Method and system for producing high-pressure hydrogen
View Patent ↗Disclosed are methods and systems for generating hydrogen gas at pressures high enough to fill a hydrogen storage cylinder for stationary and transportation applications. The hydrogen output of an electrochemical hydrogen gas generating device, a hydrogen-producing reactor, or a diluted hydrogen stream is integrated with an electrochemical hydrogen compressor operating in a high-differential-pressure mode. The compressor brings the hydrogen produced by the hydrogen generating device to the high pressure required to fill the storage cylinder.
1. A system for producing high-pressure hydrogen, comprising:
(a) a first device for generating hydrogen at a first pressure; and
(b) integrated with said first device, a second device including at least one electrochemical hydrogen compressor cell, said electrochemical hydrogen compressor cell including
an anode, wherein said anode is a gas-diffusion electrode,
a solid metallic film cathode having an inner surface and an outer surface, wherein at least one surface is roughened and/or comprises deposited or particulate material including one or more noble metals or transition metals to accelerate atomic hydrogen transport through the film, and
an ionic conductive membrane in intimate contact with and separating said anode and said cathode, wherein said ionic conductive membrane is in contact with said inner surface of said solid metallic film,
said anode capable of oxidizing hydrogen generated by said first device and said cathode capable of directly generating hydrogen atoms at said inner surface of said solid metallic film by direct reaction of water or hydrogen ions in said ionic conductive membrane with electrons to form atomic hydrogen without formation of hydrogen gas, and evolving hydrogen at a second pressure at said outer surface of said solid metallic film,
wherein the first pressure is atmospheric or moderate pressure and the second pressure is greater than the first pressure.
2. The system of claim 1 , wherein the first device is a reactor that converts a hydrogen-containing compound into a hydrogen gas-containing stream.
3. The system of claim 1 , wherein the first device is a low-pressure hydrocarbon fuel processor that produces a hydrogen gas-containing stream.
4. The system of claim 1 , wherein the first device is a low-pressure ammonia processor that produces a hydrogen gas-containing stream.
5. The system of claim 1 , wherein the first device is a fuel cell that exhausts an effluent of a not completely reacted, diluted hydrogen gas stream.
6. The system of claim 1 , further comprising a DC power generator electrically connected to the second device.
7. The system of claim 1 , further comprising a gas conditioner in fluid communication with the first device for treatment of hydrogen generated by the first device.
8. The system of claim 7 , wherein the gas conditioner is a humidifier.
9. The system of claim 1 , wherein the solid metallic film comprises palladium (Pd) or a palladium alloy.
10. The system of claim 1 , wherein at least one surface of the solid metallic film has been roughened.
11. The system of claim 1 , wherein at least one surface of the solid metallic film comprises deposited or particulate material including one or more noble metals or transition metals.
12. The system of claim 11 , wherein the deposited or particulate material includes one or more of the metals Ir, Rh, and Co.
13. A system for producing high-pressure hydrogen, comprising:
(a) a first stack of at least one electrochemical hydrogen generating cell for generating hydrogen at a first pressure, said electrochemical hydrogen generating cell including a first anode and a first cathode; and
b) integrated with said first stack, a second stack of at least one electrochemical hydrogen compressor cell, said electrochemical hydrogen compressor cell including
a second anode, wherein said second anode is a gas-diffusion electrode,
a second cathode that is a solid metallic film cathode having an inner surface and an outer surface, wherein at least one surface is roughened and/or comprises deposited or particulate material including one or more noble metals or transition metals to accelerate atomic hydrogen transport through the film,
and an ionic conductive membrane in intimate contact with and separating said second anode and said second cathode, wherein said ionic conductive membrane is in contact with said inner surface of said solid metallic film,
said second anode capable of oxidizing hydrogen generated by said first stack and said second cathode capable of directly generating hydrogen atoms at said inner surface of said solid metallic film by direct reaction of water or hydrogen ions in said ionic conductive membrane with electrons to form atomic hydrogen without formation of hydrogen gas, and evolving hydrogen at a second pressure at said outer surface of said solid metallic film,
wherein the first pressure is atmospheric or moderate pressure and the second pressure is greater than the first pressure.
14. The system of claim 13 , wherein one or both surfaces of the metallic film have been roughened.
15. The system of claim 13 , wherein one or both surfaces of the metallic film comprise deposited or particulate material including one or more noble metals or transition metals.
16. The system of claim 15 , wherein the deposited or particulate material includes one or more of the metals Ir, Rh, and Co.
17. The system of claim 13 , wherein the solid metallic film comprises palladium (Pd) or a palladium alloy.
18. The system of claim 13 , wherein the ionic conductive membrane is a solid alkaline membrane.
19. The system of claim 13 , wherein the ionic conductive membrane is a proton-exchange membrane.
20. The system of claim 13 , further comprising a DC power generator electrically connected to the second stack.
21. A system for producing high-pressure hydrogen, comprising:
(a) a first stack of at least one electrochemical hydrogen generating cell for generating hydrogen at a first pressure, said electrochemical hydrogen generating cell including
a first anode,
a first cathode, and
a proton-exchange membrane or solid alkaline membrane in intimate contact with and separating said first anode and said first cathode; and
(b) integrated with said first stack, a second stack of at least one electrochemical hydrogen compressor cell, said electrochemical hydrogen compressor cell including
a second anode, wherein said second anode is a gas-diffusion electrode,
a second cathode that is a solid metallic film cathode having an inner surface and an outer surface, wherein at least one surface is roughened and/or comprises deposited or particulate material including one or more noble metals or transition metals to accelerate atomic hydrogen transport through the film, and
an ionic conductive membrane in intimate contact with and separating said second anode and said second cathode, wherein said ionic conductive membrane is in contact with said inner surface of said solid metallic film,
said second anode capable of oxidizing hydrogen generated by said first stack and said second cathode capable of directly generating hydrogen atoms at said inner surface of said solid metallic film by direct reaction of water or hydrogen ions in said ionic conductive membrane with electrons to form atomic hydrogen without formation of hydrogen gas, and evolving hydrogen at a second pressure at said outer surface of said solid metallic film, wherein the first pressure is atmospheric or moderate pressure and the second pressure is greater than the first pressure.
22. The system of claim 21 , further comprising a DC power generator electrically connected to the second stack.
23. A method of producing high-pressure hydrogen in a system including a first device for generating hydrogen at a first pressure, and a second device including at least one electrochemical hydrogen compressor cell, said hydrogen compressor cell including a gas-diffusion anode, a solid metallic film cathode having an inner surface and an outer surface, wherein at least one surface is roughened and/or comprises deposited or particulate material including one or more noble metals or transition metals to accelerate atomic hydrogen transport through the film, and an ionic conductive membrane in intimate contact with and separating said anode and said cathode, wherein said ionic conductive membrane is in contact with said inner surface of said solid metallic film, the method comprising:
(a) operating said first device to produce hydrogen at a first pressure;
(b) feeding the hydrogen produced by said first device to said second device;
(c) generating hydrogen atoms at said inner surface of said solid metallic film by direct reaction of water or hydrogen ions in said ionic conductive membrane with electrons to form atomic hydrogen without formation of hydrogen gas;
(d) transporting the hydrogen atoms through said solid metallic film to said outer surface of said solid metallic film; and
(e) combining the hydrogen atoms at said outer surface of said solid metallic film to produce hydrogen at a second pressure,
wherein the first pressure is atmospheric or moderate pressure and the second pressure is greater than the first pressure.
24. The method of claim 23 , wherein the system further includes a gas conditioner in fluid communication with the first device,
and wherein the method further comprises treating the hydrogen produced by the first device with the gas conditioner before feeding the hydrogen to the second device.
25. The method of claim 24 , wherein the gas conditioner is a humidifier.
26. The method of claim 23 , wherein the system further includes a DC power generator electrically connected to the second device.