Process for making visco-elastic foam
View Patent ↗Process for preparing a visco-elastic polyurethane foam by reacting a polyisocyanate composition with a polyol composition comprising b1) an EO-rich polyol; b2) a polyol with an EO content between 20-50% and a primary hydroxy content of at least 50%; b3) a polyol with an EO content between 10-20% and a primary hydroxy content of at least 50%; and b4) a polyoxyalkyleneglycol. Further provided is a polyol composition.
1. A process for preparing a visco-elastic polyurethane foam at an NCO index of 70-120 by reacting:
a) a polyisocyanate composition;
b1) a polyoxyethylene-polyoxypropylene polyol, having an average equivalent weight between 800 and 4000 and an average nominal hydroxy functionality of 2-6, where the EO is present as random EO and/or tipped EO, the total EO content being at least 50% by weight;
b2) a polyoxyethylene-polyoxypropylene polyol, having an average equivalent weight between 800 and 4000 and an average nominal hydroxy functionality of 2-6, where the EO is present as tipped EO and/or random EO, the total EO content being between 20 and 50% by weight, having a primary hydroxy content of at least 50% calculated on the amount of primary and secondary hydroxyl groups;
b3) a polyoxyethylene-polyoxypropylene polyol, having an average equivalent weight between 800 and 4000 and an average nominal hydroxyl functionality of 2-6, having a primary hydroxy content of at least 50% calculated on the amount of primary and secondary hydroxyl groups, and having an EO content of from 10 to 20% by weight;
b4) a polyoxyalkyleneglycol having an average molecular weight from 100 to 1200;
b5) a polyoxyalkylene monool having a molecular weight of at least 120;
these compounds b1, b2, b3, b4 and b5 being reacted according to the following proportions, based on the combined weights of b1, b2, b3, b4 and b5, b1: 30-85 wt %, b2: 5-50 wt %, b3: 2-30 wt %, b4: 0-50 wt %, b5: 1-2 wt %;
c) water; and optionally
d) additives and auxiliaries known per se.
2. The process of claim 1 , wherein compounds b1, b2, b3, b4 and b5 are reacted according to the following proportions, based on the combined weights of b1, b2, b3, b4 and b5: b1: 40-80 wt %, b2: 5-30 wt %, b3: 2-20 wt %, b4: 10-40 wt % and b5: 1-15 wt %.
3. The process of claim 1 , wherein the functionality of the polyols b1, b2 and b3 is 2-4 and the EO content of the polyol and the monool based on the combined weights of b1, b2, b3, b4 and b5 is at least 40% by weight.
4. The process of claim 2 , wherein the functionality of the polyols b1, b2 and b3 is 2-4 and the EO content of the polyol and the monool based on the combined weights of b1, b2, b3, b4 and b5 is at least 40% by weight.
5. The process of claim 1 , wherein the monool b5 is a polyoxyethylene polyoxypropylene or polyoxyethylene monool having a molecular weight of 200-900.
6. The process of claim 2 , wherein the monool b5 is a polyoxyethylene polyoxypropylene or polyoxyethylene monool having a molecular weight of 200-900.
7. The process of claim 3 , wherein the monool b5 is a polyoxyethylene polyoxypropylene or polyoxyethylene monool having a molecular weight of 200-900.
8. The process of claim 4 , wherein the monool b5 is a polyoxyethylene polyoxypropylene or polyoxyethylene monool having a molecular weight of 200-900.
9. The process of claim 1 , wherein the monool b5 is a polyoxyethylene polyoxypropylene monool comprising at least 50% by weight, based on the weight of the monool, of oxyethylene groups or a polyoxyethylene monool or mixtures thereof.
10. The process of claim 2 , wherein the monool b5 is a polyoxyethylene polyoxypropylene monool comprising at least 50% by weight, based on the weight of the monool, of oxyethylene groups or a polyoxyethylene monool or mixtures thereof.
11. The process of claim 3 , wherein the monool b5 is a polyoxyethylene polyoxypropylene monool comprising at least 50% by weight, based on the weight of the monool, of oxyethylene groups or a polyoxyethylene monool or mixtures thereof.
12. The process of claim 4 , wherein the monool b5 is a polyoxyethylene polyoxypropylene monool comprising at least 50% by weight, based on the weight of the monool, of oxyethylene groups or a polyoxyethylene monool or mixtures thereof.
13. The process of claim 5 , wherein the monool b5 is a polyoxyethylene polyoxypropylene monool comprising at least 50% by weight, based on the weight of the monool, of oxyethylene groups or a polyoxyethylene monool or mixtures thereof.
14. The process of claim 6 , wherein the monool b5 is a polyoxyethylene polyoxypropylene monool comprising at least 50% by weight, based on the weight of the monool, of oxyethylene groups or a polyoxyethylene monool or mixtures thereof.
15. The process of claim 7 , wherein the monool b5 is a polyoxyethylene polyoxypropylene monool comprising at least 50% by weight, based on the weight of the monool, of oxyethylene groups or a polyoxyethylene monool or mixtures thereof.
16. The process of claim 8 , wherein the monool b5 is a polyoxyethylene polyoxypropylene monool comprising at least 50% by weight, based on the weight of the monool, of oxyethylene groups or a polyoxyethylene monool or mixtures thereof.
17. A polyol composition comprising:
b1) a polyoxyethylene-polyoxypropylene polyol, having an average equivalent weight between 800 and 4000 and an average nominal hydroxy functionality of 2-6, where the EO is present as random EO and/or tipped EO, the total EO content being at least 50% by weight;
b2) a polyoxyethylene-polyoxypropylene polyol, having an average equivalent weight between 800 and 4000 and an average nominal hydroxy functionality of 2-6, where the EO is present as tipped EO and/or random EO, the total EO content being between 20 and 50% by weight, having a primary hydroxy content of at least 50% calculated on the amount of primary and secondary hydroxyl groups;
b3) a polyoxyethylene-polyoxypropylene polyol, having an average equivalent weight between 800 and 4000 and an average nominal hydroxyl functionality of 2-6, having a primary hydroxy content of at least 50% calculated on the amount of primary and secondary hydroxyl groups and having an EO content of from 10 to 20% by weight;
b4) a polyoxyalkyleneglycol having an average molecular weight from 100 to 1200;
b5) a polyoxyalkylene monool having a molecular weight of at least 120;
these compounds b1, b2, b3, b4 and b5 being present according to the following proportions, based on the combined weights of b1, b2, b3, b4 and b5, b1: 30-85 wt %, b2: 5-50 wt %, b3: 2-3 wt %, b4: 0-50 wt %, b5: 1-20 wt %.
18. The polyol composition of claim 17 , wherein polyols b1, b2, b3, b4 and b5 are present according to the following proportions, based on the combined weights of b1, b2, b3, b4and b5: b1: 40-80 wt %, b2: 5-3 wt %, b3: 2-20 wt %, b4: 10-40 wt %, b5: 1-15 wt %.
19. The polyol composition of claim 17 , wherein the EO content based on the combined weights of b1, b2, b3, b4 and b5 is at least 40% by weight.
20. The polyol composition of claim 18 , wherein the EO content based on the combined weights of b1, b2, b3, b4 and b5 is at least 40% by weight.
21. The polyol composition of claim 17 , wherein the monool b5 is a polyoxyethylene polyoxypropylene or polyoxyethylene monool having a molecular weight of 200-900.
22. The polyol composition of claim 18 , wherein the monool b5 is a polyoxyethylene polyoxypropylene or polyoxyethylene monool having a molecular weight of 200-900.
23. The polyol composition of claim 19 , wherein the monool b5 is a polyoxyethylene polyoxypropylene or polyoxyethylene monool having a molecular weight of 200-900.
24. The polyol composition of claim 20 , wherein the monool b5 is a polyoxyethylene polyoxypropylene or polyoxyethylene monool having a molecular weight of 200-900.
25. The polyol composition of claim 17 , wherein the monool b5 is a polyoxyethylene polyoxypropylene monool comprising at least 50% by weight, based on the weight of the monool, of oxyethylene groups or a polyoxyethylene monool or mixtures thereof.
26. The polyol composition of claim 18 , wherein the monool b5 is a polyoxyethylene polyoxypropylene monool comprising at least 50% by weight, based on the weight of the monool, of oxyethylene groups or a polyoxyethylene monool or mixtures thereof.
27. The polyol composition of claim 19 , wherein the monool b5 is a polyoxyethylene polyoxypropylene monool comprising at least 50% by weight, based on the weight of the monool, of oxyethylene groups or a polyoxyethylene monool or mixtures thereof.
28. The polyol composition of claim 21 , wherein the monool b5 is a polyoxyethylene polyoxypropylene monool comprising at least 50% by weight, based on the weight of the monool, of oxyethylene groups or a polyoxyethylene monool or mixtures thereof.