IP Library Granted Patent US 7,335,692
Granted Patent B2
US 7,335,692 · App. 10/656,435 · Granted Feb 26, 2008

Rubber composition for tire tread

Assignee: Michelin Recherche et Technique, S.A.
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Quick Facts
Patent No.
US 7,335,692
App. No.
10/656,435
Granted
Feb 26, 2008
Kind
B2
Abstract

The present invention relates to a cross-linkable or cross-linked rubber composition usable in a tread of a tire, and to a tire incorporating this tread. A rubber composition according to the invention is based on at least one diene elastomer, and a plasticizer comprising a glycerol oleic acid triester, said plasticizer comprises: one or more synthetic and/or natural compounds not extracted from petroleum in a mass fraction of from 45% to 100%, said compounds comprising at least one glycerol fatty acid triester, and the fatty acid(s) as a whole comprise oleic acid in a mass fraction equal to or greater than 60%, and one or more paraffinic, aromatic or naphthenic type plasticizing oils extracted from petroleum in a mass fraction of from 55% to 0%. The invention applies in particular to tires of passenger-vehicle type.

Claims (24)

1. A cross-linkable or cross-linked rubber composition usable for constituting a tire tread, said composition being based on one or more diene elastomers and a plasticizer, wherein said plasticizer comprises:

one or more synthetic and/or natural compounds not extracted from petroleum present in a mass fraction of from 45% to 100%, wherein at least one of said natural compounds is sunflower oil, said sunflower oil comprising at least one glycerol fatty acid triester, wherein as a whole, the fatty acids in said sunflower oil comprise oleic acid in a mass fraction equal to or greater than 70%, wherein the amount of said sunflower oil in the composition is from 10 to 40 phr,

one or more plasticizing oils extracted from petroleum in a mass fraction of from 0% to 55%, wherein the plasticizing oils are selected from the group consisting of paraffinic, aromatic and naphthenic oils; and

a hydrocarbon plasticizing resin in a quantity of from 5 to 20 phr, wherein said hydrocarbon plasticizing resin is miscible in said diene elastomer(s), has a glass transition temperature of between 10° C. and 150° C. and a number-average molecular weight of between 400 g/mol and 2000 g/mol.

2. The cross-linkable or cross-linked rubber composition according to claim 1 , wherein the fatty acids comprise oleic acid in a mass fraction equal to or greater than 85%.

3. The cross-linkable or cross-linked rubber composition according to claim 1 , wherein said synthetic compound not extracted from petroleum is glycerol oleic acid triester.

4. The cross-linkable or cross-linked rubber composition according to claim 1 , wherein said plasticizers comprises one or more synthetic and/or natural compounds not extracted from petroleum in a mass fraction of from 70% to 100%, and said one or more plasticizing oils extracted from petroleum is in a mass fraction of from 0% to 30%.

5. The cross-linkable or cross-linked rubber composition according to according to claim 4 , wherein said plasticizer comprises one or more synthetic and/or natural compounds not extracted from petroleum in a mass fraction of from 80% to 100%, and said one or more plasticizing oils extracted from petroleum in a mass fraction from 0% to 20%.

6. The cross-linkable or cross-linked rubber composition according to claim 5 , wherein said plasticizer comprises one or more synthetic and/or natural compounds not extracted from petroleum in a mass of 100%.

7. The cross-linkable or cross-linked rubber composition according to claim 1 , wherein said composition comprises one or more plasticizing oils extracted from petroleum in a quantity of from 0 to 30 phr.

8. The cross-linkable or cross-linked rubber composition according to claim 7 , wherein said composition comprises one or more synthetic and/or natural compounds not extracted from petroleum in a quantity of from 20 to 35 phr, and said one or more plasticizing oils extracted from petroleum in a quantity of from 0 to 20 phr.

9. The cross-linkable or cross-linked rubber composition according to claim 1 , wherein said composition comprises between 50 phr and 100 phr of a majority of diene elastomer having a glass transition temperature of between −65° C. and −10° C., and between 0 phr and 50 phr of a minority diene elastomer having a glass transition temperature of between−110° C. and −80° C.

10. The cross-likable or cross-linked rubber composition according to claim 9 , wherein said majority diene elastomer is selected from the group consisting of solution-prepared styrene-butadiene copolymers, emulsion-prepared styrene-butadiene copolymers, natural polyisoprenes, synthetic polyisoprenes having a cis-1,4 linkage content greater than 95% and mixtures thereof, and said minority diene elastomer is a polybutadiene having a cis-1,4 linkage content greater than 90%.

11. The cross-likable or cross-linked rubber composition according to claim 10 , wherein said solution prepared styrene-butadiene copolymer have a glass transition temperature of from −50° C. to −15° C. and trans-1,4 butadiene linkage content which is greater than 50%.

12. The cross-likable or cross-linked rubber composition according to claim 11 , wherein said emulsion-prepared styrene-butadiene copolymers have a glass transition temperature of from −55° C. to −30° C.

13. The cross-linkable or cross-linked rubber composition according to claim 9 , wherein said majority diene elastomer is present in a quantity of 100 phr.

14. The cross-linkable or cross-linked rubber composition according to claim 9 , wherein said composition comprises a blend of said majority and minority diene elastomers.

15. The cross-linkable or cross-linked rubber composition according to claim 14 , wherein the blend comprises polybutadienes having a cis-1,4 linkage content greater than 90% and an emulsion-prepared styrene-butadiene copolymer.

16. The cross-likable or cross-linked rubber composition according to claim 1 , wherein said reinforcing filler is carbon black in a quantity of from 60 to 200 phr.

17. The cross-likable or cross-linked rubber composition according to claim 1 , wherein said reinforcing filler is a reinforcing white filler in a quantity equal to or greater than 70 phr.

18. The cross-likable or cross-linked rubber composition according to claim 1 , wherein said reinforcing filler is a bled of carbon black and a reinforcing white filler.

19. The cross-likable or cross-linked rubber composition according to claim 1 , wherein said plasticizing resin has a glass transition temperature of from 30° C. to 100° C., a number-average molecular weight of between 400 and 1000 g/mol, and a polymolecularity index less than 2.

20. A tread for a tire comprising a rubber composition in accordance with claim 1 .

21. A tire comprising a tread according to claim 20 .

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 2, 2017
From: MICHELIN RECHERCHE ET TECHNIQUE S.A.
To: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
Reel/Frame 044017/0813 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 26, 2004
From: VASSEUR, DIDIER; LABAUZE, GERARD
To: MICHELIN RECHERCHE ET TECHNIQUE S.A.
Reel/Frame 015014/0251 →
Priority Claims (1)
FR 01 03356 · Mar 12, 2001 · national
Continuity (2)
Continuation PCTEP020255800 · Mar 8, 2002
Related Publication 20040127617A1 · Jul 1, 2004