Water-dispersible polyester stabilized, acid-treated, fluoroalkyl compositions
View Patent ↗In this invention, an acid treated, aqueous dispersion is provided that improves the oil and water-repellency of materials. The acid-treated, aqueous dispersion comprises at least one polymer, at least one water-dispersible polyester, water, and at least one acid-generating compound; wherein the polymer comprises repeating units from at least one fluoroalkyl monomer and optionally, at least one ethylenically unsaturated monomer. Articles coated with the acid-treated, aqueous dispersion are also provided.
1. An acid-treated, aqueous dispersion comprising a polymer, at least one water-dispersible polyester, water and at least one acid-generating compound; wherein said polymer comprises repeating units from at least one fluoroalkyl monomer and optionally at least one ethylenically unsaturated monomer; wherein said fluoroalkyl monomer is a (meth)acrylate having a Rf group; and wherein the Rf group is a group having at least two hydrogen atoms of an alkyl group substituted by fluorine atoms.
2. An acid-treated, aqueous dispersion according to claim 1 wherein said acid-generating compound is selected from the group consisting of sulfuric acid, hydrochloric acid, phosphoric acid, phosphorous acid, acetic acid, hydroxy acetic acid, citric acid, sulfonic acid and their respective salts.
3. An acid-treated, aqueous dispersion according to claim 2 wherein said acid is sulfonic acid.
4. An acid-treated, aqueous dispersion according to claim 3 wherein said acid is para-toluene sulfonic acid.
5. An acid-treated, aqueous dispersion according to claim 1 wherein said acid-generating compound present in said acid-treated, aqueous dispersion ranges from about 0.01% to about 0.2% based on the weight of said acid-treated, aqueous dispersion.
6. An acid-treated, aqueous dispersion according to claim 1 wherein the carbon number of said Rf group is from 2 to about 20.
7. An acid-treated, aqueous dispersion according to claim 6 wherein the carbon number of said Rf group is from 6 to 14.
8. An acid-treated, aqueous dispersion according to claim 1 wherein the number of fluorine atoms in said Rf group is at least 60%, as represented by [(the number of fluorine atoms in the Rf group)/(the number of hydrogen atoms contained in an alkyl group having the same carbon number as the Rf group)]×100(%).
9. An acid-treated, aqueous dispersion according to claim 8 wherein the number of fluorine atoms in said Rf group is at least 80%, as represented by [(the number of fluorine atoms in the Rf group)/(the number of hydrogen atoms contained in an alkyl group having the same carbon number as the Rf group)]×100(%).
10. An acid-treated, aqueous dispersion according to claim 1 wherein said Rf group is a perfluoroalkyl group.
11. An acid-treated, aqueous dispersion according to claim 10 wherein the number of carbon atoms in said perfluoralkyl group is from 2 to about 20.
12. An acid-treated, aqueous dispersion according to claim 1 wherein the fluoroalkyl monomer is represented by the formula: Rf-Q-OCOCR═CH 2 ; wherein Q is a bivalent organic group, and R is a hydrogen atom or methyl group.
13. An acid-treated, aqueous dispersion according to claim 12 wherein Q is selected from the group consisting of —(CH2)p+q—; —(CH2)pCONH(CH2)q—; —(CH2)pOCONH(CH2)q—; —(CH2)pSO2NR′(CH2)q—; —(CH2)pNHCONH(CH2)q—; or —(CH2)pCH(OH)—(CH2)q—; wherein R′ is a hydrogen or an alkyl group, and each of p and q is an integer of at least 0, provided that p+q is an integer of from 1 to 22.
14. An acid-treated, aqueous dispersion according to claim 13 wherein Q is selected from the group consisting of —(CH2)p+q—; —(CH2)pCONH(CH2)q—; and —(CH2)pSO2NR′(CH2)q—; wherein q is an integer of at least 2; and p+q is from 2 to 6.
15. An acid-treated, aqueous dispersion according to claim 14 wherein Q is —(CH2)p+q, and wherein p+q is from 2 to 6.
16. An acid-treated, aqueous dispersion according to claim 12 wherein said fluoroalkyl monomer is selected from the group consisting of:
F(CF2)5CH2OCOCR═CH2,
F(CF2)6CH2CH2OCOCR═CH2,
H(CF2)6CH2CH2OCOCR═CH2,
F(CF2)8CH2CH2OCOCR═CH2,
i-C3F7(CF2)5CH2CH2OCOCR═CH2,
F(CF2)8SO2N(C3H7)CH2CH2OCOCR═CH2,
F(CF2)8(CH2)4OCOCR═CH2,
F(CF2)8SO2N(CH3)CH2CH2OCOCR═CH2,
F(CF2)8SO2N(C2H5)CH2CH2OCOCR═CH2 ,
F(CF2)8CONHCH2CH2OCOCR═CH2,
i-C3F7(CF2)5(CH2)3OCOCR═CH2,
i-C3F7(CF2)5CH2CH(OCOCH3)OCOCR═CH2,
i-C3F7(CF2)5CH2CH2CH(OH)CH2OCOCR═CH2,
F(CF2)9CH2CH2OCOCR═CH2, and
F(CF2)9CONHCH2CH2OCOCR═CH2; wherein R represents a hydrogen or a methyl group, and i-C3F7 represents a perfluoroisopropyl group [(CF3)2CF—].
17. An acid-treated, aqueous dispersion according to claim 16 wherein said fluoroalkyl monomer is selected from the group consisting of perfluoroalkylethyl acrylate and perfluoroalkylmethyl acrylate.
18. An acid-treated, aqueous dispersion according to claim 17 wherein said fluoroalkyl compound is perfluoroalkylethyl acrylate or perfluoroalkylmethyl acrylate; wherein the alkyl group has about 6 to about 14 carbon atoms.
19. An acid-treated, aqueous dispersion according to claim 1 wherein said ethylenically unsaturated monomer is at least one selected from the group consisting of styrenic compounds, ethylenically unsaturated compounds, nitrogen-containing compounds, vinyl chloride, and vinylidene chloride.
20. An acid-treated, aqueous dispersion according to claim 19 wherein said styrenic compound is at least one selected from the group consisting of styrene, α-methyl styrene, vinyl naphthalene, vinyl toluene, and chloromethyl styrene.
21. An acid-treated, aqueous dispersion according to claim 19 wherein said ethylenically unsaturated compound is at least one selected from the group consisting of methyl acrylate, acrylic acid, methacrylic acid, methyl methacrylate, ethyl acrylate, ethyl methacrylate, butyl acrylate, butyl methacrylate, isobutyl acrylate, isobutyl methacrylate, n-hexyl acrylate, n-hexyl methacrylate, ethylhexyl acrylate, ethylhexyl methacrylate, octyl acrylate, octyl methacrylate, isodecyl acrylate, isodecyl methacrylate, laury methacrylate, lauryl acrylate, tridecyl acrylate, tridecyl methacrylate, stearyl acrylate, stearyl methacrylate, glycidyl methacrylate, alkyl crotonates, vinyl acetate, di-n-butyl maleate, di-octylmaleate, acetoacetoxyethyl methacrylate, acetoacetoxyethyl acrylate, acetoacetoxypropyl methacrylate, acetoacetoxypropyl acrylate, diacetone acrylamide, acrylamide, methacrylamide, hydroxyethyl methacrylate, hydroxyethyl acrylate, allyl methacrylate, tetrahydrofurfuryl methacrylate, tetrahydrofurfuryl acrylate, cyclohexyl methacrylate, cyclohexyl acrylate, n-hexyl acrylate, n-hexyl methacrylate, 2-ethoxyethyl acrylate, 2-ethoxyethyl methacrylate, isodecyl methacrylate, isodecyl acrylate, 2-methoxy acrylate, 2-methoxy methacrylate, 2-(2-ethoxyethoxy) ethylacrylate, 2-phenoxyethyl acrylate, 2-phenoxyethyl methacrylate, isobornyl acrylate, isobornyl methacrylate, caprolactone acrylate, caprolactone methacrylate, polypropyleneglycol monoacrylate, polypropyleneglycol monomethacrylate, poyethyleneglycol(400) acrylate, polypropyleneglycol(400) methacrylate, benzyl acrylate, benzyl methacrylate, sodium 1-allyloxy-2-hydroylpropyl sulfonate, and acrylonitrile.
22. An acid-treated, aqueous dispersion according to claim 19 wherein said nitrogen containing compound is at least one selected from the group consisting of methacrylamide, t-butylaminoethyl methacrylate, dimethylaminoethyl methacrylate, diethylaminoethyl methacrylate, N,N-dimethylaminopropyl methacrylamide, 2-t-butylaminoethyl methacrylate, N,N-dimethylaminoethyl acrylate, 2-acrylamido-2-methylpropanesulfonic acid, N-(2-methacryloyloxy-ethyl)ethylene urea, methacrylamidoethylethylene urea.
23. An acid-treated, aqueous dispersion according to claim 19 wherein said ethylenically unsaturated monomer has up to about 18 carbon atoms.
24. An acid-treated, aqueous dispersion according to claim 23 wherein said ethylenically unsaturated monomer is at least one selected from the group consisting of 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, stearyl methacrylate, and lauryl methacrylate.
25. An acid-treated, aqueous dispersion according to claim 1 wherein the amount of fluoroalkyl monomer repeating units in said polymer ranges from about 50 to about 100 weight percent based on the total weight of monomer utilized to produce said polymer.
26. An acid-treated, aqueous dispersion according to claim 25 wherein the amount of fluoroalkyl repeating units in said polymer ranges from about 60 to about 80 weight percent based on the total weight of monomer utilized to produce said polymer.
27. An acid-treated, aqueous dispersion according to claim 1 wherein said water-dispersible polyester is a polyethylene glycol polyester.
28. An acid-treated, aqueous dispersion according to claim 27 wherein the amount of said water-dispersible polyester solids in the acid-treated, aqueous dispersion range from about 1 to about 20 based on the total weight of said acid-treated, aqueous dispersion.
29. An acid-treated, aqueous dispersion according to claim 1 wherein the amount of polymer ranges from about 10% to about 50% by weight based on the weight of the acid-treated, aqueous dispersion.
30. An acid-treated, aqueous dispersion according to claim 1 wherein the weight average molecular weight of said polymer ranges from about 3,000 to about 2,000,000 as determined by gel permeation chromatography.
31. An acid-treated, aqueous dispersion according to claim 1 further comprising at least one compound selected from the group consisting of other water repellents and oil repellents, anti-fungus agents, flame retardants, antistatic agents, crease-proofing agents, antimigrants, defoamers, binders, and other antifouling agents.
32. An acid-treated, aqueous dispersion comprising at least one polymer, water, at least one nonionic water-dispersible polyester, at least one internal crosslinking agent, at least one external crosslinking agent, at least one reactive surfactant, and a chain transfer agent; wherein said polymer comprises the repeating units derived from at least one fluoroalkyl monomer and at least one ethylenically unsaturated monomer; wherein said ethylenically unsaturated monomer has up to 18 carbon atoms.
33. An acid-treated, aqueous dispersion according to claim 32 wherein the amount of said polymer ranges from about 10% to about 50% by weight based on the weight of the acid-treated, aqueous dispersion, wherein the amount of said water-dispersible polyester solids range from about 1% to about 20% based on the weight of the acid-treated, aqueous dispersion, wherein the amount of said internal crosslinking agent ranges from about 0.1% to about 5% by weight based on the total weight of monomer, wherein the amount of said external crosslinking agent ranges from about 0.1% to about 5% by weight based on the total weight of monomer; wherein the amount of said chain transfer agent ranges from about 0.1 to about 1% by weight based on the total weight of monomer.
34. An acid-treated, aqueous dispersion comprising a polymer, water, polyethylene glycol polyester, n-methyol acrylamide, diallylmaleate, n-dodecylmercaptan, and polyoxyethylene alkyl propenylphenyl ether sulfate; wherein said polymer comprises repeating units derived from a mixed fluoroacrylate monomer stream and lauryl methacrylate; and wherein said mixed fluoroacrylate monomer stream comprises 2-(perfluoroallkyl)ethyl acrylate.
35. An acid-treated, aqueous dispersion according to claim 34 wherein the amount of said polymer ranges from about 10% to about 50% by weight based on the weight of the acid-treated, aqueous dispersion, wherein the amount of polyethylene glycol polyester solids range from about 1% to about 20% based on the weight of the acid-treated, aqueous dispersion, wherein the amount of n-methyol acrylamide ranges from about 0.1% to about 5% by weight based on the total weight of monomer, wherein the amount of diallylmaleate ranges from about 0.1% to about 5% by weight based on the total weight of monomer; wherein the amount of n-dodecylmercaptan ranges from about 0.1 to about 1% by weight based on the total weight of monomer.
36. A substrate coated with said acid-treated, aqueous dispersion of claim 1 .
37. A substrate according to claim 36 wherein said substrate is selected from the group consisting of a yarn, thread, fiber, fabric, paper material, and carpet.
38. A substrate coated with said acid-treated, aqueous dispersion of claim 32 .
39. A fabric coated with said acid-treated, aqueous dispersion of claim 1 .