Semi-solid casting process of aluminum alloys with a grain refiner
View Patent ↗A method for the refining of primary aluminum in hypoeutectic alloys by mixing a titanium based grain refiner into a solid/semi-solid hypoeutectic slurry is described. The method provides control of the morphology, size, and distribution of primary Al in a hypoeutectic Al—Si casting by mixing a hypoeutectic Al—Si liquid with titanium boron alloys. The invention enables grain refining techniques for SSM casting of hypoeutectic Al—Si alloys.
1. A rheocasting method for semi-solid metal casting, comprising:
providing a first alloy, the first alloy including an aluminum-silicon hypoeutectic alloy;
providing a second alloy, the second alloy including a grain refiner;
providing a reactive material;
liquefying at least one of the first alloy and the second alloy by heating to a first temperature;
combining the reactive material and the second alloy to form a mixture;
combining the first alloy and the mixture to form a combination;
generating a semi-solid metal by cooling the combination to a second temperature, wherein the semi-solid metal includes a multitude of aluminum particles having a particle size and a particle number;
injecting the semi-solid metal into a die cavity to form a cast product; and
controlling the particle size and the particle number by modulating the second temperature and an elapse time between the generation of the semi-solid metal and the injection.
2. The method of claim 1 , wherein the particle size is minimized by reducing the elapse time.
3. The method of claim 1 , wherein the particle number is maximized by reducing the elapse time.
4. The method of claim 1 , wherein the elapse time is reduced by combining the first alloy with the second alloy, the first alloy having a relatively lower temperature than the second alloy.
5. The method of claim 1 , wherein the second alloy comprises at least one of titanium, niobium, tantalum, vanadium, molybdenum, zirconium, and beryllium.
6. The method of claim 1 , wherein the reactive material comprises at least one of aluminum, boron, carbon, sulfur, phosphorus, and nitrogen.
7. The method of claim 1 , wherein the cast product comprises aluminum particles having an average diameter of less than about 70 microns.
8. The method of claim 7 , wherein the cast product comprises aluminum particles having an average diameter from about 40 microns to about 60 microns.
9. The method of claim 1 , further comprising heating both the first alloy and the second alloy.
10. The method of claim 1 , wherein the first temperature is greater than about 617° C.
11. The method of claim 10 , wherein the first temperature is about 1135° C.
12. The method of claim 1 , wherein the first temperature is about 600° C. to about 700° C.
13. The method of claim 12 , wherein the first temperature is about 612° C. to about 630° C.
14. The method of claim 1 , wherein the first temperature is about 1135° C.
15. The method of claim 1 , wherein the first alloy comprises about less than 11.7% silicon.
16. The method of claim 15 , wherein the first alloy comprises about 6% to about 8% silicon.
17. The method of claim 16 , wherein the first alloy comprises about 7% silicon.
18. The method of claim 1 , wherein the second alloy comprise about 1% to about 10% titanium.
19. The method of claim 18 , wherein the second alloy comprises about 2% to about 5% titanium.
20. The method of claim 19 , wherein the second alloy comprises about 3% to about 5% titanium.
21. The method of claim 1 , wherein the cast product comprises about less than 1% titanium.
22. The method of claim 1 , wherein the cast product comprises about 0.2% to about 0.5% titanium.
23. The method of claim 22 , wherein the cast product comprises about 0.25% to about 0.3% titanium.