Sulfur-containing phosphor powders, methods for making phosphor powders and devices incorporating same
View Patent ↗Sulfur-containing phosphor powders, methods for making phosphor powders and devices incorporating same. The powders have a small particle size, narrow particle size distribution and are substantially spherical. The method of the invention permits the continuous production of such powders. The invention also relates to products such as display devices incorporating such phosphor powders.
1. A method for the production of a sulfur-containing phosphor powder, comprising the steps of:
a) forming an aqueous-based solution comprising soluble precursors of a sulfur-containing phosphor;
b) generating an aerosol of droplets from said aqueous-based solution;
c) heating said droplets to form a particulate intermediate compound that is capable of being post-treated to form said sulfur-containing phosphor compound; and
d) treating said particulate intermediate compound to form said sulfur-containing phosphor powder.
2. A method as recited in claim 1 , wherein said method further comprises the step of milling said phosphor powder.
3. A method as recited in claim 1 , wherein said method further comprises the step of annealing said phosphor powder.
4. A method as recited in claim 1 , wherein said particulate intermediate compound has an average particle size of from about 0.3 to about 3 μm.
5. A method as recited in claim 1 , wherein said treating step comprises the step of heating said phosphor powder in contact with sulfur or a sulfur-containing compound.
6. A method as recited in claim 1 , wherein said treating step comprises the step of heating said phosphor powder in contact with H 2 S gas at a temperature and for a time sufficient to form said sulfur-containing phosphor powder.
7. A method as recited in claim 1 , wherein said sulfur-containing phosphor is selected from the Group 2 and Group 12 metal sulfides.
8. A method as recited in claim 1 , wherein said sulfur-containing phosphor is a thiogallate.
9. A method as recited in claim 1 , wherein said aqueous-based solution further comprises a precursor to an activator ion.
10. A method as recited in claim 1 , wherein said sulfur-containing phosphor is CaS.
11. A method as recited in claim 1 , wherein said sulfur-containing phosphor is ZnS.
12. A method as recited in claim 1 , wherein said sulfur-containing phosphor is Y 2 O 2 S.