Chemimechanical desilication of nonwood plant materials
View Patent ↗A process for removing silica from nonwood plant materials involving both chemical and mechanical action is described. The silica-rich epidermal cells are liberated mechanically by a pre-pulping and low-consistency refining step and subsequently removed from the pulp via the filtrate of a thickening step. Amorphous silica is liberated chemically by using an alkaline dilution source in the pulper, then removed from the pulp via the filtrate of a thickening step and a dewatering step. The silica is then removed from the filtrate by adjusting the pH, followed by a separation step. The desilicated fibrous material may then be chemically or mechanically pulped and bleached using known processes. The silica removed from the nonwood plant material may then be used as a feedstock for other applications.
1. A process for desilicating nonwood plant fibers comprising:
(a) wet pre-pulping the nonwood plant fiber under controlled conditions of temperature, solids content, and with sufficient alkali to bring the pH within a pH range of 7 to about 11 and less than that required to dissolve all silica present in the fiber;
(b) removing both suspended solids and dissolved solids from the fibrous portion of the pre-pulped material by filtration or dewatering, or filtration and dewatering;
(c) adding acid to the filtrate to force the precipitation of solubilized silicate; and
(d) removing the silica and other solids from the filtrate, and reusing the filtrate in the pre-pulping step.
2. The process of claim 1 wherein the resulting nonwood plant fibers is subsequently pulped chemically and/or mechanically, then bleached.
3. The process of claim 1 wherein the precipitated silica is used as a raw material for other applications.
4. The process of claim 1 wherein the fiber is wet pre-pulped at a temperature of about 50° C. to about 90° C.
5. The process of claim 1 wherein the fiber is wet pre-pulped to a solids content of about 0.5% to 6.0% solids.