Fluid loss control and sealing agent for drilling depleted sand formations
View Patent ↗An oil-based drilling fluid having a polymer latex capable of providing a deformable latex film on at least a portion of a subterranean sand formation has been discovered to inhibit or control fluid loss and act as a sealing agent when used to drill in sand formations for hydrocarbon recovery operations. Typically, the polymer latex is an aqueous suspension of particles formed by emulsion polymerization that is in turn emulsified into a hydrocarbon base fluid. The polymer particles of suitable size precipitate onto the pores of a subterranean sand formation to at least partial seal the formation with a deformable polymer film.
1. An oil-based drilling fluid for use in sealing sand formations comprising:
a) a polymer latex capable of providing a deformable latex film on at least a portion of a subterranean formation, the latex comprising polymer particles in an aqueous continuous phase, where the polymer particles are selected from the group consisting of polyvinylacetate copolymer, polyvinyl acetate/vinyl chloride/ethylene copolymer, polyvinyl acetate/ethylene copolymer, polydimethylsiloxane, and mixtures thereof;
b) a hydrocarbon base fluid; and
c) an emulsifier.
2. The oil-based drilling fluid of claim 1 where the polymer particles in the latex average between about 0.8 to less than 10 microns in size.
3. The oil-based drilling fluid of claim 1 where the latex particles are in a size distribution where the majority of the particles range from more than 10 to less than 100 microns.
4. The oil-based drilling fluid of claim 1 where the polymer latex is capable of providing a deformable latex seal on at least a portion of a subterranean sand formation.
5. The oil-based drilling fluid of claim 1 where the polymer latex is present in the drilling fluid in an amount of from about 0.1 to about 10 volume % based on the total oil-based drilling fluid.
6. The oil-based drilling fluid of claim 5 where the polymer particles in the latex comprises particles that average about 1 microns to less than 100 microns in size.
7. An oil-based drilling fluid for use in sealing subterranean sand formations comprising:
a) from about 1 to about 10 volume % of a polymer latex having particles selected from the group consisting of polyvinylacetate copolymer, polyvinyl acetate/vinyl chloride/ethylene copolymer, polyvinyl acetate/ethylene copolymer, polydimethylsiloxane, and mixtures thereof in an aqueous continuous phase, where the polymer latex is capable of providing a deformable latex film on at least a portion of a subterranean formation;
b) a hydrocarbon base fluid; and
f) an emulsifier in an amount effective to keep the latex suspended in the oil-based drilling fluid.
8. A method of inhibiting fluid loss of an oil-based drilling fluid in a sand formation, the method comprising:
a) providing an oil-based drilling fluid comprising:
i) a polymer latex capable of providing a deformable latex film on at least a portion of a subterranean formation, the latex comprising polymer particles in an aqueous continuous phase, where the polymer particles are in a size distribution where the majority of the particles range from about 1 to less than 100 microns;
ii) a hydrocarbon base fluid; and
iii) an emulsifier; and
b) circulating the oil-based drilling fluid in contact with a borehole wall in a sand formation.
9. The method of claim 8 where in providing the oil-based drilling fluid the polymer particles in the latex average from about 1 to 10 microns in size.
10. The method of claim 8 where in providing the oil-based drilling fluid, the polymer latex is capable of providing a deformable latex seal on at least a portion of a subterranean sand formation and the polymer particles are selected from the group consisting of polymethyl methacrylate, polyethylene, carboxylated styrene/butadiene copolymer, polyvinylacetate copolymer, polyvinyl acetate/vinyl chloride/ethylene copolymer, polyvinyl acetate/ethylene copolymer, natural latex, polyisoprene, polydimethylsiloxane, and mixtures thereof.
11. The method of claim 8 where in providing the oil-based drilling fluid, the polymer latex is present in the drilling fluid in an amount of from about 0.1 to about 10 vol. % based on the total oil-based drilling fluid.
12. A method of inhibiting fluid loss of an oil-based drilling fluid in a sand formation, the method comprising:
a) providing an oil-based drilling fluid comprising:
i) from about 0.1 to about 10 vol. % of a polymer latex comprising polymer particles in an aqueous continuous phase where the polymer particles are selected from the group consisting of polymethyl methacrylate, polyethylene, carboxylated styrene/butadiene copolymer, polyvinylacetate copolymer, polyvinyl acetate/vinyl chloride/ethylene copolymer, polyvinyl acetate/ethylene copolymer, natural latex, polyisoprene, polydimethylsiloxane, and mixtures thereof and are in a size distribution where the majority of the particles range from about 1 to less than 100 microns;
ii) a hydrocarbon base fluid; and
iii) an emulsifier; and
where the proportion is based on the total oil-based drilling fluid; and
b) circulating the oil-based drilling fluid in contact with a borehole wall in a sand formation.