IP Library Granted Patent US 7,244,416
Granted Patent B2
US 7,244,416 · App. 10/645,253 · Granted Jul 17, 2007

Stabilized photoprotective composition

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 7,244,416
App. No.
10/645,253
Granted
Jul 17, 2007
Kind
B2
Abstract

Sunscreen compositions contain the active ingredients avobenzone, zinc oxide and phenylbenzimidazole sulfonic acid. The phenylbenzimidazole sulfonic acid protects avobenzone against photodegradation.

Claims (14)

1. A sunscreen composition comprising avobenzone, zinc oxide in an amount from about 6 to about 25 weight percent and sufficient phenylbenzimidazole sulfonic acid to stabilize the avobenzone against photodegradation, wherein the composition does not contain a diester or polyester of a naphthalene dicarboxylic acid.

2. The composition of claim 1 , wherein the concentration of avobenzone is about 1 to about 3 weight percent, and the concentration of phenylbenzimidazole sulfonic acid is about 0.5 to about 4 weight percent.

3. A method for protecting the skin against ultraviolet radiation, comprising applying to the skin an effective amount of the composition of claim 1 .

4. A method for protecting the skin against ultraviolet radiation, comprising applying to the skin an effective amount of the composition of claim 2 .

5. The composition of claim 1 , wherein the concentration of zinc oxide is about 10 weight percent.

6. The composition of claim 1 , wherein the concentration of phenylbenzimidazole sulfonic acid is about 1 weight percent.

7. The composition of claim 1 , which is in the form of an emulsion.

8. The composition of claim 7 , wherein the emulsion is an oil-in-water emulsion.

9. A method for increasing the SPE value of a sunscreen composition comprising avobenzone and zinc oxide, wherein zinc oxide is present in the composition in an amount of about 6 to about 25 weight percent, the method comprising adding to the composition an amount of phenylbenzimidazole sulfonic acid sufficient to photostabilize avobenzone, thereby increasing the SPF value, wherein the composition does not contain a diester or polyester of a naphthalene dicarboxylic acid.

10. The method of claim 9 wherein zinc oxide is present in the composition in an amount of about 10 weight percent.

11. The method of claim 9 wherein the amount of phenylbenzimidazole sulfonic acid is about 1 weight percent.

12. A method for improving the photostability of avobenzone in a composition comprising avobenzone and zinc oxide, wherein zinc oxide is present in the composition in an amount of about 6 to about 25 weight percent, the method comprising adding to the composition an amount of phenylbenzimidazole sulfonic acid sufficient to photostabilize avobenzone, wherein the composition does not contain a diester or polyester of a naplithalene dicarboxylic acid.

13. The method of claim 10 wherein zinc oxide is present in the composition in an amount of about 10 weight percent.

14. The method of claim 10 wherein the amount of phenylbenzimidazole sulfonic acid is about 1 weight percent.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 23, 2019
From: BAYER HEALTHCARE LLC
To: BEIERSDORF AG
Reel/Frame 050797/0698 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 29, 2019
From: COPPERTONE LLC
To: BAYER HELTHCARE LLC
Reel/Frame 048741/0344 →
CHANGE OF NAME Recorded Mar 20, 2019
From: BAYER CONSUMER CARE HOLDINGS LLC
To: COPPERTONE LLC
Reel/Frame 048650/0536 →
CHANGE OF NAME Recorded Mar 19, 2019
From: MSD CONSUMER CARE HOLDINGS LLC
To: BAYER CONSUMER CARE HOLDINGS LLC
Reel/Frame 048638/0753 →