Preparation of a printing plate using ink-jet
View Patent ↗A method for forming an image useful as a lithographic printing plate is disclosed. The imageable precursor comprises a water solubilized phenolic resin made up of an insoluble phenolic resin and a surfactant. The precursor can be imaged with an imaging solution, either off press or on press, using ink jet imaging techniques. The resulting imaged precursor can be developed using an aqueous liquid, such as water or a fountain solution, either off press or on press.
1. A method for forming an image, the method comprising the steps of:
a) imaging an imageable precursor that comprises an overlayer over a substrate by imagewise applying an imaging solution to the overlayer and forming an imaged precursor comprising imaged and complementary unimaged regions in the overlayer;
in which:
the substrate has a hydrophilic surface;
the overlayer is over the hydrophilic surface of the substrate;
the overlayer comprises a water-solubilized phenolic resin;
the water-solubilized phenolic resin comprises a water-insoluble novolac resin and a surfactant selected from the group consisting of anionic surfactants, nonionic surfactants, and mixtures thereof; and
the imaging solution comprises a water soluble insolubilizing agent; and
b) developing the imaged precursor with an aqueous liquid and removing the unimaged regions, thus revealing the underlying hydrophilic surface of the substrate, without removing the imaged regions.
2. The method of claim 1 in which the insolubilizing agent contains a cationic group.
3. The method of claim 2 in which the surfactant is an anionic surfactant.
4. The method of claim 3 in which the insolubilizing agent is selected from the group consisting of cationic dispersing agents, cationic polymers, and diazonium salts.
5. The method of claim 1 in which the aqueous liquid is either water or a fountain solution.
6. The method of claim 5 in which the insolubilizing agent comprises a diazonium salt.
7. The method of claim 6 additionally comprising, after step a), an additional step of either heating the imaged imageable precursor, irradiating the imaged imageable precursor with ultraviolet radiation, or heating the imaged imageable precursor and irradiating the imaged imageable precursor with ultraviolet radiation.
8. The method of claim 7 in which the additional step is carried out after step a) and before step b).
9. The method of claim 6 in which the diazonium salt is an alkyl or aryl sulfate or an alkyl or aryl thiosulfate.
10. The method of claim 1 in which the insolubilizing agent comprises a diazonium salt and the method additionally comprises an additional step of, after step a), of either heating the imaged imageable precursor, irradiating the imaged imageable precursor with ultraviolet radiation, or heating the imaged imageable precursor and irradiating the imaged imageable precursor with ultraviolet radiation.
11. The method of claim 10 in which the additional step is carried out after step a) and before step b).
12. The method of claim 11 in which the surfactant is an anionic surfactant.
13. The method of claim 1 in which the aqueous liquid is a fountain solution.
14. The method of claim 13 in which step b) is carried out on press.
15. The method of claim 13 in which the insolubilizing agent comprises a diazonium salt and the surfactant is an anionic surfactant.
16. The method of claim 15 additionally comprising, after step a), an additional step of either heating the imaged imageable precursor, irradiating the imaged imageable precursor with ultraviolet radiation, or heating the imaged imageable precursor and irradiating the imaged imageable precursor with ultraviolet radiation.
17. The method of claim 1 in which the water-insoluble novolac resin is water solubilized by the formation of micelles.
18. The method of claim 17 in which the insolubilizing agent comprises a diazonium salt and the surfactant is an anionic surfactant.
19. The method of claim 18 additionally comprising, after step a), an additional step of either heating the imaged imageable precursor, irradiating the imaged imageable precursor with ultraviolet radiation, or heating the imaged imageable precursor and irradiating the imaged imageable precursor with ultraviolet radiation.
20. The method of claim 1 in which the insolubilizing agent comprises a diazonium salt, the surfactant is an anionic surfactant, the aqueous liquid is a fountain solution, and step b) is carried out on press.
21. The method of claim 20 in which step a) is carried out on press.
22. The method of claim 6 in which the diazonium salt is an aromatic sulfonate.
23. The method of claim 22 in which the diazonium salt is the condensation product of 3-methoxy-4-diazodiphenylamine and 4 4′-bismethoxymethyldiphenyl ether with a mesitylene sulfonate counter ion.
24. The method of claim 23 in which step a) is carried out off press and step b) is carried out on press.
25. The method of claim 1 in which step a) is carried out off press and step b) is carried out on press.
26. The method of claim 7 in which the additional step is the step of either irradiating the imaged imageable precursor with ultraviolet radiation, or the step of heating the imaged imageable precursor and irradiating the imaged imageable precursor with ultraviolet radiation.
27. The method of claim 19 in which the additional step is the step of either irradiating the imaged imageable precursor with ultraviolet radiation, or the step of heating the imaged imageable precursor and irradiating the imaged imageable precursor with ultraviolet radiation.
28. The method of claim 5 in which the aqueous liquid is water.
29. The method of claim 28 in which the insolubilizing agent comprises a diazonium salt and the surfactant is an anionic surfactant.