Process for producing hexamethylenediamine and aminocapronitrile from adiponitrile, wherein the hexamethylenediamine contains less than 100 ppm tetrahydroazepine
Process for making both ACN and HMD from partial hydrogenation of ADN by using a combination of distillations resulting in the formation of a mixture of HMD and THA that can be hydrogenated to produce a mixture of HMD and HMI that can be separated easily by simple distillation.
1. A process for co-producing HMD and ACN from ADN, wherein the HMD contains less than 200 ppm THA, said process comprising the steps of:
(1) contacting ADN and hydrogen in the presence of a hydrogenation catalyst to produce a reaction product that comprises HMD, ACN, THA, and unreacted ADN;
(2) distilling the reaction product to provide a distillate that comprises HMD and THA;
(3) contacting the distillate with hydrogen in the presence of a hydrogenation catalyst, thereby providing a hydrogenation product that comprises HMD and HMI, said hydrogenation product containing less than 200 ppm THA; and
(4) distilling the hydrogenation product to provide a final distillate that comprises HMI and a bottoms that comprises HMD that contains less than 200 ppm THA and is substantially free of HMI.
2. The process of claim 1 wherein the hydrogenation catalyst of step (3) is Raney Nickel or Raney Cobalt.