Photothermographic material
View Patent ↗A photothermographic material containing, on a substrate, at least a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder in which the total silver iodide content of the photosensitive silver halide is 40 mol % or more and 100 mol % or less, and the coating amount of the photosensitive silver halide, in terms of an amount of silver, is 0.0005 g/m 2 or more and 0.4 g/m 2 or less, as well as an image forming method for the photothermographic material which comprises exposing the photothermographic material by using a semiconductor laser having an emission peak intensity at a wavelength of from 350 nm to 450 nm as a light source.
1. A photothermographic material containing, on a substrate, at least a photosensitive silver halide having an average particle size of 5 nm to 40 nm, a non-photosensitive organic silver salt comprising silver behenate in an amount of 40 mol % to 99 mol %, a reducing agent which contains a compound represented by general formula (R):
in which R 11 and R 11′ each represents independently an alkyl group of 1 to 20 carbon atoms, R 12 and R 12′ each represents independently an alkyl group of 1 to 20 carbon atoms, L represents an —S— group or —CHR 13 — group, R 13 represents a hydrogen atom or an alkyl group of 1 to 20 carbon atoms, and X 1 and X 1′ each represents independently a hydrogen atom or a group capable of substitution on a benzene ring, and
a binder in which the total silver iodide content of the photosensitive silver halide is 90 mol % to 100 mol %, and the coating amount of photosensitive silver halide in terms of an amount of silver is 0.005 g/m 2 to 0.05 g/m 2 wherein in the photosensitive silver halide is formed in a state where the non-photosensitive organic salt is not present and wherein the average γ-phase ratio of the photosensitive silver halide is 5 mol % to 90 mol %.
2. A photothermographic material according to claim 1 , wherein R 11 and R 11′ in general formula (R) each represents independently a secondary or tertiary alkyl group of 3 to 15 carbon atoms.
3. A photothermographic material according to claim 1 , which further comprising a compound represented by the following general formula (H):
Q—(Y) N —C(Z 1 )(Z 2 )X General formula (H)
in which Q represents an alkyl group, aryl group or heterocyclic group, Y represents a bivalent connection group, N represents 0 or 1, Z 1 and Z 2 each represents a halogen atom, and X represents a hydrogen atom or an electron attractive group.
4. A photothermographic material according to claim 1 , wherein the average γ-phase ratio of the photosensitive silver halide is 25 mol % to 50 mol %.
5. A photothermographic material according to claim 1 , further comprising a compound in which a one-electron oxidant formed by one-electron oxidation can release one electron or more electrons.
6. A photothermographic material according to claim 1 , wherein the non-photosensitive organic silver salt contains silver behenate in an amount of 65 mol % to 85 mol %.
7. A photothermographic material according to claim 1 , further comprising a development accelerator.
8. A photothermographic material according to claim 1 , further comprising a compound represented by the following general formula (D):
in which R 21 to R 23 each represents independently an alkyl group, aryl group, alkoxy group, aryloxy group, amino group or heterocyclic group.
9. An image forming method for a photothermographic material which comprises exposing a photothermographic material according to claim 1 by using a semiconductor laser having an emission peak intensity at a wavelength of from 350 nm to 450 nm as a light source.
10. An image forming method for a photothermographic material according to claim 9 , wherein the exposure illuminance of the semiconductor laser is 1 mW/mm 2 or more.
11. An image forming method for the photothermographic material according to claim 9 , wherein the exposure illuminance of the semiconductor laser is 10 mW/mm 2 to 50 mW/mm 2 .