Electroluminescent iridium compounds with fluorinated phenylpryidines, phenylpyrimidines, and phenylquinolines and devices made with such compounds
View Patent ↗The present invention is generally directed to electroluminescent Ir(III) compounds, the substituted 2-phenylpyridines, phenylpyrimidines, and phenylquinolines that are used to make the Ir(III) compounds, and devices that are made with the Ir(III) compounds.
1. An organic electronic device comprising an emitting layer having an emission maximum in the range of 450 to 500 nm, wherein at least 20% by weight of the emitting layer comprises at least one compound having a Sixth Formula below:
IrL a L b L′L″ (Sixth Formula)
where
L′ is selected from a phosphine and an isonitrile;
L″ is selected from F, Cl, Br, and I;
L a and L b have structure (I) below,
wherein:
R 1 through R 8 are independently selected from alkyl, alkoxy, halogen, nitro, cyano, fluoro, fluorinated alkyl and fluorinated alkoxy groups, and at least one of R 1 through R 8 is selected from F, C n F 2n+1 , OC n F 2n+1 , and OCF 2 X, where n is an integer from 1 through 6 and X is H, Cl, or Br, and
A is C;
Wherein L″ is Cl, and L′ is selected from tris[3,5-bis(trifluoromethyl)phenyl]phosphine; 2,6-dimethylphenyl isocyanide; 3-trifluoromethylphenyl isocyanide; and 4-toluenesulfonylmethyl isocyanide.
2. An organic electronic device comprising a light-emitting layer and an electron transport layer, wherein the material in the electron transport layer is selected from
3. An organic electronic device comprising an emitting layer having an emission maximum in the range of 450 to 500 nm, wherein at least 20% by weight of the emitting layer comprises at least one compound having a Sixth Formula below:
IrL a L b L′L″ (Sixth Formula)
where
L′ is an isonitrile;
L″ is selected from F, Cl, Br, and I;
L a and L b have structure (I) below,
wherein:
R 1 through R 8 are independently selected from alkyl, alkoxy, halogen, nitro, cyano, fluoro, fluorinated alkyl and fluorinated alkoxy groups, and at least one of R 1 through R 8 is selected from F, C n F 2n+1 , OC n F 2n+1 , and OCF 2 X, where n is an integer from 1 through 6 and X is H, Cl, or Br, and
A is C;
wherein the isonitrile comprises an isonitrile substituent on an aromatic group.