IP Library Granted Patent US 7,097,771
Granted Patent B2
US 7,097,771 · App. 10/640,364 · Granted Aug 29, 2006

In-tank time release ion exchange resin containing a fuel additive

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Quick Facts
Patent No.
US 7,097,771
App. No.
10/640,364
Granted
Aug 29, 2006
Kind
B2
Abstract

The invention provides a device containing an ion-exchange resin to which is chemically bound a fuel additive material which will gradually be released from the resin into a fuel in which the device is placed.

Claims (17)

1. A device for delivering at least one fuel additive to a fuel upon immersion in the fuel, said device comprising an ion-exchange resin having an equilibrium constant whereby ion exchange occurs in response to chemical equilibrium forces sufficient to effectuate an exchange, and to which a fuel additive is reversibly bound by a chemical interaction, wherein the ion-exchange resin is selected from the group consisting of anionic exchange resins and cationic exchange resins having acidic or basic groups located on the resin, and wherein the fuel additive is at least partially removed from the ion-exchange resin in exchange for a component in the fuel which reversibly binds to the ion-exchange resin, and wherein the fuel additive is selected from the group consisting of lubricity additives, combustion improvers, cold flow improvers, dehazers, demulsifiers, cetane improvers, antioxidants, scavengers, pollution suppressants, manganese tricarbonyl additives, isostearic imidazoline, NOx/SOx hydrocarbon emission reducers, and deposit formation reducers and preventers.

2. The device of claim 1 , wherein the fuel is selected from the group consisting of gasoline, middle distillate fuel, diesel, bio diesel, kerosene, and mixture thereof or precursors thereof.

3. The device of claim 1 , wherein the ion-exchange resin is selected from the group consisting of anionic exchange resins.

4. The device of claim 1 , wherein the ion-exchange resin is selected from the group consisting of cationic exchange resins.

5. The device of claim 1 , wherein the fuel additive is at least partially removed from the ion-exchange resin through reversible exchange with a contaminant in the fuel.

6. The device of claim 5 , wherein the contaminant in the fuel is an impurity.

7. The device of claim 1 , wherein the fuel additive is selected from the group consisting of lubricity additives, combustion improvers, detergents, dispersants, cold flow improvers, dehazers, demulsifiers, cetane improvers, antioxidants, scavengers, and pollution suppressants.

8. The device of claim 1 , wherein the fuel additive comprises a manganese-containing compound.

9. The device of claim 1 , wherein the device further comprises a permeable membrane through which fuel can permeate into the device and the fuel additive can permeate out of the device.

10. A machine having an engine, said machine comprising the device of claim 1 .

11. A device for supplying an additive to a fuel and adapted to release the fuel additive into said fuel at a controlled rate upon immersion of the device in the fuel, said device comprising:

a fuel-permeable housing assembly defining a chamber; and

an ion-exchange resin having an equilibrium constant whereby ion exchange occurs in response to chemical equilibrium forces sufficient to effectuate an exchange, disposed within said chamber to which a fuel additive is reversibly bound by a chemical interaction, wherein the ion-exchange resin is selected from the group consisting of anionic exchange resins and cationic exchange resins having acidic or basic groups located on the resin, and wherein the fuel additive is at least partially removed from the ion-exchange resin in exchange for a component in the fuel which reversibly binds to the ion-exchange resin, and wherein the fuel additive is selected from the group consisting of lubricity additives, combustion improvers, cold flow improvers, dehazers, demulsifiers, cetane improvers, antioxidants, scavengers, pollution suppressants, manganese tricarbonyl additives, isostearic imidazoline, NOx/SOx hydrocarbon emission reducers, and deposit formation reducers and preventers.

12. A method for supplying a fuel additive to a fuel comprising:

immersing in a fuel an ion-exchange resin having an equilibrium constant whereby ion exchange occurs in response to chemical equilibrium forces sufficient to effectuate an exchange, selected from the group consisting of anionic exchange resins and cationic exchange resins having acidic or basic groups located on the resin to which is reversibly bound a fuel additive; chemically displacing the fuel additive from the ion-exchange resin in exchange for a component in the fuel which reversibly binds to the ion-exchange resin, whereby the fuel additive is released into the fuel, and wherein the fuel additive is selected from the group consisting of lubricity additives, combustion improvers, cold flow improvers, dehazers, demulsifiers, cetane improvers, antioxidants, scavengers, pollution suppressants, manganese tricarbonyl additives, isostearic imidazoline, NOx/SOx hydrocarbon emission reducers, and deposit formation reducers and preventers.

13. A system for supplying an additive to a fuel and adapted to release the fuel additive into said fuel at a controlled rate, said system comprising:

an ion-exchange resin having an equilibrium constant whereby ion exchange occurs in response to chemical equilibrium forces sufficient to effectuate an exchange, to which a fuel additive is reversibly bound by a chemical interaction, wherein the ion-exchange resin is selected from the group consisting of anionic exchange resins and cationic exchange resins having acidic or basic groups located on the resin, and wherein the fuel additive is at least partially removed from the ion-exchange resin in exchange for a component in the fuel which reversibly binds to the ion-exchange resin, and wherein the fuel additive is selected from the group consisting of lubricity additives, combustion improvers, cold flow improvers, dehazers, demulsifiers, cetane improvers, antioxidants, scavengers, pollution suppressants, manganese tricarbonyl additives, isostearic imidazoline, NOx/SOx hydrocarbon emission reducers, and deposit formation reducers and preventers.

Assignments (5)
RELEASE OF SECURITY INTEREST Recorded Aug 5, 2011
From: SUNTRUST BANK
To: AFTON CHEMICAL CORPORATION
Reel/Frame 026707/0563 →
SECURITY AGREEMENT Recorded Feb 14, 2007
From: AFTON CHEMICAL CORPORATION
To: SUNTRUST BANK
Reel/Frame 018883/0865 →
CHANGE OF NAME Recorded Nov 1, 2004
From: ETHYL PETROLEUM ADDITIVES, INC.
To: AFTON CHEMICAL CORPORATION
Reel/Frame 015918/0557 →
SECURITY AGREEMENT Recorded Jun 24, 2004
From: ETHYL PETROLEUM ADDITIVES, INC.
To: SUNTRUST BANK, AS ADMINISTRATIVE AGENT
Reel/Frame 014782/0317 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 13, 2003
From: COLUCCI, WILLIAM J.
To: ETHYL PETROLEUM ADDITIVES, INC.
Reel/Frame 014399/0678 →