IP Library Granted Patent US 6,929,875
Granted Patent B2
US 6,929,875 · App. 10/701,801 · Granted Aug 16, 2005

Method of making wallboard

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Quick Facts
Patent No.
US 6,929,875
App. No.
10/701,801
Granted
Aug 16, 2005
Kind
B2
Abstract

The present invention provides a dispersant and foaming agent combination that is useful in the production of gypsum wallboard and other aqueous cementitious products, a method of forming a gypsum wallboard and a gypsum wallboard. The dispersant in the combination according to the invention is a naphthalene sulfonate-aldehyde condensate alkali salt polymer having a weight average molecular weight of from about 17,000 to about 47,000. The alkali is preferably an alkali metal and/or an alkaline earth metal. The aldehyde is preferably formaldehyde. The foaming agent used in the combination according to the invention is a soap, preferably an alkali salt of an alkyl ether sulfate and/or an alkyl sulfate. The combination of a high molecular weight dispersant and a foaming agent produces a gypsum wallboard core effect that more efficiently entrains air (i.e., creates void space), thereby lowering overall board weight without detrimentally affecting strength. A gypsum wallboard formed using the dispersant and foaming agent combination according to the invention exhibits a higher nail pull value than gypsum wallboard formed using a conventional dispersant and a foaming agent at the same solids loading ratio.

Claims (14)

1. A method of fabricating a gypsum wallboard comprising:

forming an aqueous slurry comprising:

calcined gypsum;

a naphthalene sulfonate-aldehyde condensate alkali salt polymer having a weight average molecular weight from about 17,000 to about 47,000; and

a soap;

molding the aqueous slurry into a sheet;

allowing calcined gypsum to rehydrate; and

removing excess water from the sheet to form a hardened wallboard.

2. The method of fabricating a gypsum wallboard according to claim 1 wherein the aldehyde in the naphthalene sulfonate-aldehyde condensate alkali salt polymer is selected from the group consisting of formaldehyde, paraformaldehyde, and gluteraldehyde.

3. The method of fabricating a gypsum wallboard according to claim 1 wherein the soap comprises an alkyl sulfate and/or an alkyl ether sulfate.

4. The method of fabricating a gypsum wallboard according to claim 1 wherein the aldehyde in the naphthalene sulfonate-aldehyde condensate alkali salt polymer is formaldehyde and the soap comprises a mixture of an alkyl sulfate and an alkyl ether sulfate.

5. The method of fabricating a gypsum wallboard according to claim 1 wherein the naphthalene sulfonate-aldehyde condensate alkali salt polymer is a sodium salt.

6. The method of fabricating a gypsum wallboard according to claim 1 wherein the naphthalene sulfonate-aldehyde condensate alkali salt polymer is a calcium salt.

7. A wallboard comprising a hardened gypsum-containing core having a layer of paper disposed thereon, wherein said hardened gypsum-containing core includes a plurality of air-filled void spaces created by bubbles formed from a synergistic interaction between a naphthalene sulfonate-aldehyde condensate alkali salt polymer having a weight average molecular weight from about 17,000 to about 47,000 and a soap, wherein the paper has a maximum weight of about 35 pounds per thousand square feet and the wallboard has an overall weight rating of less than 1,500 pounds per thousand square feet based on a one-half inch board thickness and a nail pull resistance of at least about 77 pounds based upon a one-half inch board thickness as measured in accordance with the ASTM C473-00standard.

Assignments (17)
RELEASE OF SECURITY INTEREST Recorded Jun 30, 2024
From: TWIN BROOK CAPITAL PARTNERS, LLC, AS ADMINISTRATIVE AGENT
To: RG DISPERSANTS USA LLC
Reel/Frame 067877/0761 →
RELEASE OF SECURITY INTEREST Recorded Oct 19, 2020
From: U.S. BANK NATIONAL ASSOCIATION
To: GEO SPECIALTY CHEMICALS, INC.
Reel/Frame 054095/0109 →
RELEASE OF SECURITY INTEREST Recorded Sep 25, 2019
From: CITIZENS BANK, N.A.
To: GEO SPECIALTY CHEMICALS, INC.
Reel/Frame 050486/0061 →
SECURITY INTEREST Recorded Aug 30, 2019
From: GEO SPECIALTY CHEMICALS, INC.
To: TWIN BROOK CAPITAL PARTNERS, LLC, AS ADMINISTRATIVE AGENT
Reel/Frame 050219/0608 →
RELEASE OF SECURITY INTEREST Recorded Aug 20, 2019
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: GEO SPECIALTY CHEMICALS, INC.
Reel/Frame 050102/0181 →
SECURITY INTEREST Recorded Jan 11, 2019
From: GEO SPECIALTY CHEMICALS, INC.
To: CITIZENS BANK, N.A.
Reel/Frame 047968/0591 →
RELEASE OF SECURITY INTEREST Recorded Oct 19, 2017
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: GEO SPECIALTY CHEMICALS, INC.
Reel/Frame 043905/0673 →
SECURITY INTEREST Recorded Oct 18, 2017
From: GEO SPECIALTY CHEMICALS, INC.
To: U.S. BANK NATIONAL ASSOCIATION
Reel/Frame 043898/0392 →
RELEASE OF SECURITY INTEREST Recorded Feb 26, 2013
From: WELLS FARGO CAPITAL FINANCE, LLC
To: GEO SPECIALTY CHEMICALS, INC.; GEO SPECIALTY CHEMICALS LIMITED
Reel/Frame 029876/0076 →
RELEASE OF SECURITY INTEREST Recorded Oct 31, 2012
From: WELLS FARGO CAPITAL FINANCE, LLC
To: GEO SPECIALTY CHEMICALS, INC.; GEO SPECIALTY CHEMICALS LIMITED
Reel/Frame 029215/0137 →
SECURITY AGREEMENT Recorded Oct 31, 2012
From: GEO SPECIALTY CHEMICALS, INC.
To: CITIZENS BANK OF PENNSYLVANIA
Reel/Frame 029217/0707 →
RELEASE OF SECURITY INTEREST Recorded Mar 24, 2010
From: THE CIT GROUP/BUSINESS CREDIT, INC.
To: GEO SPECIALTY CHEMICALS, INC.
Reel/Frame 024128/0129 →
SECURITY AGREEMENT Recorded Mar 24, 2010
From: GEO SPECIALTY CHEMICALS, INC.; GEO SPECIALTY CHEMICALS LIMITED
To: WELLS FARGO CAPITAL FINANCE, LLC
Reel/Frame 024128/0355 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS Recorded Apr 8, 2009
From: GEO SPECIALTY CHEMICALS, INC.
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 022521/0554 →
SECURITY AGREEMENT Recorded Feb 19, 2009
From: GEO SPECIALTY CHEMICALS, INC.
To: THE CIT GROUP/BUSINESS CREDIT, INC.
Reel/Frame 022277/0316 →
SECURITY AGREEMENT Recorded Mar 17, 2006
From: GEO SPECIALTY CHEMICALS, INC.
To: WELLS FARGO BANK, NATIONAL ASSOCIATION
Reel/Frame 017314/0492 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 2, 2004
From: SAVOLY, ARPAD; ELKO, DAWN P.; VEAL, BENNIE; MCCRARY, JAMES
To: GEO SPECIALTY CHEMICALS, INC.
Reel/Frame 014940/0949 →