Fullerene-based secondary cell electrodes
View Patent ↗This invention provides methods and materials for the manufacture of lithium ion rechargeable battery electrodes comprising fullerene compounds which have not been exposed to oxygen. Fullerene compounds are intercalated into carbonaceous materials to form electrodes having superior intercalation/deintercalation properties. Fullerene monomers, such as C 60 , C 70 , C 74 , C 76 , C 78 , C 80 , C 84 and C 80–100 and fluorinated derivatives thereof, are useful in the methods and materials of this invention. Materials incorporating C 74 are particularly preferred. The invention also provides fullerene polymer materials useful for lithium ion electrodes with greatly improved electrochemical properties.
1. A method of forming an electrode comprising:
synthesizing fullerenes in a substantially oxygen free atmosphere; wherein the synthesized fullerenes include C n compounds, where n≧74; and
combining the synthesized fullerenes with a carbonaceous material in a substantially oxygen free atmosphere to form the electrode.
2. The method of claim 1 , wherein the formed electrode includes a majority of fullerenes that are substantially unoxidized.
3. The method of claim 1 , wherein the fullerenes are synthesized and combined with the carbonaceous material in an atmosphere comprising at least one of argon and helium.
4. The method of claim 1 , wherein the electrode includes fullerenes in an amount from about 1% to about 25% by weight.
5. The method of claim 1 , wherein a polymeric binder material is further combined with the synthesized fullerenes and the carbonaceous material to form the electrode.
6. The method of claim 1 , wherein the carbonaceous material includes graphite.
7. The method of claim 1 , further comprising:
forming a lithium ion battery including the formed electrode.