Impact-modified polycarbonate blends
View Patent ↗A thermoplastic molding composition having improved flammability rating and mechanical properties is disclosed. The composition contains aromatic polycarbonate having a weight-average molecular weight M w ≧25,000 g/mol., polyalkylene terephthalate, graft (co)polymer characterized in that its grafted phase includes structural units derived from acrylate monomers, an oligomeric organic phosphoric acid ester, and an optional fluorinated polyolefin. In a preferred embodiment the graft (co)polymer is characterized in its core-shell morphology.
1. A thermoplastic molding composition comprising
A) from 40 to 90 parts by weight of aromatic poly(ester) carbonate having a weight-average molecular weight M w ≧25,000 g/mol.,
B) from 0.5 to 12 parts by weight of polyalkylene terephthalate,
C) from 1 to 20 parts by weight of graft (co)polymer consisting of from 10 to 90 wt. % (based on the weight of the graft (co)polymer) of a graft base having a glass transition temperature below 0° C., and from 90 to 10 wt. % (based on the weight of the graft (co)polymer) of polymerized vinyl monomers as a grafted phase, the vinyl monomers containing at least 20 wt. % (based on the weight of the grafted phase) of acrylate monomers,
D) an oligomeric organic phosphonic acid ester or from 2 to 20 parts by weight of an oligomeric organic phosphoric acid ester, and
E) from 0 to 1 part by weight of fluorinated polyolefin,
the sum of the parts by weight of all the components A) through E) being 100.
2. The composition according to claim 1 , wherein the aromatic poly(ester) carbonate has a {overscore (M)} w >26,000 g/mol.
3. The composition according to claim 1 , wherein the polyalkylene terephthalate has an intrinsic viscosity ≦0.8 cm 3 /g.
4. The composition according to claim 1 , wherein the graft base is at least one member selected from the group consisting of diene rubbers, copolymers of diene rubbers, EP(D)M rubbers, acrylate rubbers and silicone-acrylate composite rubbers.
5. The composition according to claim 1 , wherein the vinyl monomers are at least one member selected from the group consisting of vinyl aromatic monomers, vinyl aromatic monomers substituted on the ring, (meth)acrylic acid (C 1 –C 8 )-alkyl esters, vinyl cyanides and derivatives of unsaturated carboxylic acids.
6. The composition according to claim 1 , wherein the amount of acrylate monomer is at least 50 wt. %.
7. The composition according to claim 1 , wherein the amount of acrylate monomer is at least 75 wt. %.
8. The composition according to claim 1 , wherein component D conforms to formula (IV)
wherein
R 1 , R 2 , R 3 and R 4 independently represent C 1 - to C 8 -alkyl, or C 5 - to C 6 -cycloalkyl, C 6 - to C 20 -aryl or C 7 - to C 12 -aralkyl each optionally substituted by alkyl,
n, independently one of the others represents 0 or 1,
q is 0.5 to 30, and
X represents a mono- or poly-nuclear aromatic radical having 6 to 30 carbon atoms, or a linear or branched aliphatic radical having 2 to 30 carbon atoms, which may be OH-substituted and may contain up to 8 ether bonds.
9. The composition according to claim 8 , wherein q is 1 to 5.
10. The composition according to claim 9 , wherein q is 1 to 2.
11. The composition according to claim 8 , wherein X represents a member selected from the group consisting of
12. The composition according to claim 11 , wherein X is a derivative of hydroquinone, resorcinol or bisphenol A.
13. The composition according to claim 1 , containing
from 50 to 80 parts by weight of component A),
from 1 to 10 parts by weight of component C),
from 2 to 15 parts by weight of component D).
14. The composition according to claim 1 , containing from 5 to 10 parts by weight of component B).
15. The composition according to claim 1 , wherein Component B) is polyethylene terephthalate.
16. The composition of claim 1 wherein the graft (co)polymer has a core-shell morphology.
17. A molded article comprising the composition of claim 1 .
18. A thermoplastic molding composition comprising
A) from 40 to 90 parts by weight of aromatic poly(ester) carbonate having a weight-average molecular weight M w ≧25,000 g/mol.,
B) from 0.5 to 12 parts by weight of polyalkylene terephthalate,
C) from 1 to 20 parts by weight of graft (co)polymer consisting of from 10 to 90 wt. % (based on the weight of the graft (co)polymer) of a graft base having a glass transition temperature below 0° C., and from 90 to 10 wt. % (based on the weight of the graft (co)polymer) of polymerized vinyl monomers as a grafted phase, the vinyl monomers containing at least 20 wt. % (based on the weight of the grafted phase) of acrylate monomers,
D) from 2 to 20 parts by weight of an oligomeric organic phosphoric acid ester,
E) from 0 to 1 part by weight of fluorinated polyolefin, and
F) from 0 to 10 parts by weight of at least one additive selected from the group consisting of lubricants, mold-release agents, nucleating agents, antistatic agents, stabilisers, colorants, fillers, reinforcing agents, flameproofing agents other than component D), and flameproofing synergists,
the sum of the parts by weight of all the components A) through F) being 100.
19. A molded article comprising the composition of claim 18 .
20. The composition of claim 18 wherein the graft (co)polymer has a core-shell morphology.