Liquid crystalline polymer composites, method of manufacture thereof, and articles formed therefrom
View Patent ↗A liquid crystalline composite comprising a liquid crystalline polymer, particulate filler, and fibrous web. Further disclosed is a method for forming the liquid crystalline polymer composite. The liquid crystalline polymer composite is useful in circuit materials, circuits, and multi-layer circuits, economical to make, and has excellent flame retardant properties.
1. A circuit material comprising a layer of a dielectric liquid crystalline composite, the composite comprising
a liquid crystalline polymer;
a particulate filler composition comprising a combination of silica and polytetrafluoroethylene; and
a fibrous web, wherein the composite has a dielectric constant of less than about 3.8 at frequencies higher than or equal to 1 GHz, a dissipation factor of less than or equal to about 0.007, and a UL-94 rating of V-1 or better.
2. The circuit material of claim 1 further comprising a copper conductive layer, wherein the the bond strength between the conductive layer and liquid crystalline composite layer is greater than or equal to about 1 pli at 200° C.
3. The circuit material of claim 1 , wherein the silica is treated with a coupling agent.
4. The circuit material of claim 1 , wherein the composite further has a water absorption of less than about 0.1%.
5. The circuit material of claim 1 , further comprising a first conductive layer disposed on one side of the composite layer.
6. The circuit material of claim 5 , wherein the first conductive layer is copper.
7. The circuit material of claim 5 , further comprising a second conductive layer disposed on a side of the composite layer opposite the first conductive layer.
8. The circuit material of claim 5 , wherein the second conductive layer is copper.
9. A circuit, comprising
a dielectric substrate layer, wherein the dielectric substrate comprises
a liquid crystalline polymer,
a particulate filler composition comprising a combination of silica and polytetrafluoroethylene, and
a fibrous web; and
a circuit layer disposed on the dielectric substrate layer, wherein the circuit layer has a dielectric constant of less than about 3.8, a dissipation factor of less than about 0.007 measured between 1 and 10 GHz, and a UL-94 rating of V-1 or better.
10. The circuit of claim 9 , wherein the circuit layer is copper.
11. The circuit of claim 9 , further comprising a conductive layer disposed on a side of the dielectric substrate opposite the first circuit layer.
12. The circuit of claim 11 , wherein the conductive layer is copper.
13. The circuit of claim 8 , wherein the conductive layer is patterned to form a second circuit layer.
14. A multi-layer circuit comprising:
a first circuit, the first circuit comprising a first dielectric substrate layer and a first circuit layer;
a second circuit, the second circuit comprising a second dielectric substrate layer and a second circuit layer; and
a bond ply disposed between the first dielectric substrate layer and the second circuit layer; wherein at least one of the first dielectric substrate layer, the second dielectric substrate layer, or the bond ply comprises a liquid crystalline polymer, a particulate filler composition comprising a combination of silica and polytetrafluoroethylene, and a fibrous web; and further wherein the multi-layer circuit has a dielectric constant of less than about 3.8, a dissipation factor of less than or equal to about 0.007 measured between 1 and 10 GHz, and a UL-94 rating of V-1 or better.
15. The multi-layer circuit of claim 14 , wherein the circuit layers are copper.
16. The multi-layer circuit of claim 14 , further comprising a resin coated conductive layer comprising a first conductive layer disposed on a flowable dielectric material, wherein the flowable dielectric material is disposed on a side of the first circuit layer opposite the first dielectric substrate layer.
17. A circuit material comprising
a conductive layer; and
a layer of a liquid crystalline composite disposed on the conductive layer, the composite comprising
a liquid crystalline polymer,
a particulate filler composition, wherein the particulate filler composition comprises silica and polytetrafluoroethylene; and
a fibrous web;
wherein the bond strength between the conductive layer and the liquid crystalline composite layer is greater than or equal to about 1 pli measured at 200° C.
18. The circuit material of claim 17 , wherein the silica is treated with a coupling agent that is a silane that bonds to the silica and to the liquid crystalline polymer.
19. A liquid crystalline composite, disposed on a conductive layer, the composite comprising
a liquid crystalline polymer;
a particulate filler composition, wherein the particulate filler composition comprises a combination of silica and polytetrafluoroethylene; and
a fibrous web,
wherein the bond strength between the conductive layer and the liquid crystalline composite layer is greater than or equal to about 1 pli measured at 200° C.