IP Library Granted Patent US 7,185,663
Granted Patent B2
US 7,185,663 · App. 10/623,163 · Granted Mar 6, 2007

Methods and compositions for on-line gas turbine cleaning

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Quick Facts
Patent No.
US 7,185,663
App. No.
10/623,163
Granted
Mar 6, 2007
Kind
B2
Abstract

Methods and compositions for on-line cleaning of internal surfaces of selected sections of a hydrocarbon fuel burning gas turbine and associated heat recovery equipment, during operation. Cleaning solutions containing graphite and/or molybdenum-based particles and oil soluble corrosion inhibitors, aromatic solvents, and surfactants are selectively introduced directly into the combustion chamber (combustor) of the gas turbine, into the fuel stream, water washing system, or the combustion air system (hot gas path). The cleaning process dislodges unwanted ash deposit buildup and, thereby restores the gas turbine to rated power. When introduced into the compressor section, the particles impinge on the metal surfaces, cleaning them prior to entering the hot gas section where the process may be repeated. They may also be carried through the exhaust to additionally clean attendant heat recovery equipment, if present.

Claims (9)

1. A method for on-line cleaning of the internal surfaces of selected sections of a hydrocarbon fuel burning gas turbine, during operation, without significant loss of turbine power, comprising the steps of:

contacting the surfaces to be cleaned with a cleaning composition comprising:

expandable graphite particles ranging in size from about 0.01 to about 50,000 microns and capable of expanding up to about 200 times their initial volume when heated above a predetermined temperature;

an oil soluble magnesium carboxylate corrosion inhibitor having a minimum concentration of 30% magnesium; and

an aromatic solvent.

2. The method according to claim 1 , wherein

said cleaning composition comprises about 1.0 wt % of said expanded graphite particles;

about 83.3 wt % of said oil soluble magnesium carboxylate corrosion inhibitor; and

about 15.7 wt % of said aromatic solvent.

Assignments (3)
SECURITY INTEREST Recorded Oct 28, 2016
From: LIQUID MINERALS GROUP LTD.
To: U.S. BANK NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 040163/0537 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 25, 2016
From: PILOT CHEMICAL CORP.
To: LIQUID MINERALS GROUP LTD.
Reel/Frame 040120/0730 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 12, 2016
From: LIQUID MINERALS GROUP, INC.; ENVIROCHEM SOLUTIONS LLC; HUGHES, MARK D.; SMITH, DANIEL T.
To: PILOT CHEMICAL CORP.
Reel/Frame 039138/0557 →