Low viscosity filler composition of boron nitride particles of spherical geometry and process
View Patent ↗A low viscosity filler boron nitride agglomerate particles having a generally spherical shape bound together by an organic binder and to a process for producing a BN powder composition of spherically shaped boron nitride agglomerated particles having a treated surface layer which controls its viscosity.
1. A composition consisting essentially of:
spherical agglomerated boron nitride particles comprising irregular shaped boron nitride particles bound together by an organic binder in a generally spherical geometry, the spherical agglomerated particles having an average diameter of about 10 microns or greater, a tap density of from about 0.287 to about 0.631 g/cc, and a surface layer of the organic binder and/or decomposition product thereof.
2. A composition as defined in claim 1 , wherein said organic binder is selected from the group consisting of an acrylic and an acetate.
3. A composition as defined in claim 1 , wherein the molar ratio of said organic binder to said boron nitride is about 0.00170-0.008.
4. A composition as defined in claim 1 , wherein the concentration of said organic binder in said slurry is about 1.8 wt. % or greater.
5. A composition as defined in claim 1 , wherein said organic binder is selected from the group consisting of nickel acetate, aluminum acetate and titanium acetate and monoethylenically unsaturated acid free monomers, consisting of C 1 -C 4 alkyl esters of acrylic or methacrylic acids, hydroxylalkyl esters of acrylic or methacrylic acids, acrylamides and alkyl-substituted acrylamides.
6. A low viscosity boron nitride filled polymer composition comprising:
a polymer selected from the group consisting of a polyester, epoxy and polyamide; and
spherical particles of agglomerated boron nitride having a tap density of from about 0.287 to about 0.631 g/cc loaded to a concentration of between 30 to 50 wt. % boron nitride, wherein the spherical particles of boron nitride comprise non-spherical shaped boron nitride particles bound together by an organic binder.
7. A low viscosity boron nitride filled polymer composition as defined in claim 6 , wherein said binder is selected from the group consisting of an acrylic or an acetate.
8. A low viscosity boron nitride filled polymer composition as defined in claim 6 , wherein said binder is selected from the group of nickel acetate, aluminum acetate and titanium acetate.
9. A low viscosity boron nitride filled polymer composition as defined in claim 8 , wherein the concentration of metal acetate in said slurry is about 1.8 wt. % or greater.
10. A process for forming a boron nitride powder comprising agglomerated particles of spherical geometry having an average particle size of about 10 to 150 microns in diameter and a tap density of from about 0.287 to about 0.631 g/cc, said process comprising the steps of:
mixing an aqueous slurry including irregular shaped particles consisting essentially of boron nitride, water, and an organic binder; and
spray drying the aqueous slurry into a powder composition of agglomerated boron nitride particles.
11. The process of claim 10 , wherein said organic binder is selected from the group consisting of consisting of acrylics and acetates.
12. A process for forming a boron nitride powder comprising agglomerated particles of spherical geometry having an average particle size of about 10 to 150 microns in diameter and a tap density of from about 0.287 to about 0.631 g/cc, said process comprising the steps of:
mixing an aqueous slurry including irregular shaped particles consisting essentially of boron nitride, water, and a binder selected from the group consisting of nickel acetate, aluminum acetate and titanium acetate; and
spray drying the aqueous slurry into a powder composition of agglomerated boron nitride particles.
13. A powder comprising substantially spherical agglomerated particles consisting essentially of a composite of non-spherical boron nitride particles bound together by an organic binder, wherein said spherical agglomerated particles have an average particle size of about 10 to 150 microns in diameter and a tap density of from about 0.287 to about 0.631 g/cc.
14. The boron nitride powder of claim 13 , wherein said particles have a surface layer comprising an organic binder and/or decomposition product thereof.
15. The boron nitride powder of claim 14 , wherein said decomposition product comprises a hydroxide.
16. The boron nitride powder of claim 13 , wherein said spherical agglomerates particles are prepared by spray drying an aqueous slurry of non-spherical shaped boron nitride particles, water, and an organic binder.
17. The boron nitride powder of claim 16 , wherein said aqueous slurry further comprises a base for maintaining the pH of the slurry basic.
18. The boron nitride powder of claim 17 , wherein said organic binder is at a level of about 1.8 wt. % or greater of said aqueous slurry.
19. A polymer composition comprising the boron nitride powder of claim 13 .