IP Library Granted Patent US 6,843,176
Granted Patent B2
US 6,843,176 · App. 10/661,236 · Granted Jan 18, 2005

Method to remove unwanted, unexposed, radiation-sensitive layer in a lithographic printing plate

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Quick Facts
Patent No.
US 6,843,176
App. No.
10/661,236
Granted
Jan 18, 2005
Kind
B2
Abstract

A method for forming a printing plate from a printing plate precursor having a radiation-sensitive layer, sensitive to radiation in a first frequency spectrum such as the far or near infrared, and to radiation in a second frequency spectrum other than the first frequency spectrum such as visible or ultraviolet. The plate is exposed twice. Once to imaging radiation in the first frequency spectrum and again to radiation in the second frequency spectrum. The second frequency spectrum exposure is done only to the areas of the plate undesirably shaded during the imagewise exposure.

Claims (30)

1. A method for forming a printing plate precursor comprising a radiation-sensitive layer, said radiation sensitive layer exhibiting sensitivity to radiation in a first frequency spectrum and to radiation in a second frequency spectrum other than said first frequency spectrum, said precursor forming a printing plate following imagewise exposure in an exposure device to said radiation in said first frequency spectrum, wherein said imagewise exposure (i) generates imagewise exposed and unexposed areas of said plate and (ii) generates undesirably unexposed areas due to unwanted shading during said imagewise exposure, the method comprising identifying and pre-exposing to radiation in said second frequency spectrum prior to placing said precursor in said exposure device areas of said precursor undesirably unexposed during said imagewise exposure.

2. The method according to claim 1 wherein said printing plate is a positive working lithographic printing plate.

3. The method according to claim 1 wherein said printing plate is a negative working lithographic printing plate.

4. The method according to claim 1 wherein said undesirably unexposed areas result from applying a clamping device on said precursor during said imagewise exposure of said precursor.

5. The method according to claim 1 wherein said precursor is heat sensitive and said imagewise exposure comprises imagewise heating said plate precursor layer.

6. The method according to claim 5 wherein said heat sensitive precursor comprises a photothermal conversion material.

7. A method according to claim 1 wherein said first frequency radiation is heating radiation and said second frequency radiation is one of visible and ultraviolet radiation.

8. The method according to claim 7 further comprising, following said imagewise exposure, by developing said printing plate precursor.

9. The method according to claim 7 wherein said precursor comprises a photothermal conversion material.

10. The method according to claim 7 wherein said undesirably unexposed areas result from applying a clamping device on said precursor during said imagewise exposure of said precursor.

11. The method according to claim 1 for forming a printing plate, the method comprising the step of:

(a) developing the printing plate precursor with a developer to form the printing plate.

12. The method of claim 11 in which the first frequency region is in the ultraviolet, and the second frequency region is in the infrared.

13. The method of claim 11 in which the first frequency region is in the infrared, and the second frequency region in the ultraviolet.

14. The method of claim 11 wherein said exposure to radiation in said first and said second frequency spectra creates exposed regions on said precursor and wherein the exposed regions are removed by the developer.

15. The method of claim 11 wherein said exposure to radiation in said first and said second frequency spectra creates exposed regions on said precursor and wherein the unexposed regions are removed by the developer.

16. A method for forming a printing plate comprising a printing plate precursor comprising a radiation-sensitive layer, said radiation sensitive layer exhibiting sensitivity to radiation in a first frequency spectrum and to radiation in a second frequency spectrum other than said first frequency spectrum, the method comprising imagewise exposing said printing plate precursor to said radiation in said first frequency spectrum and exposing to radiation in said second frequency spectrum any areas of said plate subject to undesirable shading during said imagewise exposure as a result of applying a clamping device on said precursor during said imagewise exposure of said precursor, wherein said clamping device is transparent to said second frequency radiation.

17. The method according to claim 16 wherein said clamping device comprises clear glass, polymethyl methacrylate, polycarbonate, polyvinyl chloride, glass fiber-reinforced polyester, magnesium fluoride, barium fluoride, calcium fluoride, potassium bromide, lithium fluoride, thallium halides, chalcgenide glass, polycrystalline zinc selenide, zinc sulfide, lanthanide sulfides, fused silica, quartz, UVT acrylic or a combination thereof.

18. The method according to claim 16 wherein the undesirably unexposed areas of said plate are exposed to said radiation in said second frequency spectrum following the imagewise exposing of the precursor to the first frequency spectrum radiation.

19. The method according to claim 16 wherein the undesirably unexposed areas of said plate are exposed to said radiation in said second frequency spectrum during the imagewise exposing of the precursor to the first frequency spectrum radiation.

20. The method according to claim 16 wherein said first frequency spectrum radiation is heating radiation and said second frequency spectrum radiation is one of visible or ultraviolet radiation and wherein said clamping device is transparent to at least one of said visible or ultraviolet radiation.

21. The method according to claim 20 wherein said clamping device comprises clear glass, polymethyl methacrylate, polycarbonate, polyvinyl chloride, glass fiber-reinforced polyester, magnesium fluoride, barium fluoride, calcium fluoride, potassium bromide, lithium fluoride, thallium halides, chalcgenide glass, polycrystalline zinc selenide, zinc sulfide, lanthanide sulfides, fused silica, quartz, UVT acrylic, or a combination thereof.

22. The method according to claim 20 wherein the undesirably unexposed areas of said plate are identified and exposed to said at least one of visible or ultraviolet radiation prior to the step of exposing the precursor by imagewise heating.

23. The method according to claim 20 wherein the undesirably unexposed areas of said plate are identified and exposed to said at least one of visible or ultraviolet radiation during the step of exposing by imagewise heating the precursor.

24. The method according to claim 20 wherein the undesirably unexposed areas of said plate are identified and exposed to said at least one of visible or ultraviolet radiation following the step of exposing by imagewise heating the precursor.

25. A method for forming a printing plate comprising a heat sensitive printing plate precursor said precursor also exhibiting sensitivity to at least one of visible and ultraviolet radiation, the method comprising:

(a) exposing said printing plate precursor by imagewise heating in an imagesetter;

(b) exposing to at least one of said visible and ultraviolet radiation only areas of said plate undesirably shaded during said imagewise heating exposure of said precursor as said precursor exits said imagesetter following said exposure to imagewise radiation; and

(c) developing said printing plate precursor.

26. The method according to claim 25 wherein said exposure to said at least one of visible and ultraviolet radiation is performed with a fluorescent light source positioned at an exit of said imagesetter and extending across said exit.

Assignments (11)
RELEASE OF SECURITY INTEREST Recorded Jan 24, 2020
From: BARCLAYS BANK PLC
To: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST) INC.; KODAK AMERICAS LTD.; KODAK REALTY INC.; LASER PACIFIC MEDIA CORPORATION; QUALEX INC.; KODAK PHILIPPINES LTD.; NPEC INC.
Reel/Frame 052773/0001 →
RELEASE OF SECURITY INTEREST Recorded Jul 22, 2019
From: JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC, INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX, INC.; KODAK PHILIPPINES, LTD.; NPEC, INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
Reel/Frame 049814/0001 →
RELEASE OF SECURITY INTEREST Recorded Feb 8, 2017
From: BARCLAYS BANK PLC
To: EASTMAN KODAK COMPANY
Reel/Frame 041656/0531 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Sep 5, 2013
From: CITICORP NORTH AMERICA, INC., AS SENIOR DIP AGENT; WILMINGTON TRUST, NATIONAL ASSOCIATION, AS JUNIOR DIP AGENT
To: EASTMAN KODAK COMPANY; PAKON, INC.
Reel/Frame 031157/0451 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (FIRST LIEN) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC; KODAK AMERICAS, LTD.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE
Reel/Frame 031158/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (SECOND LIEN) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
To: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT
Reel/Frame 031159/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (ABL) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
To: BANK OF AMERICA N.A., AS AGENT
Reel/Frame 031162/0117 →
PATENT SECURITY AGREEMENT Recorded Apr 1, 2013
From: EASTMAN KODAK COMPANY; PAKON, INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 030122/0235 →
SECURITY INTEREST Recorded Feb 21, 2012
From: EASTMAN KODAK COMPANY; PAKON, INC.
To: CITICORP NORTH AMERICA, INC., AS AGENT
Reel/Frame 028201/0420 →
MERGER Recorded Aug 18, 2006
From: KPG HOLDING COMPANY, INC. (FORMERLY KODAK POLYCHROME GRAPHICS LLC)
To: EASTMAN KODAK COMPANY
Reel/Frame 018132/0373 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 12, 2003
From: RAY, KEVIN B.; HUANG, JIANBING; RAY, JOANNE
To: KODAK POLYCHROME GRAPHICS LLC
Reel/Frame 014498/0792 →