IP Library Granted Patent US 7,244,365
Granted Patent B2
US 7,244,365 · App. 10/693,812 · Granted Jul 17, 2007

Process for safely decontaminating the chill water used in meat processing

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Quick Facts
Patent No.
US 7,244,365
App. No.
10/693,812
Filed
Oct 24, 2003
Granted
Jul 17, 2007
Kind
B2
Art Unit
1724
USPC
210/746
Abstract

This invention relates to a process for safely decontaminating the chill water used in meat processing. The decontaminant used in the process is chlorine dioxide.

Claims (23)

1. A process for safely decontaminating the chill water used in meat processing, which comprises:

(a) measuring the oxidative-reduction potential of the chill water in the chill bath of a chiller prior to introducing the meat to be processed and chlorine dioxide into the chill water, in order to obtain a reference oxidative-reduction potential for said chill water,

(b) introducing the meat to be processed into the chill water,

(c) feeding chlorine dioxide to said chill water to achieve a predetermined target oxidative-reduction potential in the chill water from 400 mV to 750 mV,

wherein the concentration of chlorine dioxide fed is from 100 ppm to 3000 ppm, and

wherein the amount of chlorine dioxide fed is sufficient to increase the oxidative-reduction potential of the chill water to a level that exceeds the reference oxidative-reduction potential established in (a), and achieves the target oxidative-reduction potential referenced in (c), provided that the level of chlorine dioxide in the chill water does not exceed a residual level of 3.0 ppm;

(d) monitoring the oxidative-reduction potential of the chill water with an oxidative-reduction potential analyzer;

(e) monitoring the level of chlorine dioxide gas in the atmosphere surrounding the chill water with an air quality monitor; and

(f) terminating the flow of the aqueous solution of chlorine dioxide into the chill water, if the oxidative-reduction potential exceeds 750 mV, if the oxidative-reduction potential of the chill water meets the target established in (c), or if the level of chlorine dioxide gas in the atmosphere surrounding the chill water exceeds 0.3 ppm.

2. The process of claim 1 wherein said chlorine dioxide is an aqueous solution of chlorine dioxide generated on site by means of a chlorine dioxide generator achieving a generation efficiency of at least 90% and the oxidative-reduction potential is measured with an oxidative-reduction potential sensor.

3. The process of claim 2 wherein the flow of aqueous chlorine dioxide to the chill water is controlled by a master on-line control unit that receives analog and/or digital signals from the chiller, the chlorine dioxide generator, the oxidative-reduction potential analyzer, and the air quality monitor.

4. The process of claim 3 wherein the oxidative-reduction potential of the chill water and the level of chlorine dioxide gas in the atmosphere surrounding the chill are continuously and simultaneously monitored.

5. The process of claim 4 wherein the master control unit receives a signal from the chiller indicating that the chiller contains chill water and is operational before the chlorine dioxide generator is activated to supply chlorine dioxide to the chill water.

6. The process of claim 5 further comprising two or more oxidative-reduction potential sensors each connected to two or more oxidative-reduction potential analyzers, respectively, wherein the two or more oxidative-reduction potential analyzers are connected to the on-line master controller and send oxidative-reduction potential signals to the controller that are compared to each other to determine whether there is a discrepancy between them.

7. The process of claim 6 wherein predetermined target oxidative-reduction potential in the chill water is from 580 mV to 680 mV and the concentration of chlorine dioxide fed is from 750 ppm to 2000 ppm.

8. The process of claim 7 wherein the master on-line controller initiates a probe wash using a pump and/or a probe freshwater back flush if one or both of the ORP analyzers indicate a low ORP or if a discrepancy exists between the analyzers, which exceeds a limit considered to be unacceptable, and wherein an alarm is activated signaling such condition.

9. The process of claim 8 wherein an alarm is signaled when the level of chlorine dioxide gas in the atmosphere surrounding the chill water exceeds 0.1 ppm.

10. The process of claim 9 wherein the flow of the aqueous solution of chlorine dioxide into the chill water is terminated if the level of chlorine dioxide gas in the atmosphere surrounding the chill water exceeds 0.25 ppm.

11. The process of claim 10 wherein an interlocking circuit connects the on-line master control unit to the chlorine dioxide generator and terminates the flow of chlorine dioxide to the chill water if the chlorine dioxide level in the chill water or the surrounding air is unacceptable or if the target oxidative-reduction potential is met.

12. The process of claim 11 wherein an alarm is activated if the oxidative-reduction potential of the chill water is such that the chlorine dioxide level of the chill water is unacceptably high.

13. The process of claim 12 wherein the meat processed is poultry or seafood.

14. The process of claim 13 wherein all data described is collected and stored by the master control unit and is available for download either locally or remotely.

15. The process of claim 14 wherein the data is downloaded remotely by a land-based telephone line or cellular technology.

Assignments (19)
RELEASE OF SECURITY INTEREST Recorded Nov 14, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073564/0864 →
SECURITY INTEREST Recorded Nov 14, 2025
From: CHEM-AQUA, INC.; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; NCH CORPORATION; NCH LIFE SCIENCES LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 073570/0838 →
RELEASE OF 2023 NOTES PATENT SECURITY INTERESTS Recorded Oct 10, 2025
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
To: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 073074/0198 →
SECURITY AGREEMENT (2024 NOTES) Recorded Jun 24, 2024
From: BIRKO CORPORATION; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 067824/0278 →
2023 NOTES PATENT SECURITY AGREEMENT Recorded Jul 7, 2023
From: BIRKO CORPORATION; SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC; DIVERSEY, INC.; DIVERSEY TASKI, INC.; INNOVATIVE WATER CARE GLOBAL CORPORATION
To: BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 064225/0170 →
SECURITY AGREEMENT (NOTES) Recorded Sep 14, 2022
From: SOLENIS TECHNOLOGIES, L.P.; INNOVATIVE WATER CARE, LLC
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A. AS COLLATERAL AGENT
Reel/Frame 061432/0821 →
RELEASE OF SECURITY INTEREST Recorded Nov 10, 2021
From: CITIBANK, N.A.
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 058848/0636 →
ABL PATENT SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: BANK OF AMERICA, N.A.
Reel/Frame 058102/0122 →
TERM LOAN PATENT SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: GOLDMAN SACHS BANK USA
Reel/Frame 058102/0407 →
NOTES SECURITY AGREEMENT Recorded Nov 10, 2021
From: INNOVATIVE WATER CARE, LLC; SOLENIS TECHNOLOGIES, L.P.
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 058103/0066 →
RELEASE OF SECURITY INTEREST Recorded Nov 10, 2021
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 058856/0724 →
INTELLECTUAL PROPERTY SECOND LIEN SECURITY AGREEMENT RELEASE Recorded Jul 20, 2018
From: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 047058/0800 →
INTELLECTUAL PROPERTY FIRST LIEN SECURITY AGREEMENT RELEASE Recorded Jul 20, 2018
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 046594/0252 →
FIRST LIEN NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Jul 20, 2018
From: SOLENIS TECHNOLOGIES, L.P.
To: CITIBANK, N.A., COLLATERAL AGENT
Reel/Frame 046595/0241 →
SECOND LIEN NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Jul 20, 2018
From: SOLENIS TECHNOLOGIES, L.P.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 046629/0213 →
NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS (SECOND LIEN) Recorded Aug 14, 2014
From: SOLENIS TECHNOLOGIES, L.P.
To: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
Reel/Frame 033535/0847 →
NOTICE AND CONFIRMATION OF GRANT OF SECURITY INTEREST IN PATENTS (FIRST LIEN) Recorded Aug 14, 2014
From: SOLENIS TECHNOLOGIES, L.P.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 033535/0806 →
U.S. ASSIGNMENT OF PATENTS Recorded Aug 4, 2014
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
To: SOLENIS TECHNOLOGIES, L.P.
Reel/Frame 033471/0048 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENT NUMBER 6763859 PREVIOUSLY RECORDED ON REEL 016408 FRAME 0950. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded May 9, 2014
From: ASHLAND INC.
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC
Reel/Frame 032867/0391 →