ink of claim 1 , further comprising a pigmented dispersion comprising a pigment and a polymeric dispersant.
11. The inkjet ink of claim 10 , wherein the pigmented dispersion comprises carbon black pigment.
12. The inkjet ink of claim 1 , further comprising
a pigmented dispersion comprising a pigment and a polymeric dispersant; and
a binder.
13. The inkjet ink of claim 12 , wherein the pigmented dispersion comprises carbon black pigment.