High current density electropolishing in the preparation of highly smooth substrate tapes for coated conductors
View Patent ↗A continuous process of forming a highly smooth surface on a metallic tape by passing a metallic tape having an initial roughness through an acid bath contained within a polishing section of an electropolishing unit over a pre-selected period of time, and, passing a mean surface current density of at least 0.18 amperes per square centimeter through the metallic tape during the period of time the metallic tape is in the acid bath whereby the roughness of the metallic tape is reduced. Such a highly smooth metallic tape can serve as a base substrate in subsequent formation of a superconductive coated conductor.
1. A continuous process of providing a highly smooth surface to a metallic tape, the process comprising:
passing a metallic tape consisting essentially of an uncoated polycrystalline nickel alloy having an initial roughness of more than about 10 nm as a RMS roughness through an acid bath contained within a polishing section of an electropolishing unit over a pre-selected period of time; and,
passing a mean surface current density of at least 0.37 amperes per square centimeter through the metallic tape during the period of time the metallic tape is in the acid bath whereby the roughness of the metallic tape is reduced to a RMS roughness of less than about 1 nm;
depositing a layer of oriented cubic oxide material onto the metallic tape having a roughness of less than about 1 nm, wherein the in-plane alignment of the oriented cubic oxide material is less than about 7 degrees.
2. The process of claim 1 wherein the RMS roughness of the metallic tape is reduced to less than 0.5 nm.
3. The process of claim 1 wherein the acid bath consists essentially of a mixture of sulphuric acid and phosphoric acid.
4. The process of claim 1 wherein the metallic tape is in direct electrical contact with an anode in said electropolishing unit while said metallic tape is within an electrically conductive liquid throughout said electropolishing unit and within said acid bath in said polishing section, said acid bath further in contact with a cathode in said electropolishing unit so as to complete an electrical circuit.
5. The process of claim 4 wherein the anode includes a metal selected from the group consisting of titanium, niobium, tantalum, platinum, rhenium, rhodium, nickel, chromium, gold and silver.
6. The process of claim 5 wherein the acid bath consists essentially of a mixture of sulphuric acid and phosphoric acid.
7. The process of claim 1 wherein the metallic tape is in direct electrical contact with an anode in said electropolishing unit while said metallic tape is in contact with mechanical contacts as the metallic tape is passed through the acid bath so as to complete an electrical circuit.
8. The process of claim 1 wherein the metallic tape is passed through the acid bath and the acid bath provides electrical contact with the metallic tape.