Bituminous composition with improved ‘walk-on-ability’ and its use in roofing applications
View Patent ↗Disclosed is a bituminous composition that comprises a bituminous component (A), an elastomer component (B), preferably a block copolymer of a conjugated diene and a monovinylaromatic hydrocarbon, and an additive (C), wherein the additive is a compound of the general formula Ar—R—Ar (I) wherein each “Ar” independently is a benzene ring or fused aromatic ring system of 6 to 20 carbon atoms, substituted by at least one hydroxyl group, and “R” is an optionally substituted divalent radical comprising 6 to 20 atoms in the backbone and at least one amide and/or ester group in the backbone. These compositions are disclosed to be particularly useful in the preparing and repair of roofing.
1. A bituminous composition comprising a bituminous component (A), at least one elastomer component (B) selected from the group consisting of polydienes, copolymers of dienes with a monovinylaromatic hydrocarbon, polyacrylates, polysulfides, polysilicones and polyesteramides having elastomeric behavior, and an additive (C), wherein the additive is a compound having the general formula:
Ar—R—Ar (I)
wherein each “Ar” independently is a benzene ring or fused aromatic ring system of 6 to 20 carbon atoms, substituted by at least one hydroxyl group, and “R” is:
an optionally substituted divalent radical comprising 6 to 20 atoms in the backbone and at least one amide group in the backbone represented by the general formula
—[C(═O)X]n—
wherein “X” is a nitrogen atom; and “n” is an integer having a value from 1 to 4
said elastomer component (B) being present in an amount in the range of from about 2 to about 20% wt and said additive (C) being present in an amount in the range of from about 0.01 to about 5 weight percent, based on the total bituminous composition.
2. The bituminous composition of claim 1 wherein the elastomer component is a block copolymer of a conjugated diene and a monovinylaromatic hydrocarbon.
3. The bituminous composition of claim 1 , wherein both “Ar” symbols in the general formula are 3,5-dialkyl-4-hydroxylphenyl groups.
4. The bituminous composition of claim 3 , wherein both 3,5-dialkyl-4hydroxylphenyl groups are 3,5-di-tert-butyl-4-hydroxylphenyl groups.
5. The bituminous composition of claim 1 , wherein the additive is bis(3,5-ditertbutyl-4-hydroxyphenylethylamino)dicarbonic acid amide.
6. The bituminous composition of claim 1 , wherein the bituminous component is naturally occurring bitumen or derived from a mineral oil.
7. The bituminous composition of claim 6 , wherein the bituminous component has a penetration in the range of from about 50 to about 250 dmm at 25° C.
8. The bituminous composition of claim 2 , wherein the block copolymer used as elastomer component (B) comprises at least two terminal blocks of a poly(monovinylaromatic hydrocarbon) and at least one block of one or more conjugated dienes or a partially hydrogenated version thereof.
9. The bituminous composition of claim 8 , wherein the conjugated diene is selected from the group consisting of butadiene, 2-methyl-1,3-butadiene (isoprene), 2,3-dimethyl-1,3-butadiene, 1,3-pentadiene and 1,2-hexadiene, and mixtures thereof.
10. The bituminous composition of claim 8 , wherein the monovinylaromatic hydrocarbon is selected from the group consisting of o-methyl styrene, p-methyl styrene, p-tert-butylstyrene, 2,4-dimethylstyrene, a-methylstyrene, vinyl naphthalene, vinyl toluene, vinyl xylene, and mixtures thereof.
11. The bituminous composition of claim 10 , wherein the monovinylaromatic hydrocarbon is styrene.
12. The bituminous composition of claim 10 , wherein the content of monovinylaromatic hydrocarbons of the block copolymer ranges from about 10 to about 70 weight percent based on the total block copolymer.
13. The bituminous composition of claim 8 , wherein the polymer blocks of monovinylaromatic hydrocarbons have an apparent molecular weight in the range from about 2,000 to about 100,000 and the polymer blocks of conjugated dienes have an apparent molecular weight in the range of from about 25,000 to about 1,000,000.
14. The bituminous composition of claim 8 , wherein the total vinyl content of the block copolymer is at least 6 weight percent based on the blocks of poly(conjugated diene).
15. A roofing felt comprising
(i) a bituminous composition comprising a bituminous component (A), at least one elastomer component (B) selected from the group consistion of polydienes, copolymers of dienes with a monovinylaromatic hydrocarbon, polyacrylates, polysulfides, polysilicones and polyesteramides having elastomeric behavior, and an additive (C), wherein the additive is a compound having the general formula:
Ar—R—Ar (I)
wherein each “Ar” independently is a benzene ring or fused aromatic ring system of 6 to 20 carbon atoms, substituted by at least one hydroxyl group, and “R” is:
an optionally substituted divalent radical comprising 6 to 20 atoms in the backbone and at least one amide group in the backbone represented by the general formula
—[C(═O)X]n—
wherein “X” is a nitrogen atom; and “n” is an integer having a value from 1 to 4
said elastomer being present in an amount in the range of from about 2 to about 20% wt and said additive (C) being present in an amount in the range of from about 0.01 to about 5 weight percent, based on the total bituminous composition; and
(ii) a filler selected from the group consisting of talc, calcium carbonate and carbon black.
16. A process for preparing a bituminous composition comprising admixing a bituminous component (A), at least one elastomer component (B) selected from the group consisting of polydienes, copolymers of dienes with a monovinylaromatic hydrocarbon, polyacrylates, polysulfides, polysilicones and polyesteramides having elastomeric behavior, and an additive (C), wherein the additive is a compound of the general formula:
Ar—R—Ar (I)
wherein each “Ar” independently is a benzene ring or fused aromatic ring system of 6 to 20 carbon atoms, substituted by at least one hydroxyl group, and “R” is
an optionally substituted divalent radical comprising 6 to 20 atoms in the backbone and at least one amide group in the backbone represented by the general formula
—[C(═O)X]n—
wherein “X” is a nitrogen atom; and “n” is an integer having a value from 1 to 4
said elastomer being present in an amount in the range of from about 2 to about 20% wt and said additive (C) being present in an amount in the range of from about 0.01 to about 5 weight percent, based on the total bituminous composition.
17. The process of claim 16 wherein the elastomer component and the additive are admixed with each other prior to being admixed with the bituminous component.
18. A composition useful for preparing or repairing roofs, said composition comprising
(i) a bituminous composition prepared by admixing a bituminous component (A), at least one elastomer component (B) selected from the group consisting of polydienes, copolymers of dienes with a monovinylaromatic hydrocarbon, polyacrylates, polysulfides, polysilicones and polyesteramides having elastomeric behavior, and an additive (C), wherein the additive is a compound of the general formula:
Ar—R—Ar (I)
wherein each “Ar” independently is a benzene ring or fused aromatic ring system of 6 to 20 carbon atoms, substituted by at least one hydroxyl group, and “R” is
an optionally substituted divalent radical comprising 6 to 20 atoms in the backbone and at least one amide group in the backbone represented by the general formula
—[C(═O)X]n—
wherein “X” is a nitrogen atom; and “n” is an integer having a value from 1 to 4
wherein the elastomer component and the additive are admixed with each other prior to being admixed with the bituminous component for preparing or repairing roofs, said elastomer component being present in an amount in the range of from about 2 to about 20% wt and said additive (C) being present in an amount in the range of from about 0.01 to about 5 weight percent, based on the total bituminous composition; and
(ii) a filler.
19. A bituminous composition comprising a bituminous component (A), at least one elastomer component (B) selected from the group consisting of polydienes, copolymers of dienes with a monovinylaroinatic hydrocarbon, polyacrylates, polysulfides, polysilicones and polyesteramides having elastomeric behavior, and an additive (C), wherein the additive is 1,2-bis(3,5-ditertbutyl-4- hydroxyhydrocinnamoyl)hydrazine), said elastomer component (B) being present in an amount in the range of from about 2 to about 20 % wt and said additive (C) being present in an amount in the range of from about 0.01 to about 5 weight percent, based on the total bituminous composition.
20. The roofing felt of claim 15 wherein the additive is bis(3,5-ditertbutyl-4-hydroxyphenylethylamino)dicarbonic acid amide.
21. The roofing felt of claim 15 wherein the elastomer component (B) comprises at least two terminal blocks of a poly(monovinylaromatic hydrocarbon) and at least one block of one or more conjugated dienes or a partially hydrogenated version thereof.
22. A rooting felt comprising
(i) a bituminous composition comprising a bituminous component (A), at least one elastomer component (B), wherein the elastomer component comprises at least two terminal blocks of a poly(monovinylaromatic hydrocarbon) and at least one block of one or more conjugated dienes or a partially hydrogenated version thereof, and an additive (C), wherein the additive is bis(3,5-ditertbutyl-4-hydroxyphenylethylamino)dicarbonic acid amide, said elastomer being present in an amount in the range of from about 2 to about 20 % wt and said additive (C) being present in an amount in the range of from about 0.01 to about 5 weight percent, based on the total bituminous composition; and
(ii) a filler selected from the group consisting of talc, calcium carbonate and carbon black.
23. The process of claim 16 wherein the additive is bis(3,5-ditertbutyl-4-hydroxyphenylethylamino)dicarbonic acid amide.
24. The process of claim 16 wherein the elastomer component comprises at least two terminal blocks of a poly(monovinylaromatic hydrocarbon) and at least one block of one or more conjugated dienes or a partially hydrogenated version thereof.
25. A process for preparing a bituminous composition admixing a bituminous component (A), at least one elastomer component (B), wherein the elastomer component comprises at least two terminal blocks of a poly(monovinylaromatic hydrocarbon) and at least one block of one or more conjugated dienes or a partially hydrogenated version thereof, and an additive (C), wherein the additive is bis(3,5-ditertbutyl-4-hydroxyphenylethylamino)dicarbonic acid amide, said elastomer being present in an amount in the range of from about 2 to about 20 % wt and said additive (C) being present in an amount in the range of from about 0.01 to about 5 weight percent, based on the total bituminous composition.
26. The process of claim 25 wherein the elastomer component and the additive are admixed with each other prior to being admixed with the bituminous component.
27. The composition of claim 18 wherein the additive is bis(3,5-ditertbutyl-4-hydroxyphenylethylamino)dicarbonic acid amide.
28. The composition of claim 18 wherein the elastomer component comprises at least two terminal blocks of a poly(monovinylaromatic hydrocarbon) and at least one block of one or more conjugated idenes or a partially hydrogenated version thereof.
29. A composition useful for preparing or repairing roofs, said composition comprising
(i) a bituminous composition prepared by admixing a bituminous component (A), at least one elastomer component (B), wherein the elastomer component comprises at least two terminal blocks of a poly(monovinylaromatic hydrocarbon) and at least one block of one or more conjugated dienes or a partially hydrogenated version thereof, and an additive (C), wherein the additive is bis(3,5-ditertbutyl-4-hydroxyphenylethylamino)dicarbonic acid amide, wherein the elastomer component and the additive are admixed with each other prior to being admixed with the bituminous component for preparing or repairing roofs, said elastomer component being present in an amount in the range of from about 2 to about 20 % wt and said additive (C) being present in an amount in the range of from about 0.01 to about 5 weight percent, based on the total bituminous composition; and
(ii) a filler.