Photothermographic material, and image forming method using same
The present invention provides a photothermographic material comprising a substrate and a composition provided thereon. The composition includes a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for thermal development and a binder. Each of organic compounds comprised in an amount of approximately 0.05 g/m 2 or more in the composition has a volatilization remaining ratio of 50% or more at 160° C. The photothermographic material preferably comprises, as a color tone adjuster, a combination of a phthalazine acid and a phthalic acid compound each having a specific structure. The invention further provides a method for producing the imaged photothermographic material. In the production of this material, a thermal developing device having a filter for collecting volatilized material is used.
1 . A photothermographic material comprising a substrate and a composition disposed thereon, wherein:
the composition comprises a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for thermal development and a binder; wherein
each of organic compounds comprised in an amount of approximately 0.05 g/m 2 or more in the composition has a volatilization remaining ratio of 50% or more at 160° C.
2 . A photothermographic material according to claim 1 , wherein at least one of the organic compounds is represented by the following general formula (I):
wherein each of W 1 to W 4 independently represents a hydrogen atom or a monovalent substituent, and at least one of W 1 to W 4 is a monovalent substituent.
3 . A photothermographic material according to claim 1 , wherein at least one of the organic compounds is represented by the following general formula (II):
wherein each of R 1 to R 4 independently represent a hydrogen atom or a monovalent substituent, and when three out of R 1 to R 4 are hydrogen atoms, a remaining monovalent substituent is a group other than a methyl group; and M represents a hydrogen atom, an alkali metal, an alkali earth metal, an ammonium group, or a phosphonium group.
4 . A photothermographic material according to claim 1 , which comprises at least one compound selected from the compounds represented by the following general formula (I) and at least one compound selected from the compounds represented by the following general formula (II):
wherein each of W 1 to W 4 independently represents a hydrogen atom or a monovalent substituent, and at least one of W 1 to W 4 is a monovalent substituent:
wherein each of R 1 to R 4 independently represents a hydrogen atom or a monovalent substituent, and when three out of R 1 to R 4 are hydrogen atoms, a remaining monovalent substituent is a group other than a methyl group; and M represents a hydrogen atom, an alkali metal, an alkali earth metal, an ammonium group, or a phosphonium group.
5 . A method for forming an image by heating an exposed photothermographic material using a thermal developing device, wherein
the thermal developing device comprises a filter for collecting volatilized substances, and
the photothermographic material comprises a substrate and a composition disposed thereon, wherein:
the composition comprises a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent for thermal development and a binder; wherein
each of organic compounds comprised in an amount of approximately 0.05 g/m 2 or more in the composition has a volatilization remaining ratio of 50% or more at 160° C.
6 . An image forming method according to claim 5 , wherein at least one of the organic compounds is represented by the following general formula (I):
wherein each of W 1 to W 4 independently represents a hydrogen atom or a monovalent substituent, and at least one of W 1 to W 4 is a monovalent substituent.
7 . An image forming method according to claim 5 , wherein at least one of the organic compounds is represented by the following general formula (II):
wherein each of R 1 to R 4 independently represents a hydrogen atom or a monovalent substituent, and when three out of R 1 to R 4 are hydrogen atoms, a remaining monovalent substituent is a group other than a methyl group; and M represents a hydrogen atom, an alkali metal, an alkali earth metal, an ammonium group, or a phosphonium group.
8 . An image forming method according to claim 5 , wherein the photothermographic material comprises at least one compound selected from the compounds represented by the following general formula (I) and at least one compound selected from the compounds represented by the following general formula (II):
wherein each of W 1 to W 4 independently represents a hydrogen atom or a monovalent substituent, and at least one of W 1 to W 4 is a monovalent substituent:
wherein each of R 1 to R 4 independently represents a hydrogen atom or a monovalent substituent, and when three out of R 1 to R 4 are hydrogen atoms, a remaining monovalent substituent is a group other than a methyl group; and M represents a hydrogen atom, an alkali metal, an alkali earth metal, an ammonium group, or a phosphonium group.
9 . An image forming method according to claim 5 , wherein the time for thermal development is in a range of 7 to 15 seconds.