Planographic printing plate precursor
View Patent ↗A planographic printing plate precursor includes a support having disposed thereon a recording layer containing a water-insoluble and alkali-soluble resin, a development inhibitor and an infrared absorber and exhibiting enhanced solubility in an aqueous alkali solution through light exposure. The recording layer may have either a mono-layer construction or a multi-layer construction containing a lower layer and an upper layer. In the case of the multi-layer construction, a layer containing the water-insoluble and alkali-soluble resin is used as the lower layer, and a layer containing the water-insoluble and alkali-soluble resin and the development inhibitor and exhibiting enhanced solubility in an aqueous alkali solution through light exposure is used as the upper layer, and at least one of the lower layer and the upper layer contains the infrared absorber.
1. A planographic printing plate precursor comprising a support having disposed thereon a recording layer that contains a polyimide precursor resin containing a structural unit represented by the following formula (1) and exerting water-insolubility and alkali-solubility, a development inhibitor and an infrared absorber, and exhibits enhanced solubility in an aqueous alkali solution through light exposure:
wherein R 1 represents a linking group containing at least one aromatic ring to which a —COOH group directly bonds; and R 2 represents an alkylene group, an arylene group or an aralkylene group.
2. The planographic printing plate precursor according to claim 1 , wherein the polyimide precursor resin has a weight average molecular weight of from 3,000 to 100,000.
3. The planographic printing plate precursor according to claim 1 , wherein the polyimide precursor resin is contained in an amount of from 20 to 90% by mass based on the total solid content of the recording layer.
4. A planographic printing plate precursor comprising a support having disposed thereon a recording layer including:
a lower layer containing a polyimide precursor resin having a structural unit represented by the following formula (1) and exerting water-insolubility and alkali-solubility; and
an upper layer containing a water-insoluble and alkali-soluble resin and a development inhibitor and exhibiting enhanced solubility in an aqueous alkali solution through light exposure,
wherein at least one of the lower layer and the upper layer of the recording layer contains an infrared absorber,
wherein R 1 represents a linking group containing at least one aromatic ring to which a —COOH group directly bonds; and R 2 represents an alkylene group, an arylene group or an aralkylene group.
5. The planographic printing plate precursor according to claim 4 , wherein the polyimide precursor resin has a weight average molecular weight of from 3,000 to 100,000.
6. The planographic printing plate precursor according to claim 4 , wherein the polyimide precursor resin is contained in an amount of from 40 to 90% by mass based on the total solid content of the lower layer.
7. A planographic printing plate precursor comprising a support having disposed thereon a recording layer that contains a water-insoluble and alkali-soluble resin having, as a basic skeleton, a reaction product formed using at least one kind of a diisocyanate compound represented by the following formula (I), at least one kind of a diol compound having a carboxylic group represented by the following general formulae (II), (III), and (IV), and a compound having a primary or secondary amine, a development inhibitor and an infrared absorber, and exhibits enhanced solubility in an aqueous alkali solution through light exposure:
wherein R 1 represents a divalent linking group, R 2 represents a hydrogen atom, an alkyl group, an aralkyl group, an aryl group, an alkoxy group, or an aryloxy group, and R 3 , R 4 , and R 5, which may be the same or different, each represent a single bond or a divalent linking group.
8. The planographic printing plate precursor according to claim 7 , wherein the resin has a weight average molecular weight of from 3,000 to 200,000.
9. The planographic printing plate precursor according to claim 7 , wherein the resin is contained in an amount of 10% by mass or more relative to a total alkali-soluble resin in the recording layer.
10. A planographic printing plate precursor comprising a support having disposed thereon a recording layer including:
a lower layer containing a water-insoluble and alkali-soluble resin having a urea bond in a polymer main chain; and
an upper layer containing a water-insoluble and alkali-soluble resin and a development inhibitor and exhibiting enhanced solubility in an aqueous alkali solution through light exposure,
wherein at least one of the lower layer and the upper layer of the recording layer contains an infrared absorber.
11. The planographic printing plate precursor according to claim 10 , wherein the resin having a urea bond in a polymer main chain has a weight average molecular weight of from 3,000 to 200,000.
12. The planographic printing plate precursor according to claim 10 , wherein the resin having a urea bond in a polymer main chain is contained in an amount of 10% by mass or more relative to a total alkali-soluble resin in the lower layer of the recording layer.
13. A planographic printing plate precursor comprising a support having disposed thereon a recording layer that contains a water-insoluble and alkali-soluble resin having, as a basic skeleton, a reaction product formed using at least one kind of a diisocyanate compound represented by the following formula (I), at least one kind of a diol compound having a carboxylic group represented by the following formulae (II), (III) and (IV), and at least one kind of a diol compound represented by the following formulae (V) and (VI), a development inhibitor and an infrared absorber, and exhibits enhanced solubility in an aqueous alkali solution through light exposure:
wherein R 1 represents a divalent linking group, R 2 represents a hydrogen atom, an alkyl group, an aralkyl group, an aryl group, an alkoxy group, or an aryloxy group, R 3 , R 4 , and R 5 , which may be the same or different, each represent a single bond or a divalent linking group, and R 6 and R 7 , which may be the same or different, each represent a divalent linking group and may be bonded to each other to form a cyclic structure.
14. The planographic printing plate precursor according to claim 13 , wherein the resin has a weight average molecular weight of from 5,000 to 200,000.
15. The planographic printing plate precursor according to claim 13 , wherein the resin is used in combination with a novolak resin.
16. A planographic printing plate precursor comprising a support having disposed thereon a recording layer including:
a lower layer containing a water-insoluble and alkali-soluble polyurethane resin; and
an upper layer containing a water-insoluble and alkali-soluble resin and a development inhibitor and exhibiting enhanced solubility in an aqueous alkali solution through light exposure,
wherein at least one of the lower layer and the upper layer of the recording layer contains an infrared absorber,
wherein the polyurethane resin is contained in the lower layer in an amount of 55 to 95% by mass.