Nanosized silver oxide powder
View Patent ↗The present invention provides silver oxide particles having an average diameter of less than or equal to 100 nm that are stable and can be transported in dry powder form. The surface of the silver oxide particles is coated with an extremely thin layer of a surfactant such as fatty acid. Nanosized silver oxide particles according to the invention are preferably formed via the addition of a strong base to a mixture including an aqueous silver salt solution and a surfactant dissolved in an organic solvent that is at least partially water miscible. The strong base causes silver oxide to precipitate from the mixture as nanosized particles, which are immediately encapsulated by the surfactant and thus protected from further crystal growth and Ostwald ripening. The nanosized surfactant coated particles of silver oxide can be washed and dried and then transported in dry form.
1. A method of forming silver oxide particles, the method comprising:
mixing a first solution and a second solution together to form a mixture, wherein the first solution comprises a silver salt dissolved in water and the second solution comprises a surfactant dissolved in an organic solvent; and
contacting the mixture with a base to precipitate silver oxide particles that are at least partially encapsulated by the surfactant.
2. The method according to claim 1 wherein the first solution comprises silver nitrate dissolved in deionized water.
3. The method according to claim 2 wherein the organic solvent is completely miscible with water.
4. The method according to claim 2 wherein the organic solvent is acetone.
5. The method according to claim 1 wherein the surfactant comprises a fatty acid or a derivative of a fatty acid.
6. The method according to claim 5 wherein the fatty acid is oleic acid.
7. The method according to claim 1 wherein the base is selected from the group consisting of sodium hydroxide and potassium hydroxide.
8. The method according to claim 1 further comprising:
separating the surfactant encapsulated silver oxide particles from the mixture; and
washing the surfactant encapsulated silver oxide particles.
9. The method according to claim 8 wherein the surfactant encapsulated silver oxide particles are sequentially washed with water and acetone.
10. The method according to claim 8 further comprising:
drying the washed surfactant encapsulated silver oxide particles.
11. The method according to claim 10 further comprising:
screening the dried surfactant encapsulated silver oxide particles to remove aggregates.
12. The method according to claim 1 wherein the surfactant encapsulated silver oxide particles have an average particle size of less than or equal to about 100 nm.
13. A composition of matter comprising particles of silver oxide having an average particle size of less than or equal to about 100 nm, wherein the silver oxide particles are encapsulated by a surfactant that inhibits Ostwald ripening.
14. The composition of matter according to claim 13 wherein the surfactant is a fatty acid.
15. The composition of matter according to claim 14 wherein the fatty acid is oleic acid.
16. The composition of matter according to claim 13 wherein the particles of silver oxide are in dry powder form.
17. The composition of matter according to claim 13 wherein the particles of silver oxide are dispersed in a liquid carrier.