Non-resonant two-photon absorbing material, non-resonant two-photon emitting material, and method for inducing absorption or generating emission of non-resonant two photons by using the material
View Patent ↗A non-resonant two-photon absorbing material is provided, comprising a methine dye undergoing a non-resonant two-photon absorption, in which the methine dye is preferably a cyanine dye, a merocyanine dye or an oxonol dye, and a non-resonant two-photon absorbing material is provided, comprising a non-resonant two-photon absorbing compound undergoing non-resonant two-photon absorption in the intermolecular aggregation state.
1. A method for inducing a non-resonant two-photon absorption, which comprises irradiating a non-resonant two-photon absorbing material comprising an oxonol dye undergoing a non-resonant two-photon absorption with a laser ray having a wavelength longer than the linear absorption band of the dye where the two photon cross-section is at least 1000 GM, which is in the range of 400 to 1,000 nm to induce a two-photon absorption.
2. The method as described in claim 1 , wherein the oxonol dye is represented by the following formula (3):
wherein Za 5 and Za 6 each represents an atomic group for forming a 5- or 6-membered ring,
Ma 12 to Ma 14 each independently represents a methine group, which may have a substituent or may form a ring together with another methine group,
ka 3 represents an integer of 0 to 3, provided that when ka 3 is 2 or more, multiple Ma 12 s may be the same or different and multiple Ma 13 s may be the same or different, CI represents an ion for neutralizing the electric charge, and y represents a number necessary for the neutralization of electric charge.