Multicolor image forming material and method of multicolor image formation
View Patent ↗A multicolor image forming material comprising: an image receiving sheet comprising an image receiving layer; and at least five heat transfer sheets different in color each comprising a substrate, a light-heat conversion layer and an image forming layer, each of the heat transfer sheets being adapted to be superposed on the image receiving sheet with the image forming layer facing the image receiving layer and irradiated with laser light to transfer the irradiated area of the image forming layer to the image receiving layer to record an image on the image receiving sheet, wherein an area of the recording has a size of 515 mm by 728 mm or larger, the image forming layer of at least one of the heat transfer sheets has a thickness of 0.6 μm or greater, and the at least one of the heat transfer sheets has an adhesive strength of 8 g/cm or higher between the light-heat conversion layer and the image forming layer in a non-irradiated area thereof.
1. A multicolor image forming system comprising:
an image receiving sheet comprising an image receiving layer; and
at least five heat transfer sheets different in color each comprising a substrate, a light-heat conversion layer and an image forming layer, each of the heat transfer sheets being adapted to be superposed on the image receiving sheet with the image forming layer facing the image receiving layer and irradiated with laser light to transfer the irradiated area of the image forming layer to the image receiving layer to record an image on the image receiving sheet,
wherein
an area of the recording has a size of 515 mm by 728 mm or larger,
the image forming layer of at least one of the heat transfer sheets has a thickness of 0.6 μm or greater, and
the at least one of the heat transfer sheets has an adhesive strength of 8 g/cm or higher between the light-heat conversion layer and the image forming layer in a non-irradiated area thereof.
2. The multicolor image forming system according to claim 1 , wherein at least one of the heat transfer sheets comprises a pigment and a pigment dispersant in the image forming layer thereof, a proportion of the pigment dispersant that is not adsorbed on the pigment being 2.0% by weight or less based on a total solids content of the image forming layer.
3. The multicolor image forming system according to claim 1 , wherein at least one of the heat transfer sheets comprises a pigment and a pigment dispersant in the image forming layer thereof, a proportion of the pigment dispersant that is not adsorbed on the pigment being 1.0% by weight or less based on a total solids content of the image forming layer.
4. The multicolor image forming system according to claim 2 , wherein the pigment dispersant is selected from the group consisting of a polymeric dispersant, a phosphoric ester compound, and a copper phthalocyanine sulfonic acid compound, the polymeric dispersant being a copolymer comprising (a) (C 2 H 5 ) 2 N—(CH 2 ) z —O— wherein z is 2 or 3, (b) ethylene glycol, and (c) propylene glycol at an (a):(b):(c) molar ratio of 1:10 to 20:25 to 40 or a polyblend containing the copolymer.
5. The multicolor image forming system according to claim 1 , wherein the image forming layer of at least one of the heat transfer sheets has an optical density to thickness ratio of 1.6 or higher, the thickness being expressed in micrometers and the optical density being measured at a wavelength of 808 nm.
6. The multicolor image forming system according to claim 1 , wherein the image forming layer of at least one of the heat transfer sheets has an optical density to thickness ratio of 1.8 or higher, the thickness being expressed in micrometers and the optical density being measured at a wavelength of 808 nm.
7. The multicolor image forming system according to claim 1 , wherein the image forming layer of at least one of the heat transfer sheets has an optical density to thickness ratio of 2.50 or higher, the thickness being expressed in micrometers and the optical density being measured at a wavelength of 808 nm.
8. The multicolor image forming system according to claim 1 , which has a resolution of 2400 dpi or higher.
9. The multicolor image forming system according to claim 1 , which has a resolution of 2600 dpi or higher.
10. The multicolor image forming system according to claim 1 , wherein the image forming layer of each of the heat transfer sheets and the image receiving layer of the image receiving sheet each have a water contact angle of 7.0 to 120.0°.
11. The multicolor image forming system according to claim 1 , wherein the image forming layer of each of the heat transfer sheets and the image receiving layer of the image receiving sheet each have a water contact angle of 30.0 to 100.0°.
12. A method for forming a multicolor image comprising the steps of:
superposing each of at least five heat transfer sheets according to claim 1 on an image receiving sheet according to claim 1 with the image forming layer of the heat transfer sheet facing the image receiving layer of the image receiving sheet;
imagewise irradiating the superposed heat transfer sheet with laser light; and
transferring the irradiated area of the image forming layer to the image receiving layer of the image receiving sheet in the form of a thin film to record an image.